Sequential Norrish type II photoelimination and intramolecular aldol cyclization of α-diketones: Synthesis of polyhydroxylated cyclopentitols by ring contraction of hexopyranose carbohydrate derivatives

Chemistry - A European Journal

Volumn 19, Issue 31, 2013, Pages 10312-10333

  Alvarez Dorta, Dimitri ^a   León, Elisa I ^a   Kennedy, Alan R ^b   Martín, Angeles ^a   Pérez Martín, Inés ^a   Riesco Fagundo, Concepción ^a   Suárez, Ernesto ^a  

^a INSTITUTO DE PRODUCTOS NATURALES Y AGROBIOLOGÍA   (Spain)

^b UNIVERSITY OF STRATHCLYDE   (United Kingdom)

Author keywords

carbohydrates; cyclopentitols; diketones; photochemistry; ring contraction

Indexed keywords

CARBOHYDRATE DERIVATIVES; CYCLIZATION REACTIONS; CYCLOPENTITOLS; DEUTERIUM KINETIC ISOTOPE EFFECT; DIASTEREO-SELECTIVITY; DIKETONES; POLYHYDROXYLATED; RING CONTRACTION;

ATOMS; CARBOHYDRATES; CONDENSATION REACTIONS; CYCLIZATION; ISOTOPES; PHOTOCHEMICAL REACTIONS; STEREOSELECTIVITY;

KETONES;

3-HYDROXYBUTANAL; ALDEHYDE; ALDOL; CARBOHYDRATE; KETONE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; CYCLOPENTITOLS; DIKETONES; PHOTOCHEMISTRY; RING CONTRACTION; SYNTHESIS;

CARBOHYDRATES; CYCLOPENTITOLS; DIKETONES; PHOTOCHEMISTRY; RING CONTRACTION;

ALDEHYDES; CARBOHYDRATES; CYCLIZATION; KETONES; MOLECULAR STRUCTURE; PHOTOCHEMICAL PROCESSES;

EID: 84881381083     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201301230     Document Type: Article

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