Asymmetric catalysis with libraries of palladium β-turn phosphine complexes [18]

Journal of the American Chemical Society

Volumn 122, Issue 27, 2000, Pages 6522-6523

  Gilbertson, Scott R ^a   Collibee, Scott E ^a   Agarkov, Anton ^a  

^a WASHINGTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM COMPLEX; PHOSPHINE;

ACYLATION; CATALYSIS; CATALYST; HYDROGEN BOND; LETTER; NUCLEAR OVERHAUSER EFFECT; PEPTIDE SYNTHESIS; PROTEIN STRUCTURE; REACTION ANALYSIS;

EID: 0034641261     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992306f     Document Type: Letter

References (23)

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22. For a complete listing of the libraries synthesized and the selectivities obtained with these libraries see the Supporting Information.
23. The selectivities determined in the initial library appear to be slightly higher than later numbers because of changes in the method used to determine the ee. It is important to note that the trends in the initial data are identical to subsequent data. The best ligand in the initial screen is the best ligand in all subsequent testing. The superior method for the determination of the selectivity is the method of Evans: Evans, D. A.; Campos, K. R.; Tedrow, J. S.; Michael, F. E.; Gagné, M. R. J. Org. Chem. 1999, 64, 2994-2995.