Synthesis and tribological behavior of ashless alkylphosphorofluoridothioates

Tribology International

Volumn 66, Issue , 2013, Pages 114-124

  Chen, Xin ^a   Elsenbaumer, Ronald L ^a   Aswath, Pranesh B ^a  

^a The University of Texas at Arlington   (United States)

Author keywords

Alkylphosphorofluoridothioate; Characterization; Synthesis; Wear

Indexed keywords

ALKYLPHOSPHOROFLUORIDOTHIOATE; ANTIWEAR PERFORMANCE; LONG ALKYL CHAINS; PHOSPHORUS LEVELS; TRIBOLOGICAL BEHAVIORS; TRIBOLOGICAL PERFORMANCE; XANES ANALYSIS; ZINC DIALKYLDITHIOPHOSPHATES;

CHARACTERIZATION; IRON COMPOUNDS; PHOSPHATES; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL); WEAR OF MATERIALS; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY; ZINC; ZINC SULFIDE;

TRIBOLOGY;

EID: 84878348961     PISSN: 0301679X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.triboint.2013.04.009     Document Type: Article

References (42)

1. Freuler, HC. Modified lubricating oil. US Patent 1994;2:823-364.
2. R.A. McDonald Zinc dithiophosphates L. Rudnick, Lubricant additives - chemistry and applications 2nd Edition 2009 CRC Press Chemical Industries, Boca Raton, FL 51 62
3. H.A. Spikes The history and mechanisms of ZDDP Tribology Letters 17 3 2004 469 489
4. M. Born, J.C. Hipeaux, P. Marchand, and G. Parc The relationship between chemical structure and effectiveness of some metallic dialkyl- and diaryl-dithiophosphates in different lubricated mechanisms Lubrication Science 4 2 1992 93 116 (Pubitemid 23594252)
5. F. Xie, J. Hu, F. Zheng, F. Ji, and J. Yao Anti-wear performance of organomolybdenum compounds as lubricant additives Lubrication Science 19 2 2007 81 85 (Pubitemid 46683580)
6. K.T. Miklozic, J. Graham, and H.A. Spikes Chemical and physical analysis of reaction films formed by molybdenum dialkyl-dithiocarbamate friction modifier additive using Raman and atomic force microscopy Tribology Letters 11 2 2001 71 81 (Pubitemid 33638430)
7. T. Ren, Q. Xue, and H. Wang The tribological properties of S-(1H-benzotriazol-1-yl)methyl alkyl xanthates as additives in synthetic lubricants Lubrication Engineering 51 10 1995 847 850
8. P. Njiwa, C. Minfray, T. Le Mogne, B. Vacher, J. Martin, and S. Matsui Zinc dialkyl phosphate (ZP) as an anti-wear additive: comparison with ZDDP Tribology Letters 44 1 2011 19 30
9. V.N. Bakunin, A.Y. Suslov, G.N. Kusmina, and O.P. Parenago Recent achievements in the synthesis and application of inorganic nanoparticles as lubricant components Lubrication Science 17 2 2005 127 145
10. 2 nanoparticles under mixed lubrication Wear 255 7-12 2003 785 793 (Pubitemid 37002322)
11. V.N. Bakunin, M. Kasrai, G.N. Kuzmina, G.M. Bancroft, and O.P. Parenago Influence of temperature and ZDDP concentration on tribochemistry of surface-capped molybdenum sulfide nanoparticles studied by XANES spectroscopy Tribology Letters 26 1 2007 33 43 (Pubitemid 46359409)
12. O Beeck, JW Givens, and AE. Smith On the mechanism of boundary Lubrication-I. The action of long chain polar compounds Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences 177 968 1940 90 102
13. O. Beeck, J.W. Givens, and E.C. Williams On the mechanism of boundary Lubrication-II. Wear prevention by addition agents Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences 177 968 1940 103 118
14. Beatty RP. Fluorinated lubricant additives. US Patent 2004;6:764-984.
15. K. Parekh, X. Chen, and P.B. Aswath Synthesis of fluorinated ZDDP compounds Tribology Letters 34 2 2009 141 153
16. R. Mourhatch, and P.B. Aswath Tribological behavior and nature of tribofilms generated from fluorinated ZDDP in comparison to ZDDP under extreme pressure conditions - Part 1: Structure and chemistry of tribofilms Tribology International 44 3 2011 187 200
17. R. Mourhatch, and P.B. Aswath Tribological behavior and nature of tribofilms generated from fluorinated ZDDP in comparison to ZDDP under extreme pressure conditions - Part 2: morphology and nanoscale properties of tribofilms Tribology International 44 3 2011 201 210
18. Parekh K, Aswath PB, Shaub H, Elsenbaumer RL. Low phosphorus lubricant additive. US Patent 2012;8:216-986.
19. K. Varlot, M. Kasrai, G.M. Bancroft, E.S. Yamaguchi, P.R. Ryason, and J. Igarashi X-ray absorption study of antiwear films generated from ZDDP and borate micelles Wear 249 12 2001 1029 1035
20. M. Kasrai, W.N. Lennard, R.W. Brunner, G.M. Bancroft, J.A. Bardwell, and K.H. Tan Sampling depth of total electron and fluorescence measurements in Si L- and K-edge absorption spectroscopy Applied Surface Science 99 4 1996 303 312 (Pubitemid 126363849)
21. M.L. Suominen Fuller, L. Rodriguez Fernandez, G.R. Massoumi, W.N. Lennard, M. Kasrai, and G.M. Bancroft The use of X-ray absorption spectroscopy for monitoring the thickness of antiwear films from ZDDP Tribology Letters 8 4 2000 187 192
22. M. Nicholls, M.N. Najman, Z. Zhang, M. Kasrai, P.R. Norton, and P.U.P.A. Gilbert The contribution of XANES spectroscopy to tribology Canadian Journal of Chemistry 85 10 2007 816 830 (Pubitemid 350119705)
23. M.A. Nicholls, P.R. Norton, G.M. Bancroft, M. Kasrai, T. Do, and B.H. Frazer Nanometer scale chemomechanical characterization of antiwear films Tribology Letters 17 2 2004 205 216 (Pubitemid 38870394)
24. H. Ji, M.A. Nicholls, P.R. Norton, M. Kasrai, T.W. Capehart, and T.A. Perry Zinc-dialkyl-dithiophosphate antiwear films: dependence on contact pressure and sliding speed Wear 258 5-6 2005 789 799
25. Z. Yin, M. Kasrai, M. Fuller, G.M. Bancroft, K. Fyfe, and K.H. Tan Application of soft X-ray absorption spectroscopy in chemical characterization of antiwear films generated by ZDDP Part I: the effects of physical parameters Wear 202 2 1997 172 191
26. B. Kim, R. Mourhatch, and P.B. Aswath Properties of tribofilms formed with ashless dithiophosphate and zinc dialkyl dithiophosphate under extreme pressure conditions Wear 268 3-4 2010 579 591
27. M. Fuller, Z. Yin, M. Kasrai, G.M. Bancroft, E.S. Yamaguchi, and P.R. Ryason Chemical characterization of tribochemical and thermal films generated from neutral and basic ZDDPs using X-ray absorption spectroscopy Tribology International 30 4 1997 305 315 (Pubitemid 127410162)
28. M.N. Najman, M. Kasrai, and G.M. Bancroft Chemistry of anti-wear films from ashless thiophosphate oil additives Tribology Letters 17 2 2004 217 229 (Pubitemid 38865469)
29. M.N. Najman, M. Kasrai, G.M. Bancroft, B.H. Frazer, and G. DeStatio The correlation of microchemical properties to antiwear (AW) performance in ashless thiophosphate oil additives Tribology Letters 17 4 2004 811 822
30. M.N. Najman, M. Kasrai, G.M. Bancroft, and A. Miller Study of the chemistry of films generated from phosphate ester additives on 52100 steel using X-ray absorption spectroscopy Tribology Letters 13 3 2002 209 218 (Pubitemid 41450906)
31. M.N. Najman, M. Kasrai, and G. Bancroft X-ray absorption spectroscopy and atomic force microscopy of films generated from organosulfur extreme-pressure (EP) oil additives Tribology Letters 14 4 2003 225 235 (Pubitemid 41450907)
32. W.T. Konieczko, A. Lopusinski, and J. Michalski Thionyl fluoride: a reagent for transformation of diorganyl phosphates and their structural analogs into the fluoridates Phosphorus, Sulfur and Silicon and the Related Elements 42 1-2 1989 103 104
33. Chen X, Aswath PB, Elsenbaumer RL. Alkylphosphorofluoridothioates having low wear volume and methods for synthesizing and using same. US Patent application published on December 29th, 2011; publication number: 2011/0319303; application number: 13/168478.
34. N.J. Mosey, M.H. Müser, and T.K. Woo Molecular mechanisms for the functionality of lubricant additives Science 307 5717 2005 1612 1615
35. J.M. Martin, C. Grossiord, T. Le Mogne, S. Bec, and A. Tonck The two-layer structure of Zndtp tribofilms: Part I: AES, XPS and XANES analyses Tribology International 34 8 2001 523 530
36. G. Pereira, D. Munoz-Paniagua, A. Lachenwitzer, M. Kasrai, P.R. Norton, and T.W. Capehart A variable temperature mechanical analysis of ZDDP-derived antiwear films formed on 52100 steel Wear 262 3-4 2007 461 470 (Pubitemid 46091682)
37. Y. Li, G. Pereira, A. Lachenwitzer, M. Kasrai, and P.R. Norton X-ray absorption spectroscopy and morphology study on antiwear films derived from ZDDP under different sliding frequencies Tribology Letters 27 3 2007 245 253 (Pubitemid 47123427)
38. D. Li, G.M. Bancroft, M. Kasrai, M.E. Fleet, X.H. Feng, and K. Tan S K-edge and L-edge X-ray-absorption spectroscopy of metal sulfides and sulfates - Applications in mineralogy and geochemistry The Canadian Mineralogist 33 5 1995 949 960
39. P.A. Willermet, D.P. Dailey, R.O. Carter III, P.J. Schmitz, W. Zhu, and J.C. Bell The composition of lubricant-derived surface layers formed in a lubricated cam/tappet contact, II. Effects of adding overbased detergent and dispersant to a simple ZDTP solution Tribology International 28 3 1995 163 175
40. G. Pereira, A. Lachenwitzer, D. Munoz-Paniagua, M. Kasrai, P.R. Norton, and M. Abrecht The role of the cation in antiwear films formed from ZDDP on 52100 steel Tribology Letters 23 2 2006 109 119 (Pubitemid 44458083)
41. G. Pereira, A. Lachenwitzer, M. Kasrai, G.M. Bancroft, P.R. Norton, and M. Abrecht Chemical and mechanical analysis of tribofilms from fully formulated oils Part 1 - Films on 52100 steel Tribology - Materials, Surfaces and Interfaces 1 2 2007 48 61
42. G. Nehme, R. Mourhatch, and P.B. Aswath Effect of contact load and lubricant volume on the properties of tribofilms formed under boundary lubrication in a fully formulated oil under extreme load conditions Wear 268 9-10 2010 1129 1147