Effect of electron-transfer rate and reorganization energy on the cyclic voltammetric response of redox adsorbates

Langmuir

Volumn 15, Issue 15, 1999, Pages 5158-5163

  Honeychurch, Michael J ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; CHARGE TRANSFER; CYCLIC VOLTAMMETRY; FINITE DIFFERENCE METHOD; MATHEMATICAL MODELS; RATE CONSTANTS; REDOX REACTIONS;

BUTLER-VOLMER EQUATION; GURNEY-MARCUS-LEVICH-DOGONADZE (GMLD) EQUATION; NONADIABATIC KINETIC MODELS;

ADSORPTION;

EID: 0344339180     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la990169u     Document Type: Article

References (29)

1. Greef, R.; Peat, R.; Peter, L. M.; Pletcher, D.; Robinson, J. Instrumental Methods in Electrochemistry; Ellis Horwood Ltd.: Chichester, U.K., 1985.
2. Levich, V. G. Present State of the Theory of Oxidation - Reduction in Solution (Bulk and Electrode Reactions). In Advances in Electrochemistry and Electrochemical Engineering; Delahay, P., Ed.; John Wiley & Sons: New York, 1966; Vol. 4, pp 249-372.
3. Levich, V. G. Kinetics of Reactions with Charge Transport. In Physical Chemistry; an Advanced Treatise; Eyring, H., Ed.; Academic Press: New York, 1970; Vol. 9B, pp 985-1074.
4. Dogonadze, R. R. Theory of Molecular Electrode Kinetics. In Reactions of Molecules at Electrodes; Hush, N. S., Ed.; Wiley: New York, 1971; pp 135-227.
5. Marcus, R. A. J. Chem. Phys. 1956, 24, 966-978.
6. Marcus, R. A. J. Chem. Phys. 1965, 43, 679-701.
7. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265-322.
8. Gurney, R. W. Proc. R. Soc. 1931, A134, 137-154.
9. Bockris, J. O. M.; Khan, S. U. M. Surface Electrochemistry. A Molecular Level Approach; Plenum Press: New York, 1993.
10. Chidsey, C. D. Science 1991, 251, 919-922.
11. Weber, K.; Creager, S. E. Anal. Chem. 1994, 66, 3164-3172.
12. Tender, L.; Carter, M. T.; Murray, R. W. Anal. Chem. 1994, 66, 3173-3181.
13. Nahir, T. M.; Clark, R. A.; Bowden, E. F. Anal. Chem. 1994, 66, 2595-2598.
14. Honeychurch, M. J.; Rechnitz, G. A. Electroanalysis 1998, 10, 285-293.
15. Honeychurch, M. J.; Rechnitz, G. A. Electroanalysis 1998, 10, 453-457.
16. Laviron, E. J. Electroanal. Chem. 1979, 101, 19-28.
17. Schmickler, W. Interfacial Electrochemistry; Oxford University Press: Oxford, U.K., 1996.
18. max by diffusional cyclic voltammetry have been described in detail by Miller.
19. (b) Miller, C. J. Heterogeneous Electron Transfer Kinetics at Metallic Electrodes. In Physical Electrochemistry Principles, Methods, and Applications; Rubenstein, I., Ed.; Marcel Dekker: New York, 1995; pp 27-80.
20. (a) Honeychurch, M. J. Langmuir 1998, 14, 6291-6296.
21. (b) Assumption iv of ref 19a and refs 14 and 15 make reference to desorption being rapid. Since these references deal only with strongly adsorbed and chemisorbed molecules, rapid desorption is clearly in conflict with the model discussed; therefore, this statement should be disregarded.
22. Smith, C. P.; White, H. S. Anal. Chem. 1992, 64, 2398-2405.
23. Smith, C. P.; White, H. S. Langmuir 1993, 9, 1-3.
24. Fawcett, W. R. J. Electroanal. Chem. 1994, 378, 117-124.
25. Fawcett, W. R.; Fedurco, M.; Kovacova, Z. Langmuir 1994, 10, 2403-2408.
26. Andreu, R.; Fawcett, W. R. J. Phys. Chem. 1994, 98, 12753-12758.
27. Andreu, R.; Calvente, J. J.; Fawcett, W. R.; Molero, M. J. Phys. Chem. B 1997, 101, 2884-2894.
28. Andreu, R.; Calvente, J. J.; Fawcett, W. R.; Molero, M. Langmuir 1997, 13, 5189-5196.
29. Honeychurch, M. J. J. Electroanal. Chem. 1998, 445, 63-69.