Phosphine-catalyzed enantioselective γ-addition of 3-substituted oxindoles to 2,3-butadienoates and 2-butynoates: Use of prochiral nucleophiles

Angewandte Chemie - International Edition

Volumn 53, Issue 11, 2014, Pages 2964-2968

  Wang, Tianli ^a   Yao, Weijun ^a   Zhong, Fangrui ^a   Pang, Guo Hao ^a   Lu, Yixin ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

addition; allylation; bifunctional phosphines; oxindoles; quaternary carbon centers

Indexed keywords

ADDITION PRODUCTS; BI-FUNCTIONAL; BIOLOGICALLY RELEVANT MOLECULES; CHIRAL PHOSPHINE; OXINDOLES; QUATERNARY CARBON; QUATERNARY CENTERS; REACTION PARTNERS;

ALLYLATION; AMINO ACIDS; CARBON; CATALYSIS; ENANTIOSELECTIVITY; NUCLEOPHILES; SCAFFOLDS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

PHOSPHORUS COMPOUNDS;

2 BUTYNOIC ACID; 2-BUTYNOIC ACID; ALLYL COMPOUND; BIOLOGICAL PRODUCT; DRUG DERIVATIVE; ESERMETHOLE; INDOLE DERIVATIVE; IRIDIUM; OXINDOLE; PHOSPHINE; PHOSPHINE DERIVATIVE; PHYSOSTIGMINE; UNSATURATED FATTY ACID;

ALLYLATION; ARTICLE; BIFUNCTIONAL PHOSPHINES; CATALYSIS; CHEMISTRY; OXINDOLES; QUATERNARY CARBON CENTERS; STEREOISOMERISM; SYNTHESIS; Γ-ADDITION;

ALLYLATION; BIFUNCTIONAL PHOSPHINES; OXINDOLES; QUATERNARY CARBON CENTERS; Γ-ADDITION;

ALLYL COMPOUNDS; BIOLOGICAL PRODUCTS; CATALYSIS; FATTY ACIDS, UNSATURATED; INDOLES; IRIDIUM; PHOSPHINES; PHYSOSTIGMINE; STEREOISOMERISM;

EID: 84896800794     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201307757     Document Type: Article

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