Computed CH acidity of biaryl compounds and their deprotonative metalation by using a mixed lithium/Zinc-TMP base

Chemistry - A European Journal

Volumn 19, Issue 24, 2013, Pages 7944-7960

  Kadiyala, Raghu Ram ^a   Tilly, David ^a   Nagaradja, Elisabeth ^a   Roisnel, Thierry ^a   Matulis, Vadim E ^b   Ivashkevich, Oleg A ^b   Halauko, Yury S ^c   Chevallier, Floris ^a   Gros, Philippe C ^d   Mongin, Florence ^a  

^a INSTITUT DES SCIENCES CHIMIQUES DE RENNES   (France)

^b BELARUSIAN STATE UNIVERSITY   (Belarus)

^c BELARUSIAN STATE UNIVERSITY   (Belarus)

^d UNIVERSITÉ DE LORRAINE   (France)

Author keywords

acidity; basicity; biaryls; density functional calculations; metalation

Indexed keywords

AROMATIC IODIDES; BIARYL COMPOUNDS; BIARYLS; KINETIC CONDITIONS; METALATIONS; PALLADIUM CATALYSIS; PALLADIUM-CATALYZED REACTIONS; SUZUKI COUPLINGS;

ACIDITY; ALKALINITY; CATALYSIS; DENSITY FUNCTIONAL THEORY; NAPHTHALENE; SUBSTRATES;

THERMOMECHANICAL PULPING PROCESS;

2,2,6,6 TETRAMETHYLPIPERIDIDE; 2,2,6,6-TETRAMETHYLPIPERIDIDE; AMIDE; HETEROCYCLIC COMPOUND; IODINATED HYDROCARBON; LITHIUM; PALLADIUM; PIPERIDINE DERIVATIVE; ZINC;

ARTICLE; CATALYSIS; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; COMBINATORIAL CHEMISTRY; KINETICS; SYNTHESIS;

AMIDES; CATALYSIS; COMBINATORIAL CHEMISTRY TECHNIQUES; HETEROCYCLIC COMPOUNDS; HYDROCARBONS, IODINATED; KINETICS; LITHIUM; MODELS, CHEMICAL; MOLECULAR STRUCTURE; PALLADIUM; PIPERIDINES; ZINC;

EID: 84878546292     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201300552     Document Type: Article

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