A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis

Journal of the American Chemical Society

Volumn 136, Issue 5, 2014, Pages 2149-2161

  Gao, Fang ^a   Carr, James L ^a   Hoveyda, Amir H ^a  

^a BOSTON COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC REACTIONS; ENANTIOSELECTIVE ALLYLIC SUBSTITUTION; ENANTIOSELECTIVE COUPLING; ENANTIOSELECTIVE SYNTHESIS; HIGH ENANTIOSELECTIVITY; N-HETEROCYCLIC CARBENES; NATURAL PRODUCT SYNTHESIS; TRISUBSTITUTED ALKENES;

CARBON; CATALYSIS; OLEFINS; ORGANIC POLYMERS; SUBSTITUTION REACTIONS;

ENANTIOSELECTIVITY;

ALCOHOL; ALDEHYDE; ALKENYL GROUP; CARBENE; COPPER; COPPER COMPLEX; ELECTROPHILE; ESTER; N HETEROCYCLIC CARBENE; NATURAL PRODUCT; PHOSPHATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; ENANTIOSELECTIVITY; EPIMERIZATION; SYNTHESIS;

ALKENES; BIOLOGICAL PRODUCTS; BORON COMPOUNDS; CATALYSIS; COPPER; HETEROCYCLIC COMPOUNDS; METHANE; MOLECULAR STRUCTURE; PHOSPHATES; STEREOISOMERISM;

EID: 84893799769     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4126565     Document Type: Article

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