Copolymerization of EDOT with pyrrole on TiO2 semiconductor films by one-step reaction, structure-dependent electronic properties, and charge conduction models of the composite films

Langmuir

Volumn 30, Issue 8, 2014, Pages 2241-2248

  Ma, Xun ^a   Ni, Xiuyuan ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

3 ,4-ETHYLENEDIOXYTHIOPHENE; ELECTROCHEMICAL IMPEDENCE; HETEROJUNCTION DEVICES; ORGANIC/INORGANIC HETEROJUNCTIONS; SEMICONDUCTOR FILMS; SPECULAR REFLECTIONS; STRUCTURE-DEPENDENT ELECTRONICS; VALENCE-BAND ELECTRONIC STRUCTURE;

AROMATIC COMPOUNDS; COMPOSITE FILMS; COPOLYMERIZATION; COPOLYMERS; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; INFRARED SPECTROSCOPY; PHOTOELECTRONS; TITANIUM DIOXIDE; ULTRAVIOLET PHOTOELECTRON SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

HETEROJUNCTIONS;

EID: 84897707639     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la404773r     Document Type: Article

References (51)

1. 2 nanoparticles on self-assembly behaviors and optical and photovoltaic properties of the P3HT-b-P2VP block copolymer Langmuir 2011, 27, 109-115
2. Bhatt, M. P.; Sista, P.; Hao, J.; Hundt, N.; Biewer, M. C.; Stefan, M. C. Electronic properties-morphology correlation of a rod-rod semiconducting liquid crystalline block copolymer containing poly(3-hexylthiophene) Langmuir 2012, 28, 12762-12770
3. Giovanella, U.; Botta, C.; Galeotti, F.; Vercelli, B.; Battiato, S.; Pasini, M. Perfluorinated polymer with unexpectedly efficient deep blue electroluminescence for full-colour OLED displays and light therapy applications J. Mater. Chem. C 2013, 1, 5322-5329
4. Jeong, Y. S.; Akagi, K. Liquid crystalline PEDOT derivatives exhibiting reversible anisotropic electrochromism and linearly and circularly polarized dichroism J. Mater. Chem. 2011, 21, 10472-10481
5. Yang, Z.; Xue, Z.; Liao, Y.; Zhou, X.; Zhou, J.; Zhu, J.; Xie, X. Hierarchical hybrids of carbon nanotubes in amphiphilic poly(ethyleneoxide)- block-polyaniline through a facile method: from smooth to thorny Langmuir 2013, 29, 3757-3764
6. Bhattacharyya, D.; Gleason, K. K. Single-step oxidative chemical vapor deposition of -COOH functional conducting copolymer and immobilization of biomolecule for sensor application Chem. Mater. 2011, 23, 2600-2605
7. Chang, C.; Her, L.; Hong, J. Copolymer from electropolymerization of thiophene and 3,4-ethylenedioxythiophene and its use as cathode for lithium ion battery Electrochim. Acta 2005, 50, 4461-4468
8. Sadekar, A. G.; Mohite, D.; Mulik, S.; Chandrasekaran, N.; Sotiriou-Leventis, C.; Leventis, N. Robust PEDOT films by covalent bonding to substrates using in tandem sol-gel, surface initiated free-radical and redox polymerization J. Mater. Chem. 2012, 22, 100-108
9. Snook, G. A.; Best, A. S. Co-deposition of conducting polymers in a room temperature ionic liquid J. Mater. Chem. 2009, 19, 4248-4254
10. Fossey, S. A.; Bruno, F. F.; Kumar, J.; Samuelson, L. A. Conformational analysis of the conducting copolymer poly(3,4-ethylenedioxythiophene-co-pyrrole) Synth. Met. 2009, 159, 1409-1413
11. Tewari, A.; Kokil, A.; Ravichandran, S.; Nagarajan, S.; Bouldin, R.; Samuelson, L. A.; Nagarajan, R.; Kumar, J. Soybean peroxidase catalyzed enzymatic synthesis of pyrrole/EDOT copolymers Macromol. Chem. Phys. 2010, 211, 1610-1617
12. Bruno, F. F.; Fossey, S. A.; Nagarajan, S.; Nagarajan, R.; Kumar, J.; Samuelson, L. A. Biomimetic synthesis of water-soluble conducting copolymers/homopolymers of pyrrole and 3,4-ethylenedioxythiophene Biomacromolecules 2006, 7, 586-589
13. Bruno, F. F.; Nagarajan, R.; Roy, S.; Kumar, J.; Samuelson, L. A. Biomimetic synthesis of water soluble conductive polypyrrole and poly(3,4-ethylenedioxythiophene) J. Macromol. Sci., Pure Appl. Chem. 2003, 40, 1327-1333
14. Sönmez, G.; Saraç, A. S. Structural study of pyrrole-EDOT copolymer on carbon fiber micro-electrodes Synth. Met. 2003, 135-136, 459-460
15. Saraç, A. S.; Sönmez, G.; Cebeci, F. Ç. Electrochemical synthesis and structural studies of polypyrroles, poly(3,4-ethylenedioxythiophene)s and copolymers of pyrrole and 3,4-ethylenedioxythiophene on carbon fiber microelectrodes J. Appl. Electrochem. 2003, 33, 295-301
16. Tao, Y.; Cheng, H.; Zheng, W.; Zhang, Z.; Liu, D. Electrosynthesises and characterizations of copolymers based on pyrrole and 3,4-ethylenedioxythiophene in aqueous micellar solution Synth. Met. 2012, 162, 728-734
17. Tao, Y.; Cheng, H.; Zheng, W.; Zhang, Z. Electrosynthesis and characterizations of a multielectrochromic copolymer based on pyrrole and 3,4-ethylenedioxythiophene J. Appl. Polym. Sci. 2013, 127, 636-642
18. Zhang, Z.; Tao, Y.; Xu, X.; Zhou, Y.; Cheng, H.; Zheng, W. Multicolor electrochromism of low-bandgap copolymers based on pyrrole and 3,4-ethylenedioxythiophene: fine-tuning colors through feed ratio J. Appl. Polym. Sci. 2013, 129, 1506-1512
19. 3 semiconductor substrates Langmuir 2012, 28, 4829-4834
20. 2 nanorods Sol. Energy Mater. Sol. Cells 2013, 118, 109-115
21. 2 nanorod/polythiophene composites for bulk heterojunction solar cells using hydrogen bonding Macromolecules 2012, 45, 8665-8673
22. 2-polyaniline core-shell nanofibers and their unique UV photoresponse based on different photoconductive mechanisms in oxygen and non-oxygen environments Chem. Commu. 2013, 49, 4676-4678
23. 2 hybrid solar cell ACS Appl. Mater. Interfaces 2013, 5, 1009-1016
24. Yan, J.; Ye, Q.; Hana, X.; Zhou, F. Step-by-step build-up of ordered p-n heterojunctions at nanoscale for efficient light harvesting RSC Adv. 2013, 3, 166-171
25. Maeng, J.; Jo, M.; Kang, S.; Kwon, M.; Jo, G.; Kim, T.; Seo, J.; Hwang, H.; Kim, D.; Park, S.; Lee, T. Transient reverse current phenomenon in a p-n heterojunction composed of poly(3,4-ethylene-dioxythiophene):poly(styrene- sulfonate) and ZnO nanowall Appl. Phys. Lett. 2008, 93, 123109
26. Shockley, W. The theory of pn junctions in semiconductors and pn transistors Bell Syst. Technol. J. 1949, 28, 435
27. Oldham, W. G.; Milnes, A. G. Interface states in abrupt semiconductor heterojunctions Solid-State Electron. 1964, 7, 153-165
28. Dietmueller, R.; Nesswetter, H.; Schoell, S. J.; Sharp, I. D.; Stutzmann, M. Band alignment at organic-inorganic heterojunctions between P3HT and n-type 6H-SiC ACS Appl. Mater. Interfaces 2011, 3, 4286-4291
29. Fabre, B.; Lopinski, G. P.; Wayner, D. D. M. Photoelectrochemical generation of electronically conducting polymer-based hybrid junctions on modified Si(111) surfaces J. Phys. Chem. B 2003, 107, 14326-14335
30. Hu, H.; Kung, S.; Yang, L.; Nicho, M. E.; Penner, R. M. Photovoltaic devices based on electrochemical-chemical deposited CdS and poly3-octylthiophene thin films Sol. Energy Mater. Sol. Cells 2009, 93, 51-54
31. Weng, Z.; Ni, X.; Yang, D.; Wang, J.; Chen, W. Novel photopolymerizations initiated by alkyl radicals generated from photocatalyzed decarboxylation of carboxylic acids over oxide semiconductor nanoparticles: extended photo-Kolbe reactions J. Photochem. Photobiol., A 2009, 201, 151-156
32. Yang, D.; Ni, X.; Chen, W.; Weng, Z. The observation of photo-Kolbe reaction as a novel pathway to initiate photocatalytic polymerization over oxide semiconductor nanoparticles J. Photochem. Photobiol., A 2008, 195, 323-329
33. Ng, Y. H.; Ikeda, S.; Harada, T.; Higashida, S.; Sakata, T.; Mori, H.; Matsumura, M. Fabrication of hollow carbon nanospheres encapsulating platinum nanoparticles using a photocatalytic reaction Adv. Mater. 2007, 19, 597-601
34. 4/PPy composite microspheres and their excellent Cr(VI) ion removal properties J. Mater. Chem. 2012, 22, 9034-9040
35. 4-polypyrrole nanoparticles with core-shell structure Polym. Int. 2003, 52, 1182-1187
36. Tian, B.; Zerbi, G. Lattice dynamics and vibrational spectra of polypyrrole J. Chem. Phys. 1990, 92, 3886-3891
37. Dai, C.; Hang, C.; Chi, H.; Chien, H.; Su, W.; Chiu, W. Emulsion synthesis of nanoparticles containing PEDOT using conducting polymeric surfactant: synergy for colloid stability and intercalation doping J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 2536-2548
38. 3+O(OH, Cl) nanospindles in aqueous solution J. Phys. Chem. C 2009, 113, 9465-9472
39. Yang, X.; Lu, Y. Hollow nanometer-sized polypyrrole capsules with controllable shell thickness synthesized in the presence of chitosan Polymer 2005, 46, 5324-5328
40. Pielichowski, K.; Njuguna, J. Thermal Degradation of Polymeric Materials; Rapra Technology Limited: Shawbury SY4 4NR, U.K., 2005.
41. Yue, G.; Wu, J.; Xiao, Y.; Lin, J.; Huang, M.; Lan, Z. Application of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate/polypyrrole counter electrode for dye-sensitized solar cells J. Phys. Chem. C 2012, 116, 18057-18063
42. Zheng, H. W.; Yan, Y. L.; Lv, Z. C.; Yang, S. W.; Li, X. G.; Liu, J. D.; Ye, B. J.; Peng, C. X.; Diao, C. L.; Zhang, W. F. Room-temperature ferromagnetism in Cu-implanted 6H-SiC single crystal Appl. Phys. Lett. 2013, 102, 142409
43. Ford, W. K.; Duke, C. B.; Salaneck, W. R. Electronic structure of polypyrrole and oligomers of pyrrole J. Chem. Phys. 1982, 77, 5030-5039
44. Colle, R.; Curioni, A. Density-functional theory study of electronic and structural properties of doped polypyrroles J. Am. Chem. Soc. 1998, 120, 4832-4839
45. Yun, D.; Rhee, S. Composite films of oxidized multiwall carbon nanotube and poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) as a contact electrode for transistor and inverter devices ACS Appl. Mater. Interfaces 2012, 4, 982-989
46. Lacher, S.; Obata, N.; Luo, S.; Matsuo, Y.; Zhu, B.; Yu, H.; Nakamura, E. Electropolymerized conjugated polyelectrolytes with tunable work function and hydrophobicity as an anode buffer in organic optoelectronics ACS Appl. Mater. Interfaces 2012, 4, 3396-3404
47. Gadisa, A.; Tvingstedt, K.; Admassie, S.; Lindell, L.; Crispin, X.; Andersson, M. R.; Salaneck, W. R.; Inganäs, O. Transparent polymer cathode for organic photovoltaic devices Synth. Met. 2006, 156, 1102-1107
48. Cheung, S. K.; Cheung, N. W. Extraction of Schottky diode parameters from forward current-voltage characteristics Appl. Phys. Lett. 1986, 49, 85-87
49. Chang, S.; Lu, C.; Chang, S.; Chiou, Y.; Hsu, C.; Su, P.; Hsueh, T. A novel fabrication of p-n diode based on ZnO nanowire/p-NiO Heterojunction Jpn. J. Appl. Phys. 2011, 50, 01AJ05
50. Abbotto, A.; Calderon, E. H.; Dangate, M. S.; De Angelis, F.; Manfredi, N.; Mari, C. M.; Marinzi, C.; Mosconi, E.; Muccini, M.; Ruffo, R.; Seri, M. Pyridine-EDOT heteroarylene-vinylene donor-acceptor polymers Macromolecules 2010, 43, 9698-9713
51. Hong, J.; Jang, J. A comparative study on electrorheological properties of various silica-conducting polymer core-shell nanospheres Soft Matter 2010, 6, 4669-4671