C(sp3)-H bond hydroxylation catalyzed by myoglobin reconstituted with manganese porphycene

Journal of the American Chemical Society

Volumn 135, Issue 46, 2013, Pages 17282-17285

  Oohora, Koji ^a   Kihira, Yushi ^a   Mizohata, Eiichi ^a   Inoue, Tsuyoshi ^a   Hayashi, Takashi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1-PHENYLETHANOL; CYTOCHROME P450; LINEAR RELATIONSHIPS; RATE DETERMINING STEP; REACTION MECHANISM; SPECTROSCOPIC TECHNIQUE; TURNOVER NUMBER; X RAY CRYSTAL STRUCTURES;

CATALYSIS; ETHANOL; ETHYLBENZENE; HYDROXYLATION; ISOTOPES; MANGANESE; PROTEINS; TOLUENE;

DRUG PRODUCTS;

1 PHENYLETHANOL; ALKANE; CARBON; CYCLOHEXANE; CYTOCHROME P450; ETHYLBENZENE; HEME; HISTONE; HYDROGEN; HYDROGEN PEROXIDE; ISOTOPE; MANGANESE DERIVATIVE; MYOGLOBIN; PORPHYRIN DERIVATIVE; TOLUENE; MANGANESE; METALLOPORPHYRIN; ORGANOMETALLIC COMPOUND;

ARTICLE; BINDING SITE; BIOCATALYST; CATALYSIS; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; ELECTROSPRAY MASS SPECTROMETRY; HYDROGEN BOND; HYDROXYLATION; ISOTOPE LABELING; PH; PROTEIN BINDING; PROTEIN MODIFICATION; PROTEIN STRUCTURE; REACTION ANALYSIS; SULFOXIDATION; TEMPERATURE; TURNOVER TIME; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY; BIOCATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; METABOLISM;

ALKANES; BIOCATALYSIS; CRYSTALLOGRAPHY, X-RAY; HYDROGEN PEROXIDE; HYDROXYLATION; MANGANESE; METALLOPORPHYRINS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; MYOGLOBIN; ORGANOMETALLIC COMPOUNDS;

EID: 84888351614     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja409404k     Document Type: Article

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