Enantioselective double manipulation of tetrahydroisoquinolines with terminal alkynes and aldehydes under copper(I) catalysis

Angewandte Chemie - International Edition

Volumn 53, Issue 1, 2014, Pages 277-281

  Lin, Weilong ^a   Cao, Tao ^a   Fan, Wu ^b   Han, Yulin ^a   Kuang, Jinqiang ^a   Luo, Hongwen ^b   Miao, Bukeyan ^b   Tang, Xinjun ^a   Yu, Qiong ^b   Yuan, Weiming ^b   Zhang, Jiasheng ^a   Zhu, Can ^a   Ma, Shengming ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b EAST CHINA NORMAL UNIVERSITY   (China)

Author keywords

alkynylation; asymmetric catalysis; chirality; copper; tetrahydroisoquinoline alkaloids

Indexed keywords

ALKYNYLATIONS; ASYMMETRIC CATALYSIS; CATALYST LOADINGS; ENANTIOSELECTIVE; ENANTIOSELECTIVE SYNTHESIS; STEREOGENIC CENTERS; TERMINAL ALKYNE; TETRAHYDROISOQUINOLINES;

ALDEHYDES; ALKALOIDS; AROMATIC COMPOUNDS; CATALYSIS; CHIRALITY; COPPER; ENANTIOSELECTIVITY; HYDROCARBONS; METABOLITES; NITROGEN COMPOUNDS;

LOADING;

ALDEHYDE; ALKYNE; COPPER; ISOQUINOLINE DERIVATIVE;

ALKYNYLATION; ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CHIRALITY; STEREOISOMERISM; SYNTHESIS; TETRAHYDROISOQUINOLINE ALKALOIDS;

ALKYNYLATION; ASYMMETRIC CATALYSIS; CHIRALITY; COPPER; TETRAHYDROISOQUINOLINE ALKALOIDS;

ALDEHYDES; ALKYNES; CATALYSIS; COPPER; ISOQUINOLINES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84890935104     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201308699     Document Type: Article

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65. int=0.0686), number of observations [>2σ(I)]: 16 259, parameters: 1119. CCDC 962647 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.