Tuning the work function of graphene-on-quartz with a high weight molecular acceptor

Journal of Physical Chemistry C

Volumn 118, Issue 9, 2014, Pages 4784-4790

  Christodoulou, C ^a   Giannakopoulos, A ^b   Nardi, M V ^a   Ligorio, G ^a   Oehzelt, M ^a,c   Chen, L ^b   Pasquali, L ^d,e,f   Timpel, M ^a   Giglia, A ^e   Nannarone, S ^d,e   Norman, P ^g   Linares, M ^g   Parvez, K ^h   Mullen K ^h   Beljonne, D ^b   Koch, N ^a,c  

^a HUMBOLDT UNIVERSITY   (Germany)

^b UNIVERSITY OF MONS   (Belgium)

^c HAHN MEITNER INSTITUT   (Germany)

^d UNIVERSITY OF MODENA AND REGGIO EMILIA   (Italy)

^e IOM CNR LABORATORIO TASC   (Italy)

^f UNIVERSITY OF JOHANNESBURG   (South Africa)

^g LINKÖPING UNIVERSITY   (Sweden)

^h MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION GEOMETRIES; DFT MODELING; HOLE INJECTION; INTERFACE DIPOLE; NEAR EDGE X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPIES; SURFACE COVERAGES;

ADSORPTION; QUARTZ; WORK FUNCTION; X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

GRAPHENE;

EID: 84897713744     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4122408     Document Type: Article

References (41)

1. Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.; Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Two-Dimensional Atomic Crystals Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 10451-10453
2. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Two-Dimensional Gas of Massless Dirac Fermions in Graphene Nature 2005, 438, 197-200
3. Geim, A. K.; Novoselov, K. S. The Rise of Graphene Nat. Mater. 2007, 6, 183-191
4. Castro Neto, A. H.; Guinea, F.; Peres, N. M. R.; Novoselov, K. S.; Geim, A. K. The Electronic Properties of Graphene Rev. Mod. Phys. 2009, 81, 109-162
5. Lee, C.; Wei, X.; Kysar, J. W.; Hone, J. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Science 2008, 321, 385-388
6. Li, X.; Cai, W.; An, J.; Kim, S.; Nah, J.; Yang, D.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E. Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Science 2009, 324, 1312-1314
7. Li, X.; Zhu, Y.; Cai, W.; Borysiak, M.; Han, B.; Chen, D.; Piner, R. D.; Colombo, L.; Ruoff, R. S. Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes Nano Lett. 2009, 9, 4359-4363
8. Salzmann, I.; Moser, A.; Oehzelt, M.; Breuer, T.; Feng, X.; Juang, Z.-Y.; Nabok, D.; Della Valle, R. G.; Duhm, S.; Heimel, G. Epitaxial Growth of π-Stacked Perfluoropentacene on Graphene-Coated Quartz ACS Nano 2012, 6, 10874-10883
9. Li, Y.; Liu, C.; Tong, S.; Pan, L.; Pu, L.; Minari, T.; Tsukagoshi, K.; Shi, Y. Metal-Diffusion-Induced ITO Nanoparticles at the Organic/ITO Interface J. Phys. D: Appl. Phys. 2012, 45, 165104
10. Koch, N.; Duhm, S.; Rabe, J. P.; Vollmer, A.; Johnson, R. L. Optimized Hole Injection with Strong Electron Acceptors at Organic-Metal Interfaces Phys. Rev. Lett. 2005, 95, 237601
11. Coletti, C.; Riedl, C.; Lee, D. S.; Krauss, B.; Patthey, L.; von Klitzing, K.; Smet, J. H.; Starke, U. Charge Neutrality and Band-Gap Tuning of Epitaxial Graphene on SiC by Molecular Doping Phys. Rev. B 2010, 81, 235401
12. Chen, W.; Chen, S.; Qi, D. C.; Gao, X. Y.; Wee, A. T. S. Surface Transfer p-Type Doping of Epitaxial Graphene J. Am. Chem. Soc. 2007, 129, 10418-10422
13. Drechsel, J.; Pfeiffer, M.; Zhou, X.; Nollau, A.; Leo, K. Organic Mip-Diodes by p-Doping of Amorphous Wide-Gap Semiconductors: CV and Impedance Spectroscopy Synth. Met. 2002, 127, 201-205
14. Frank, P.; Djuric, T.; Koini, M.; Salzmann, I.; Rieger, R.; Mu, K.; Resel, R.; Koch, N.; Müllen, K.; Winkler, a. Layer Growth, Thermal Stability, and Desorption Behavior of Hexaaza-Triphenylene-Hexacarbonitrile on Ag(111) J. Phys. Chem. C 2010, 114, 6650-6657
15. Liao, L. S.; Klubek, K. P. Power Efficiency Improvement in a Tandem Organic Light-Emitting Diode Appl. Phys. Lett. 2008, 92, 223311
16. Nardi, M.; Verucchi, R.; Aversa, L.; Casarin, M.; Vittadini, A.; Mahne, N.; Giglia, A.; Nannarone, S.; Iannotta, S. Electronic Properties of Tetrakis(pentafluorophenyl)porphyrin New J. Chem. 2013, 37, 1036-1045
17. Nardi, M. V.; Detto, F.; Aversa, L.; Verucchi, R.; Salviati, G.; Iannotta, S.; Casarin, M. Electronic Properties of CuPc and H2Pc: An Experimental and Theoretical Study Phys. Chem. Chem. Phys. 2013, 15, 12864-12881
18. Chen, L.; Wang, L.; Shuai, Z.; Beljonne, D. Energy Level Alignment and Charge Carrier Mobility in Noncovalently Functionalized Graphene J. Phys. Chem. Lett. 2013, 4, 2158-2165
19. Glowatzki, H.; Bröker, B.; Blum, R.-P.; Hofmann, O. T.; Vollmer, A.; Rieger, R.; Müllen, K.; Zojer, E.; Rabe, J. P.; Koch, N. "Soft" Metallic Contact to Isolated C60 Molecules Nano Lett. 2008, 8, 3825-3829
20. Niederhausen, J.; Amsalem, P.; Frisch, J.; Wilke, A.; Vollmer, A.; Rieger, R.; Müllen, K.; Rabe, J. P.; Koch, N. Tuning Hole-Injection Barriers at Organic/Metal Interfaces Exploiting the Orientation of a Molecular Acceptor Interlayer Phys. Rev. B 2011, 84, 165302
21. Amsalem, P.; Niederhausen, J.; Frisch, J.; Wilke, A.; Bröker, B.; Vollmer, A.; Rieger, R.; Müllen, K.; Rabe, J. P.; Koch, N. Metal-to-Acceptor Charge Transfer through a Molecular Spacer Layer J. Phys. Chem. C 2011, 115, 17503-17507
22. Winkler, S.; Frisch, J.; Schlesinger, R.; Oehzelt, M.; Rieger, R.; Räder, J.; Rabe, J. P.; Müllen, K.; Koch, N. The Impact of Local Work Function Variations on Fermi Level Pinning of Organic Semiconductors J. Phys. Chem. C 2013, 117, 22285-22289
23. Bröker, B.; Hofmann, O. T.; Rangger, G. M.; Frank, P.; Blum, R.-P.; Rieger, R.; Venema, L.; Vollmer, a.; Müllen, K.; Rabe, J. P. Density-Dependent Reorientation and Rehybridization of Chemisorbed Conjugated Molecules for Controlling Interface Electronic Structure Phys. Rev. Lett. 2010, 104, 246805
24. Cumpson, P. J.; Seah, M. P. Elastic Scattering Corrections in AES and XPS. II. Estimating Attenuation Lengths and Conditions Required for Their Valid Use in Overlayer/Substrate Experiments Surf. Interface Anal. 1997, 25, 430-446
25. Pasquali, L. The UHV Experimental Chamber For Optical Measurements (Reflectivity and Absorption) and Angle Resolved Photoemission of the BEAR Beamline at ELETTRA. In AIP Conference Proceedings; AIP: Melville, NY, USA, 2004; Vol. 705, pp 1142-1145.
26. Nannarone, S. The BEAR Beamline at Elettra. In AIP Conference Proceedings; AIP: Melville, NY, USA, 2004; Vol. 705, pp 450-453.
27. Serkovic Loli, L. N.; Hamoudi, H.; Gayone, J. E.; Martiarena, M. L.; Sánchez, E. A.; Grizzi, O.; Pasquali, L.; Nannarone, S.; Doyle, B. P.; Dablemont, C. Growth of N, N ′-Bis(1-ethylpropyl)perylene-3,4,9,10- tetracarboxdiimide Films on Ag (111) J. Phys. Chem. C 2009, 113, 17866-17875
28. Kresse, G.; Hafner, J. Ab Initio Molecular Dynamics for Liquid Metals Phys. Rev. B 1993, 47, 558-561
29. Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set Phys. Rev. B 1996, 54, 11169-11186
30. Kresse, G.; Furthmüller, J. Efficiency of ab-Initio Total Energy Calculations for Metals and Semiconductors Using a Plane-Wave Basis Set Comput. Mater. Sci. 1996, 6, 15-50
31. Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized Gradient Approximation Made Simple Phys. Rev. Lett. 1996, 77, 3865-3868
32. Grimme, S. Semiempirical GGA-Type Density Functional Constructed with a Long-Range Dispersion Correction J. Comput. Chem. 2006, 27, 1787-1799
33. Kokalj, A. Computer Graphics and Graphical User Interfaces as Tools in Simulations of Matter at the Atomic Scale Comput. Mater. Sci. 2003, 28, 155-168
34. Kendall, R. A.; Dunning, T. H., Jr.; Harrison, R. J. Electron Affinities of the First-row Atoms Revisited. Systematic Basis Sets and Wave Functions J. Chem. Phys. 1992, 96, 6796-6806
35. Aidas, K.; Angeli, C.; Bak, K. L.; Bakken, V.; Bast, R.; Boman, L.; Christiansen, O.; Cimiraglia, R.; Coriani, S.; Dahle, P. The Dalton Quantum Chemistry Program System Wiley Interdiscip. Rev.: Comput. Mol. Sci. 2013, 10.1002/wcms.1172
36. Hammer, B.; Hansen, L. B.; Nørskov, J. K. Improved Adsorption Energetics Within Density-Functional Theory Using Revised Perdew-Burke-Ernzerhof Functionals Phys. Rev. B 1999, 59, 7413-7421
37. Chen, J. H.; Ishigami, M.; Jang, C.; Hines, D. R.; Fuhrer, M. S.; Williams, E. D. Printed Graphene Circuits Adv. Mater. 2007, 19, 3623-3627
38. Farmer, D. B.; Golizadeh-Mojarad, R.; Perebeinos, V.; Lin, Y.-M.; Tulevski, G. S.; Tsang, J. C.; Avouris, P. Chemical Doping and Electron-Hole Conduction Asymmetry in Graphene Devices Nano Lett. 2009, 9, 388-392
39. 2 Appl. Phys. Lett. 2011, 99, 122108
40. Stöhr, J. NEXAFS Spectroscopy; Springer: Berlin, 1992.
41. Amsalem, P.; Niederhausen, J.; Wilke, A.; Heimel, G.; Schlesinger, R.; Winkler, S.; Vollmer, A.; Rabe, J. P.; Koch, N. Role of Charge Transfer, Dipole-Dipole Interactions, and Electrostatics in Fermi-Level Pinning at a Molecular Heterojunction on a Metal Surface Phys. Rev. B 2013, 87, 035440