A snapshot of P4 tetrahedron opening: Rh- and Ir-mediated activation of white phosphorus

Angewandte Chemie - International Edition

Volumn 45, Issue 25, 2006, Pages 4182-4185

  Yakhvarov, Dmitry ^a   Barbaro, Pierluigi ^b   Gonsalvi, Luca ^b   Carpio, Sonia Mañas ^b   Midollini, Stefano ^b   Orlandini, Annabella ^b   Peruzzini, Maurizio ^b   Sinyashin, Oleg ^a,b   Zanobini, Fabrizio ^b  

^a A E ARBUZOV INSTITUTE OF ORGANIC AND PHYSICAL CHEMISTRY   (Russian Federation)

^b ICCOM CNR   (Italy)

Author keywords

Iridium; P ligands; Phosphorus; Rhodium; Structure elucidation

Indexed keywords

BIMETALS; IRIDIUM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RHODIUM;

BIMETALLIC REACTION PATHWAY; P LIGANDS; STRUCTURE ELUCIDATION;

PHOSPHORUS COMPOUNDS;

EID: 33746289067     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601048     Document Type: Article

References (42)

1. a) K. H. Whitmire, Adv. Organomet. Chem. 1998, 42, 1-145;
2. b) O. J. Scherer, Acc. Chem. Res. 1999, 32, 751-762;
3. c) M. Peruzzini, I. de los Rios, A. Romerosa, F. Vizza, Eur. J. Inorg. Chem. 2001, 593-608;
4. d) M. Ehses, A. Romerosa, M. Peruzzini, Top. Curr. Chem. 2002, 120, 107-140;
5. e) M. Peruzzini, R. R. Abdreimova, Y. Budnikova, A. Romerosa, O. J. Scherer, H. Sitzmann, J. Organomet. Chem. 2004, 689, 4319-4331;
6. f) M. Peruzzini, L. Gonsalvi, A. Romerosa, Chem. Soc. Rev. 2005, 34, 1038-1047.
7. a) P. Dapporto, S. Midollini, L. Sacconi, Angew. Chem. 1979, 91, 510;
8. Angew. Chem. Int. Ed. Engl. 1979, 18, 469-470;
9. b) T. Gröer, G. Baum, M. Scheer, Organometallics 1998, 17, 5916-5919;
10. c) M. Peruzzini, M. Marvelli, A. Romerosa, R. Rossi, F. Vizza, F. Zanobini, Eur. J. Inorg. Chem. 1999, 931-933;
11. d) I. de los Rios, J. R. Hamon, P. Hamon, C. Lapinte, L. Toupet, A. Romerosa, M. Peruzzini, Angew. Chem. 2001, 113, 4028-4030;
12. Angew. Chem. Int. Ed. 2001, 40, 3910-3911;
13. e) M. Di Vaira, S. Seniori Costantini, P. Stoppioni, P. Frediani, M. Peruzzini, Dalton Trans. 2005, 2234-2236.
14. M. Di Vaira, S. Seniori Costantini, P. Stoppioni, P. Frediani, M. Peruzzini, Book of abstracts, XXth IUCR Congress, Florence, Italy, 2005, C303-P.07.01.37.
15. a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739;
16. Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695;
17. b) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842;
18. c) O. J. Scherer, G. Schwarz, G. Wolmershäuser, Z. Anorg. Allg. Chem. 1996, 622, 951-957;
19. d) V. A. Miluykov, O. G. Sinyashin, P. Lönnecke, E. Hey-Hawkins, Mendeleev Commun. 2003, 212-213;
20. e) Y. Peng, H. Fan, H. Zhu, H. W. Roesky, J. Magull, C. E. Hughes, Angew. Chem. 2004, 116, 3525-3527;
21. Angew. Chem. Int. Ed. 2004, 43, 3443-3445.
22. a) E. Hey, M. F. Lappert, J. L. Atwood, S. G. Bott, J. Chem. Soc. Chem. Commun. 1987, 597-598;
23. b) P. J. Chirik, J. A. Pool, E. Lobkovsky, Angew. Chem. 2002, 114, 3613-3615;
24. Angew. Chem. Int. Ed. 2002, 41, 3463-3465;
25. c) A. R. Fox, R. J. Wright, E. Rivard, P. P. Power, Angew. Chem. 2005, 117, 7907-7911;
26. Angew. Chem. Int. Ed. 2005, 44, 7729-7733.
27. a) F. Cecconi, C. A. Ghilardi, S. Midollini, A. Orlandini, J. Am. Chem. Soc. 1984, 106, 3667-3668;
28. b) F. Cecconi, C. A. Ghilardi, S. Midollini, A. Orlandini, Inorg. Chem. 1986, 25, 1766-1770.
29. The preparations of 3-OTf and 4-OTf are detailed in the Supporting Information.
30. 2 = 0.1478 for 3610 reflections (I > 2σ(I)). CCDC-299453 contains the supplementary crystallographic data for 5-OTf. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
31. A similar structure has been ascertained by X-ray crystallography for the isomorphous iridium complex 6-OTf: triclinic, space group P1, a = 19.822(10), b = 12.113(6), c = 11.820(6) Å, α = 73.47(6), β = 108.26(9), γ = 103.14(9)°; A. Orlandini et al., unpublished results.
32. Chemical Society Special Publication No. 18, Chemical Society, London, 1965.
33. P. Barbara, A. Ienco, C. Mealli, M. Peruzzini, O. J. Scherer, G. Schmitt, F. Vizza, G. Wolmershäuser, Chem. Eur. J. 2003, 9, 5195-5210.
34. [5a]
35. The thermal lability of 5 and 6 does not allow to verify directly this mechanistic proposal. Studies on the corresponding dppm-Co system are in progress to confirm this hypothesis.
36. 2. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
37. 31P NMR spectrum as it transforms into 5 at a much faster rate than 7 transformed into 6 (ca. 1 hour at -40°C; immediately at room temperature).
38. F. H. Stephens, M. J. A. Johnson, C. C. Cummins, O. P. Kryatova, S. V. Kryatov, E. V. Rybak-Akimova, J. E. McDonough, C. D. Hoff, J. Am. Chem. Soc. 2005, 127, 15 191-15 200.
39. F. Studt, B. A. MacKay, S. A. Johnson, B. O. Patrick, M. D. Fryzuk, F. Tuczek, Chem. Eur. J. 2005, 11, 604-608, and references therein.
40. a) A. Schmidpeter, S. Lochshmidt, S. Sheldrick, Angew. Chem. 1985, 97, 214-215;
41. Angew. Chem. Int. Ed. Engl. 1985, 24, 226-227, and references therein;
42. b) J. P. Bezombes, P. B. Hitchcock, M. Lappert, J. E. Nycs, Dalton Trans. 2004, 499-501.