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Volumn 42, Issue 25, 2013, Pages 9024-9029

Dual catalysis: New approaches for the polymerization of lactones and polar olefins

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC SYSTEM; CO-OPERATIVE EFFECTS; DUAL APPROACH; DUAL CATALYSIS; MODE OF ACTION; N-HETEROCYCLIC CARBENES; NEW APPROACHES; POLYMERIZATION CATALYSIS;

EID: 84878680137     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt00074e     Document Type: Article
Times cited : (51)

References (57)
  • 2
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    • 2/epoxide copolymerization, but usually the organic compound simply coordinates to the metal center and modulates thereby its reactivity. For recent reviews, see
    • Z. Shao H. Zhang Chem. Soc. Rev. 2009 38 2745
    • (2009) Chem. Soc. Rev. , vol.38 , pp. 2745
    • Shao, Z.1    Zhang, H.2
  • 5
    • 78650251149 scopus 로고    scopus 로고
    • For reviews on the ROP of lactones with metal-alkoxide initiators, see
    • D. J. Darensbourg Inorg. Chem. 2010 49 10765
    • (2010) Inorg. Chem. , vol.49 , pp. 10765
    • Darensbourg, D.J.1
  • 35
    • 0042693126 scopus 로고    scopus 로고
    • With transition metal mediated ROP, this is possible only if exchange between the active metal-alkoxide and free alcohol species proceeds faster than propagation (the alcohol behaves like a reversible chain transfer agent, as observed for "immortal" ROP processes). See for example
    • C. K. Williams L. E. Breyfogle S. K. Choi W. Nam V. G. Young Jr. M. A. Hillmyer W. B. Tolman J. Am. Chem. Soc. 2003 125 11350
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 11350
    • Williams, C.K.1    Breyfogle, L.E.2    Choi, S.K.3    Nam, W.4    Young, Jr.V.G.5    Hillmyer, M.A.6    Tolman, W.B.7
  • 55
    • 84863893868 scopus 로고    scopus 로고
    • The good results obtained with FLP in the polymerization of methacrylates have stimulated Chen to investigate conjugate-addition of such monomers using NHCs alone (in the absence of Lewis acid and initiator). Very promising results were obtained towards α-methylene γ-butyrolactones using It-Bu, see
    • Y. Zhang G. M. Miyake M. G. John L. Favilene L. Caporaso L. Cavallo E. Y.-X. Chen Dalton Trans. 2012 41 9119
    • (2012) Dalton Trans. , vol.41 , pp. 9119
    • Zhang, Y.1    Miyake, G.M.2    John, M.G.3    Favilene, L.4    Caporaso, L.5    Cavallo, L.6    Chen, E.Y.-X.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.