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Volumn 135, Issue 25, 2013, Pages 9420-9432

Irreversibility and hysteresis in redox molecular conduction junctions

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONAL CHANGE; FAST TRANSPORT CHANNELS; HETEROGENEOUS ELECTRON TRANSFER; METAL-MOLECULE INTERFACE; MOLECULAR CONDUCTION; NEGATIVE DIFFERENTIAL RESISTANCES; NONLINEAR CHARGE TRANSPORTS; THERMODYNAMIC IRREVERSIBILITY;

EID: 84879513181     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401336u     Document Type: Article
Times cited : (81)

References (52)
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    • Chidsey, C. E. D. Science 1991, 251 (4996) 919-922
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    • Chidsey, C.E.D.1
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    • 0004278412 scopus 로고    scopus 로고
    • Oxford University Press: Oxford.
    • A similar formalism is used, although in a different context, in Zwanzig, R. Nonequilibrium Statistical Mechanics; Oxford University Press: Oxford, 2001.
    • (2001) Nonequilibrium Statistical Mechanics
    • Zwanzig, R.1
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    • 0344339180 scopus 로고    scopus 로고
    • Honeychurch, M. J. Langmuir 1999, 15 (15) 5158-5163
    • (1999) Langmuir , vol.15 , Issue.15 , pp. 5158-5163
    • Honeychurch, M.J.1
  • 39
    • 84961978964 scopus 로고    scopus 로고
    • 4), each characterized by correspondingly small coupling strengths to the contacts and large reorganization energy, then the transport is characterized by a hopping mechanism, and significant memory effects can be seen even if only two molecular states are involved in the transport over the spanned bias range. For example, with regard to azurin, the comparison between theory and experiment seems to disfavor the explanation of its transport properties based on a resonance tunneling mechanism: see Corni, S. J. Phys. Chem. B 2005, 109, 3423-3430
    • (2005) J. Phys. Chem. B , vol.109 , pp. 3423-3430
    • Corni, S.1
  • 43
    • 33750438788 scopus 로고    scopus 로고
    • As in the Marcus model, the same reorganization energy is assumed for the WX and XW transitions (X, W = A, B, C, D). In more general terms, it can be a reduced reorganization energy, as in: Zhu, J.; Wang, J.; Stell, G. J. Chem. Phys. 2006, 125, 164511 and references therein
    • (2006) J. Chem. Phys. , vol.125 , pp. 164511
    • Zhu, J.1    Wang, J.2    Stell, G.3


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