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Volumn 41, Issue 8, 2008, Pages 957-967

Unraveling water's entropic mysteries: A unified view of nonpolar, polar, and ionic hydration

Author keywords

[No Author keywords available]

Indexed keywords

SOLVENT; WATER;

EID: 51649088169     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar7001478     Document Type: Article
Times cited : (122)

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    • The dipolar and quadrupolar solvation simulations of Matyushov and co-workers (refs 25-27) indicate that 0.9 < χNL, 2 TSuv/Euv < 1.1, while 0.5 < χS, 2ΔEvv/Euv < 0.9. Linear response theory combined with Euv 0|e ≈ 0 implies that χNL, 1 while χS, 1 is predicted when |δq|e ≈ 0 and electrostatic interactions do not significantly change the partial molar of the solute i.e, electrostriction is negligible, Thus, electrostatic entropy cancelation is apparently less general than Euv 0|e ≈ 0
    • 0|e ≈ 0.


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