Organocatalytic conjugate-addition polymerization of linear and cyclic acrylic monomers by N-heterocyclic carbenes: Mechanisms of chain initiation, propagation, and termination

Journal of the American Chemical Society

Volumn 135, Issue 47, 2013, Pages 17925-17942

  Zhang, Yuetao ^a   Schmitt, Meghan ^a   Falivene, Laura ^b   Caporaso, Lucia ^b   Cavallo, Luigi ^c   Chen, Eugene Y X ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b UNIVERSITY OF SALERNO   (Italy)

^c KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; CONJUGATE ADDITION; HIGH MOLECULAR WEIGHT; INITIATOR EFFICIENCY; METHYL METHACRYLATES; N-HETEROCYCLIC CARBENES; POLYMERIZATION ACTIVITY; TURNOVER FREQUENCY;

ACRYLIC MONOMERS; CHAINS; ESTERS; MONOMERS; SOLVENTS;

DIMERIZATION;

CARBENE; ENAMINE; GAMMA METHYL ALPHA METHYLENE GAMMA BUTYROLACTONE; HETEROCYCLIC NITRO COMPOUND; LACTONE DERIVATIVE; METHACRYLIC ACID METHYL ESTER; MONOMER; N HETEROCYCLIC CARBENE; UNCLASSIFIED DRUG;

ARTICLE; BIOMASS; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIMERIZATION; ENERGY; MOLECULAR WEIGHT; ORGANOCATALYSIS; POLYMERIZATION; PROTON TRANSPORT;

EID: 84889248740     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4088677     Document Type: Article

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