Tribological behavior and nature of tribofilms generated from fluorinated ZDDP in comparison to ZDDP under extreme pressure conditionsPart II: Morphology and nanoscale properties of tribofilms

Tribology International

Volumn 44, Issue 3, 2011, Pages 201-210

  Mourhatch, Ramoun ^a   Aswath, Pranesh B ^a  

^a The University of Texas at Arlington   (United States)

Author keywords

Additive decomposition; Antiwear additives; Focused ion beam; Nano wear and nano indentation

Indexed keywords

ADDITIVE DECOMPOSITION; ANTIWEAR ADDITIVE; EXTREME PRESSURE; HIGHER LOADS; LOADING CONDITION; MECHANICAL STRENGTH; NANO-SCRATCH; NANOINDENTERS; NANOSCALE PROPERTIES; PENETRATION DEPTH; REDUCED ELASTIC MODULUS; TRIBOFILMS; TRIBOLOGICAL BEHAVIORS; ZINC DIALKYL DITHIOPHOSPHATE;

ADDITIVES; FOCUSED ION BEAMS; HARDNESS; NANOINDENTATION; VICKERS HARDNESS TESTING; WEAR RESISTANCE; ZINC;

TRIBOLOGY;

EID: 78650513275     PISSN: 0301679X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.triboint.2010.10.035     Document Type: Article

References (44)

1. P.A. Willermet, D.P. Dailey, R.O. Carter III, P.J. Schmitz, and W. Zhu Mechanism of formation of antiwear films from zinc dialkyldithiophosphates Tribol. Int. 28 1995 177 187
2. M. Kasrai, Z. Yin, M. Fuller, G.M. Bancroft, K. Fyfe, and K.H. Tan Application of XAFS in tribology: P and S L-edge XANES spectroscopy of antiwear films J Phys IV 7 1997 2 847
3. Z. Yin, M. Kasrai, G.M. Bancroft, K.F. Laycock, and K.H. Tan Chemical characterization of antiwear films generated on steel by zinc dialkyl dithiophosphate using X-ray absorption spectroscopy Tribol Int 26 1993 383 388
4. M. Fuller, Z. Yin, M. Kasrai, G.M. Bancroft, E.S. Yamaguchi, and P.R. Ryason Chemical characterization of tribochemical and thermal films generated from neutral and basic ZDDPs using X-ray absorption spectroscopy Tribol Int 30 1997 305 315 (Pubitemid 127410162)
5. H.A. Spikes The history and mechanisms of ZDDP Tribol Lett 17 2004 469 489
6. J.M. Martin, J.L. Mansot, I. Berbezier, and H. Dexpert The nature and origin of wear particles from boundary lubrication with a zinc dialkyl dithiophosphate Wear 93 1984 117 126
7. J.M. Martin, C. Grossiord, T. Le Mogne, S. Bec, and A. Tonck The two-layer structure of Zndtp tribofilms: Part I: AES, XPS and XANES analyses Tribol Int 34 2001 523 530
8. A.M. Barnes, K.D. Bartle, and VRA Thibon A review of zinc dialkyldithiophosphates (ZDDPS): characterisation and role in the lubricating oil Tribol Int 34 2001 389 395
9. G.C. Smith, and J.C. Bell Multi-technique surface analytical studies of automotive anti-wear films Appl Surf Sci 144-145 1999 222 227
10. R. Mourhatch, and P.B. Aswath Nanoscale properties of tribofilms formed with zinc dialkyl dithiophosphate (ZDDP) under extreme pressure condition J Nanosci Nanotechnol 9 2009 2682 2691
11. B.A. Khorramian, G.R. Iyer, S. Kodali, P. Natarajan, and R. Tupil Review of antiwear additives for crankcase oils Wear 169 1993 87 95
12. S.C. Tung, and M.L. McMillan Automotive tribology overview of current advances and challenges for the future Tribol Int 37 2004 517 536
13. T.H.C. Childs, and F. Sabbagh Boundary-lubricated wear of cast irons to simulate automotive piston ring wear rates Wear 134 1989 81 97
14. G. Nehme, R. Mourhatch, and P.B. Aswath Effect of contact load and lubricant volume on the properties of tribofilms formed under boundary lubrication in a fully formulated oil Wear 268 2010 1129 1147
15. Martin JM, Minfray C. Antiwear chemistry in presence of ZDDP, World Tribology Congress III, WTC 2005-63960, September 1216, 2005. Washington DC; 2005. p. 599600.
16. S.M. Hsu, and R.S. Gates Boundary lubricating films: formation and lubrication mechanism Tribol Int 38 2005 305 312
17. S. Bec, A. Tonck, J.M. Georges, R.C. Coy, J.C. Bell, and G.W. Roper Relationship between mechanical properties and structures of zinc dithiophosphate anti-wear films Proc R Soc London 455 4181 1999 4181 4203
18. M. Aktary, M.T. McDermott, and G.A. McAlpine Morphology and nanomechanical properties of zddp antiwear films as a function of tribological contact Tribol Lett 12 155 2002 155 162
19. M. Aktary, M.T. McDermott, and G. MacAlpine Morphology and nanoindentation profiles of automotive engine components Surf Eng 18 2002 70 74
20. S. Bec, A. Tonck, J.M. Georges, and G.W. Roper Synergistic effects of MoDTC and ZDTP on frictional behaviour of tribofilms at the nanometer scale Tribol Lett 17 797 2004 797 809
21. J. Ye, S. Araki, M. Kano, and Y. Yasuda Nanometer-scale mechanical/structure properties of molybdenum dithiocarbomate and zinc dialkylsithiophosphate tribofilms and friction reduction mechanism Jpn J Appl Phys Part 1 Regul Pap Short Note Rev Pap 44 2005 5358 5361
22. A. Somayaji, R. Mourhatch, and P.B. Aswath Nanoscale mechanical properties of in-situ tribofilms generated from ZDDP and F-ZDDP with and without antioxidants J Nanosci Nanotechnol 7 2007 4378 4390
23. M.A. Nicholls, T. Do, P.R. Norton, G.M. Bancroft, M. Kasrai, and T.W. Capehart Chemical and mechanical properties of ZDDP antiwear films on steel and thermal spray coatings studied by XANES spectroscopy and nanoindentation techniques Tribol Lett 15 241 2003 241 248
24. M.A. Nicholls, T. Do, P.R. Norton, M. Kasrai, and G.M. Bancroft Review of the lubrication of metallic surfaces by zinc dialkyl-dithiophosphates Tribol Int 38 2005 15 39
25. A.J. Pidduck, and G.C. Smith Scanning probe microscopy of automotive anti-wear films Wear 212 1997 254 264
26. H. Ji, M.A. Nicholls, P.R. Norton, M. Kasrai, T.W. Capehart, and T.A. Perry Zinc-dialkyl-dithiophosphate antiwear films: dependence on contact pressure and sliding speed Wear 258 2005 789 799
27. K. Topolovec-Miklozic, T.R. Forbus, and H.A. Spikes Film thickness and roughness of ZDDP antiwear films Tribol Lett 26 2007 161 171
28. Y. Li, G. Pereira, M. Kasrai, and P.R. Norton The effect of steel hardness on the performance of zddp antiwear films: a multi-technique approach Tribol Lett 29 2008 201 211
29. G. Pereira, D. Munoz-Paniagua, A. Lachenwitzer, M. Kasrai, P.R. Norton, and T.W. Capehart A variable temperature mechanical analysis of ZDDP-derived antiwear films formed on 52100 steel Wear 262 2007 461 470
30. L. Taylor, A. Dratva, and H. Spikes Friction and wear behavior of zinc dialkyldithiophosphate additive Tribol Trans 43 2000 469 479
31. B. Kim, R. Mourhatch, and P.B. Aswath Properties of tribofilms formed with ashless dithiophosphate and zinc dialkyl dithiophosphate under extreme pressure conditions Wear 268 34 2010 579 591
32. M.A. Nicholls, P.R. Norton, G.M. Bancroft, M. Kasrai, T. Do, and B.H. Frazer Nanometer scale chemomechanical characterization of antiwear films Tribol Lett 17 205 2004 205 216
33. K. Demmou, S. Bec, J.L. Loubet, and J.M. Martin Temperature effects on mechanical properties of zinc dithiophosphate tribofilms Tribol Int 39 1558 2006 1558 1563
34. Bec S, Demmou K, Loubet J, Pavan S, Minfray C, Martin J. Mechanical properties of ZnDTP tribofilms measured by nanoindentation at controlled temperature, World Tribology Congress III, WTC 2005064011, September 1216, 2005. Washington DC; 2005. p. 8234.
35. Mosey NJ, Woo TK, Mser MH. Mechanism of wear inhibition by ZDDP lubricant additivesinsights from molecular scale simulations In: American Chemical Society, Division of Petroleum Chemistry Symposium, Washington DC; 2005. vol. 50 (3), p. 3325.
36. Mosey NJ, Woo TK, Mser MH. Rational design of new anti-wear additives for engine lubricants through molecular simulation. In: American Chemical Society, Division of Petroleum Chemistry Symposium, Washington DC; 2005. vol. 50 (3), p. 2914.
37. N.J. Mosey, M.H. Mser, and T.K. Woo Molecular mechanisms of anti-wear pad formation and functionality of lubricant additives Science 307 1612 2005 1612 1615
38. N.J. Mosey, T.K. Woo, M. Kasrai, P.R. Norton, G.M. Bancroft, and M.H. Mser Interpretation of experiments on ZDDP anti-wear films through pressure-induced cross-linking Tribol Lett 24 105 2006 105 114
39. N. Mosey, M. Muser, and T. Woo Molecular mechanisms for the functionality of lubricant additives Science 307 2005 1612 1615
40. W. Nix, and H. Gao Indentation size effects in crystalline materials: a law for strain gradient plasticity J Mech Phys Solids 46 1998 411 425
41. J. Swadener, E. George, and G. Pharr The correlation of the indentation size effect measured with indenters of various shapes J Mech Phys Solids 50 2002 681 694
42. J. Greer, W. Oliver, and W. Nix Size dependence of mechanical properties of gold at the micron scale in the absence of strain gradients Acta Mater 53 2005 1821 1830
43. R. Mirshams, and R. Pothapragada Correlation of nanoindentation measurements of nickel made using geometrically different indenter tips Acta Mater 54 2006 1123 1134
44. H. Li, and R. Bradt The microhardness indentation load size effect in rutile and cassiterite single-crystals J Mater Sci 28 1993 917 926