Dynamic behaviour of the [(triphos)Rh(η1:η2- P4RR′)]n+ complexes [triphos = MeC(CH 2PPh2)3; R = H, alkyl, aryl; R′ = lone pair, H, Me; n = 0, 1]: NMR and computational studies

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2008, Pages 1392-1399

  Barbaro, Pierluigi ^a   Caporali, Maria ^a   Ienco, Andrea ^a   Mealli, Carlo ^a   Peruzzini, Maurizio ^a   Vizza, Francesco ^a  

^a ICCOM CNR   (Italy)

Author keywords

Density functional calculations; Fluxionality; NMR spectroscopy; Phosphorus; Rhodium; Tripodal phosphane ligands

Indexed keywords

GROUND STATE; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS;

COMPUTATIONAL STUDIES; DENSITY-FUNCTIONAL CALCULATIONS; DYNAMIC BEHAVIORS; FLUXIONALITY; LONE PAIR; MULTINUCLEAR NMR; NMR STUDIES; NMR-SPECTROSCOPY; PHOSPHANE LIGANDS; TRIPODAL PHOSPHANE LIGAND;

DENSITY FUNCTIONAL THEORY;

EID: 49449112434     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701070     Document Type: Article

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