메뉴 건너뛰기




Volumn 167, Issue , 2004, Pages 1-34

Group transfer polymerization: Mechanism and comparison with other methods for controlled polymerization of acrylic monomers

(1)  Webster, Owen W a  

a NONE   (United States)

Author keywords

Group transfer polymerization; GTP mechanism; Living anionic polymerization of MMA; Living polymerization; Polyacrylates; Polymethacrylates

Indexed keywords

CARBOXYLIC ACID; MONOMER; POLYACRYLIC ACID; POLYMER; TRIMETHYLSILYL DERIVATIVE; WATER;

EID: 2442667749     PISSN: 00653195     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Review
Times cited : (169)

References (95)
  • 4
    • 0013131368 scopus 로고    scopus 로고
    • Group transfer polymerization
    • Kricheldorf HR (ed). Springer, Berlin Heidelberg New York
    • Hertler WR (1996) Group transfer polymerization. In: Kricheldorf HR (ed) Silicon in polymer synthesis. Springer, Berlin Heidelberg New York, p 69
    • (1996) Silicon in Polymer Synthesis , pp. 69
    • Hertler, W.R.1
  • 5
    • 0345387841 scopus 로고    scopus 로고
    • Group transfer polymerization for controlled polymer architecture
    • Hatada K, Kitayama T, Vogl O (eds). Marcel Dekker, New York
    • Hertler WR (1997) Group transfer polymerization for controlled polymer architecture. In: Hatada K, Kitayama T, Vogl O (eds) Macromolecular design of polymeric materials. Marcel Dekker, New York, p 109
    • (1997) Macromolecular Design of Polymeric Materials , pp. 109
    • Hertler, W.R.1
  • 22
    • 85069094287 scopus 로고    scopus 로고
    • (1992) U.S. Patent 5,162,467 (to DuPont)
    • Corbin DR, Sormani PME (1992) U.S. Patent 5,162,467 (to DuPont)
    • Corbin, D.R.1    Sormani, P.M.E.2
  • 29
    • 85069093690 scopus 로고    scopus 로고
    • (1988) U.S. Patent 4,736,003 (to DuPont)
    • Schneider LV, Dicker IB (1988) U.S. Patent 4,736,003 (to DuPont)
    • Schneider, L.V.1    Dicker, I.B.2
  • 31
    • 85069093663 scopus 로고    scopus 로고
    • unpublished results
    • Vamvakaki M (U Crete), Patrickios CS (U Cyprus), Webster OW unpublished results. MMA, MTS, TMS benzoate (made by reaction of MTS with benzoic acid) and TBA benzoate were combined in THF (25% solution) at molar ratios of 20/1/5/0.02. The polymerization was 65% complete in 2.5 h (GPC), Mn 3300, MWD 1.07. After 24 h, Mn 4900, MWD 1.07. With no TMS benzoate the polymerization was complete in 10 min, Mn 2600, MWD 1.37
    • Vamvakaki, M.1    Patrickios, C.S.2    Webster, O.W.3
  • 32
    • 85069119895 scopus 로고    scopus 로고
    • unpublished results
    • Uschida S (present location Tokyo Inst Tech), Webster OW unpublished results. MMA, MTS, TMS Ac, and TBA Ac were combined in THF (20% solution) at a molar ratio of 20/1/5/0.02. The polymerization was complete in 30 min (NMR). Mn 1632, MWD 1.17. Without the TMS Ac the THF refluxed and the polymerization was over in less than 1 min
    • Uschida, S.1    Webster, O.W.2
  • 36
    • 85069105022 scopus 로고    scopus 로고
    • unpublished results
    • Webster OW, unpublished results
    • Webster, O.W.1
  • 53
    • 0011132881 scopus 로고
    • Szwarc M (1956) Nature 178:1168
    • (1956) Nature , vol.178 , pp. 1168
    • Szwarc, M.1
  • 91
    • 85069103380 scopus 로고    scopus 로고
    • Private communication
    • Davis TP (2002) Private communication
    • (2002)
    • Davis, T.P.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.