Ion distributions at the water/1,2-dichloroethane interface: Potential of mean force approach to analyzing X-ray reflectivity and interfacial tension measurements

Journal of Physical Chemistry B

Volumn 117, Issue 17, 2013, Pages 5365-5378

  Hou, Binyang ^a   Laanait, Nouamane ^a   Yu, Hao ^a   Bu, Wei ^a   Yoon, Jaesung ^a   Lin, Binhua ^b   Meron, Mati ^b   Luo, Guangming ^c   Vanysek, Petr ^d   Schlossman, Mark L ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

^b UNIVERSITY OF CHICAGO   (United States)

^c INSTITUTE OF HIGH ENERGY PHYSICS   (China)

^d NORTHERN ILLINOIS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CESIUM; CESIUM ALLOYS; CHLORINE COMPOUNDS; ELECTRIC POTENTIAL; HYDRATION; LITHIUM; METAL IONS; X RAYS;

ELECTRIC POTENTIAL DIFFERENCE; IMMISCIBLE ELECTROLYTE SOLUTIONS; LIQUID/LIQUID INTERFACE; POTENTIAL OF MEAN FORCE; POTENTIALS OF MEAN FORCES; THERMODYNAMIC STUDIES; UNDERLYING DISTRIBUTION; X-RAY REFLECTIVITY MEASUREMENTS;

POISSON DISTRIBUTION;

EID: 84877061131     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp401892y     Document Type: Article

References (90)

1. Volkov, A. G.; Deamer, D. W. Liquid-Liquid Interfaces: Theory and Methods; CRC: Boca Raton, FL, 1996.
2. Volkov, A. G. Liquid Interfaces in Chemical, Biological, and Pharmaceutical Applications; Marcel Dekker: New York, 2001.
3. Interfacial Nanochemistry: Molecular Science and Engineering at Liquid-Liquid Interfaces; Watarai, H., Teramae, N., Sawada, T., Eds.; Kluwer Academic: New York, 2005.
4. Girault, H. H. Analytical and Physical Electrochemistry; EPFL Press: Lausanne, Switzerland, 2004.
5. Bedzyk, M. J.; Bommarito, G. M.; Caffrey, M.; Penner, T. L. Diffuse-Double Layer at a Membrane-Aqueous Interface Measured with X-ray Standing Waves Science 1990, 248, 52-56
6. Cuvillier, N.; Rondelez, F. Breakdown of the Poisson-Boltzmann Description for Electrical Double Layers Involving Large Multivalent Ions Thin Solid Films 1998, 327-329, 19-23
7. Vaknin, D.; Kruger, P.; Losche, M. Anomalous X-ray Reflectivity Characterization of Ion Distribution at Biomimetic Membranes Phys. Rev. Lett. 2003, 90, 178102-1-178102-4
8. Das, R.; Mills, T. T.; Kwok, L. W.; Maskel, G. S.; Millett, I. S.; Doniach, S.; Finkelstein, K. D.; Herschlag, D.; Pollack, L. Counterion Distribution around DNA Probed by Solution X-ray Scattering Phys. Rev. Lett. 2003, 90, 188103-1-188103-4
9. Andresen, K.; Das, R.; Park, H. Y.; Smith, H.; Kwok, L. W.; Lamb, J. S.; Kirkland, E. J.; Herschlag, D.; Finkelstein, K. D.; Pollack, L. Spatial Distribution of Competing Ions around DNA in Solution Phys. Rev. Lett. 2004, 93, 248103-1-248103-4
10. Bu, W.; Vaknin, D.; Travesset, A. Monovalent Counterion Distributions at Highly Charged Water Interfaces: Proton-Transfer and Poisson-Boltzmann Theory Phys. Rev. E 2005, 72, 060501-1-060501-4
11. Bu, W.; Vaknin, D.; Travesset, A. How Accurate is Poisson-Boltzmann Theory for Monovalent Ions near Highly Charged Interfaces? Langmuir 2006, 22, 5673-5681
12. Luo, G.; Malkova, S.; Yoon, J.; Schultz, D. G.; Lin, B.; Meron, M.; Benjamin, I.; Vanysek, P.; Schlossman, M. L. Ion Distributions Near a Liquid-Liquid Interface Science 2006, 311, 216-218
13. Luo, G.; Malkova, S.; Yoon, J.; Schultz, D. G.; Lin, B.; Meron, M.; Benjamin, I.; Vanysek, P.; Schlossman, M. L. Ion Distributions at the Nitrobenzene-Water Interface Electrified by a Common Ion J. Electroanal. Chem. 2006, 593, 142-158
14. Shapovalov, V. L.; Brezesinski, G. Breakdown of the Gouy-Chapman Model for Highly Charged Langmuir Monolayers: Counterion Size Effect J. Phys. Chem. B 2006, 110, 10032-10040
15. Padmanabhan, V.; Daillant, J.; Belloni, L.; Mora, S.; Alba, M.; Konovalov, O. Specific Ion Adsorption and Short-Range Interactions at the Air Aqueous Solution Interface Phys. Rev. Lett. 2007, 99, 086105-1-086105-4
16. Shapovalov, V. L.; Ryskin, M. E.; Konovalov, O. V.; Hermelink, A.; Brezesinski, G. Elemental Analysis within the Electrical Double Layer Using Total Reflection X-ray Fluorescence Technique J. Phys. Chem. B 2007, 111, 3927-3934
17. Sloutskin, E.; Baumert, J.; Ocko, B. M.; Kuzmenko, I.; Checco, A.; Tamam, L.; Ofer, E.; Gog, T.; Gang, O.; Deutsch, M. The Surface Structure of Concentrated Aqueous Salt Solutions J. Chem. Phys. 2007, 126, 054704-1-054704-10
18. Mezger, M.; Schroder, H.; Reichert, H.; Schramm, S.; Okasinski, J. S.; Schoder, S.; Honkimaki, V.; Deutsch, M.; Ocko, B. M.; Ralston, J. Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface Science 2008, 322, 424-428
19. Bu, W.; Vaknin, D. X-ray Fluorescence Spectroscopy from Ions at Charged Vapor/Water Interfaces J. Appl. Phys. 2009, 105, 084911-1-084911-6
20. Bu, W.; Flores, K.; Pleasants, J.; Vaknin, D. Preferential Affinity of Calcium Ions to Charged Phosphatidic Acid Surface from a Mixed Calcium/Barium Solution: X-ray Reflectivity and Fluorescence Studies Langmuir 2009, 25, 1068-1073
21. Nishi, N.; Yasui, Y.; Uruga, T.; Tanida, H.; Yamada, T.; Nakayama, S.; Matsuoka, H.; Kakiuchi, T. Ionic Multilayers at the Free Surface of an Ionic Liquid, Trioctylmethylammonium Bis(Nonafluorobutanesulfonyl)Amide, Probed by X-ray Reflectivity Measurements J. Chem. Phys. 2010, 132, 164705-1-164705-6
22. Elsen, A.; Murphy, B. M.; Ocko, B. M.; Tamam, L.; Deutsch, M.; Kuzmenko, I.; Magnussen, O. M. Surface Layering at the Mercury-Electrolyte Interface Phys. Rev. Lett. 2010, 104, 105501-1-105501-4
23. Laanait, N.; Yoon, J.; Hou, B.; Vanysek, P.; Meron, M.; Lin, B.; Luo, G.; Benjamin, I.; Schlossman, M. L. Monovalent Ion Condensation at the Electrified Liquid/Liquid Interface J. Chem. Phys. 2010, 132, 171101-1-171101-4
24. 3+ Langmuir 2011, 27, 11917-11924
25. Duval, J. F. L.; Bera, S.; Michot, L. J.; Daillant, J.; Belloni, L.; Konovalov, O.; Pontoni, D. X-ray Reflectivity at Polarized Liquid-Hg-Aqueous- Electrolyte Interface: Challenging Macroscopic Approaches for Ion-Specificity Issues Phys. Rev. Lett. 2012, 108, 206102-1-206102-5
26. Laanait, N.; Mihaylov, M.; Hou, B.; Yu, H.; Vanysek, P.; Meron, M.; Lin, B.; Benjamin, I.; Schlossman, M. L. Tuning Ion Correlations at an Electrified Soft Interface Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 20326-20331
27. The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids; Kazarinov, V. E., Ed.; Springer: Berlin, 1987.
28. Thermodynamics and Electrified Interfaces; Gileadi, E.; Urbakh, M., Eds.; Wiley-VCH: Weinheim, Germany, 2002; Vol. 1.
29. Samec, Z. Electrochemistry at the Interface between Two Immiscible Electrolyte Solutions Pure Appl. Chem. 2004, 76, 2147-2180
30. Vanysek, P. Electrochemistry on Liquid/Liquid Interfaces; Springer-Verlag: Berlin, 1985; Vol. 39.
31. Zhurov, K.; Dickson, E. J. F.; Compton, G. Dynamics of Ion Transfer Potentials at Liquid-Liquid Interfaces J. Phys. Chem. B 2011, 115, 6909-6921
32. Hung, L. Q. Electrochemical Properties of the Interface between 2 Immiscible Electrolyte-Solutions 1. Equilibrium Situation and Galvani Potential Difference J. Electroanal. Chem. 1980, 115, 159-174
33. Vanysek, P.; Zheng, C. Triphenyl[(triphenylphosphoranylidene)-amino] phosphonium tetrakis(pentafluorophenyl)borate Acta Crystallogr. 2013, E69, o87
34. Gouy, G. Constitution of the Electric Charge at the Surface of an Electrolyte J. Phys. (Paris) 1910, 9, 457-467
35. Chapman, D. L. A Contribution to the Theory of Electrocapillarity Philos. Mag. 1913, 25, 475-481
36. Kirkwood, J. G. On the Theory of Strong Electrolyte Solutions J. Chem. Phys. 1934, 2, 767-781
37. Rouzina, I.; Bloomfield, V. A. Macroion Attraction due to Electrostatic Correlation between Screening Counterions. 1. Mobile Surface-Adsorbed Ions and Diffuse Ion Cloud J. Phys. Chem. 1996, 100, 9977-9989
38. Shklovskii, B. I. Wigner Crystal Model of Counterion Induced Bundle Formation of Rodlike Polyelectrolytes Phys. Rev. Lett. 1999, 82, 3268-3271
39. Daikhin, L. I.; Kornyshev, A. A.; Urbakh, M. Ion Penetration into an 'Unfriendly Medium' and the Double Layer Capacitance of the Interface Between Two Immiscible Electrolytes J. Electroanal. Chem. 2001, 500, 461-470
40. Bostrom, M.; Williams, D. R. M.; Ninham, B. W. Specific Ion Effects: Why DLVO Theory Fails for Biology and Colloid Systems Phys. Rev. Lett. 2001, 87, 168103-1-168103-4
41. Levin, Y. Electrostatic Correlations: From Plasma to Biology Rep. Prog. Phys. 2002, 65, 1577-1632
42. Netz, R. R.; Horinek, D. Progress in Modeling of Ion Effects at the Vapor/Water Interface Annu. Rev. Phys. Chem. 2012, 63, 401-418
43. Benjamin, I. Reactivity and Dynamics at Liquid Interfaces. In Rev. Comput. Chem.; Lipkowitz, K. B., Ed. John Wiley & Sons: Hoboken, NJ, 2013, Vol. 28.
44. Bier, M.; Zwanikken, J.; van Roij, R. Liquid-Liquid Interfacial Tension of Electrolyte Solutions Phys. Rev. Lett. 2008, 101, 046104-1-046104-4
45. Onuki, A. Surface Tension of Electrolytes: Hydrophilic and Hydrophobic Ions near an Interface J. Chem. Phys. 2008, 128, 224704-1-224704-9
46. Kung, W.; Solis, F. J.; de la Cruz, M. O. Thermodynamics of Ternary Electrolytes: Enhanced Adsorption of Macroions as Minority Component to Liquid Interfaces J. Chem. Phys. 2009, 130, 044502-1-044502-7
47. Wang, R.; Wang, Z.-G. Effects of Ion Solvation on Phase Equilibrium and Interfacial Tension of Liquid Mixtures J. Chem. Phys. 2011, 135, 014707-1-014707-11
48. Girault, H. H.; Schiffrin, D. H. Thermodynamic Surface Excess of Water and Ionic Solvation at the Interface Between Immiscible Liquids J. Electroanal. Chem. 1983, 150, 43-49
49. Homolka, D.; Hajkova, P.; Marecek, V.; Samec, Z. The Double Layer at the Interface between Two Immiscible Electrolyte Solutions: Structure of the Water/Nitrobenzene Interface J. Electroanal. Chem. 1983, 159, 233-238
50. Yufei, C.; Cunnane, V. J.; Schiffrin, D. J.; Murtomaki, L.; Kontturi, K. Interfacial Capacitance and Ionic Association at Electrified Liquid/Liquid Interfaces J. Chem. Soc., Faraday Trans. 1991, 87, 107-114
51. Girault, H. H. Charge Transfer across Liquid-Liquid Interfaces. In Modern Aspects of Electrochemistry; Bockris, J. O. M., Ed.; Plenum Press: New York, 1993; Vol. 25, pp 1-62.
52. Pereira, C. M.; Martins, A.; Rocha, M.; Silva, C. J.; Silva, F. Differential Capacitance of Liquid/Liquid Interfaces: Effect of Electrolytes Present in each Phase J. Chem. Soc., Faraday Trans. 1994, 90, 143-148
53. Pereira, C. M.; Schmickler, W.; Silva, A. F.; Sousa, M. J. On the Capacity of Liquid-Liquid Interfaces Chem. Phys. Lett. 1997, 268, 13-20
54. Pereira, C. M.; Schmickler, W.; Silva, F.; Sousa, M. J. Ion Association at Liquid/Liquid Interfaces J. Electroanal. Chem. 1997, 436, 9-15
55. Zhang, Y. J.; Cremer, P. S. Chemistry of Hofmeister Anions and Osmolytes Annu. Rev. Phys. Chem. 2010, 61, 63-83
56. Pershan, P. S.; Schlossman, M. L. Liquid Surfaces and Interfaces: Synchrotron X-ray Methods; Cambridge University Press: Cambridge, U.K., 2012.
57. Horinek, D.; Netz, R. R. Specific Ion Adsorption at Hydrophobic Solid Surfaces Phys. Rev. Lett. 2007, 99, 226104-1-226104-4
58. Backes, H. M.; Ma, J. J.; Bender, E.; Maurer, G. Interfacial Tensions in Binary and Ternary Liquid-Liquid Systems Chem. Eng. Sci. 1990, 45, 275-286
59. Fermin, D. J.; Ding, Z.; Duong, H.; Girault, H. H. Photoinduced Electron Transfer at Liquid/Liquid Interfaces. 1. Photocurrent Measurements Associated with Heterogeneous Quenching of Zinc Porphyrins J. Phys. Chem. B 1998, 102, 10334-10341
60. Hou, B. Ion Distributions at Electrified Liquid-Liquid Interfaces: Microscopic and Macroscopic Measurements. Ph.D. Thesis, University of Illlinois at Chicago, 2011.
61. Laanait, N. Ion Correlations at Electrified Soft Matter Interfaces. Ph.D. Thesis, University of Illinois at Chicago, 2011.
62. Girault, H. H. J.; Schiffrin, D. J. A New Approach for the Definition of Galvani Potential Scales and Ionic Gibbs Energies of Transfer across Liquid-Liquid Interfaces Electrochim. Acta 1986, 31, 1341-1342
63. Adamson, A. W. Physical Chemistry of Surfaces, 5 th ed.; John Wiley & Sons: New York, 1990.
64. Mitrinovic, D. M.; Tikhonov, A. M.; Li, M.; Huang, Z.; Schlossman, M. L. Noncapillary-Wave Structure at the Water-Alkane Interface Phys. Rev. Lett. 2000, 85, 582-585
65. Luo, G.; Malkova, S.; Pingali, S. V.; Schultz, D. G.; Lin, B.; Meron, M.; Graber, T.; Gebhardt, J.; Vanysek, P.; Schlossman, M. L. The Width of the Water/2-Heptanone Liquid-Liquid Interface Electrochem. Commun. 2005, 7, 627-630
66. Luo, G.; Malkova, S.; Pingali, S. V.; Schultz, D. G.; Lin, B.; Meron, M.; Benjamin, I.; Vanysek, P.; Schlossman, M. L. Structure of the Interface between Two Polar Liquids: Nitrobenzene and Water J. Phys. Chem. B 2006, 110, 4527-4530
67. Demond, A. H.; Lindner, A. S. Estimation of Interfacial Tension between Organic Liquids and Water Environ. Sci. Technol. 1993, 27, 2318-2331
68. Goebel, A.; Lunkenheimer, K. Interfacial Tension of the Water/N-Alkane Interface Langmuir 1997, 13, 369-372
69. Freitas, A. A.; Quina, F. H.; Carroll, F. A. Estimation of Water-Organic Interfacial Tensions. A Linear Free Energy Relationship Analysis of Interfacial Adhesion J. Phys. Chem. B 1997, 101, 7488-7493
70. 2OH at the Water-(Hexane Solution) and Water-Vapor Interfaces J. Chem. Phys. 1999, 110, 7421-7432
71. 137Cs J. Phys. Chem. B 2006, 110, 8432-8440
72. Vanysek, P.; Novák, V. Liquid/Liquid Electrochemistry in Electroanalysis: Fundamentals Revisited ECS Trans. 2009, 19, 55-63
73. Pawar, V. P. Dielectric Relaxation of Propan-1-ol With Chlorobenzene, 1,2-Dichloroethane, and Dimethylene Chloride at (288, 298, 308, and 318) K Using Time-Domain Reflectometry Technique J. Chem. Eng. Data 2006, 51, 882-885
74. Burley, D. M.; Hutson, V. C. L.; Outhwaite, C. W. Calculation of the Thermodynamic Properties of Electrolyte Solutions Using a Modified Poisson-Boltzmann Equation Mol. Phys. 1972, 23, 867-886
75. Outhwaite, C. W.; Bhuiyan, L. B.; Levine, S. Theory of the Electric Double Layer Using a Modified Poisson-Boltzmann Equation J. Chem. Soc., Faraday Trans. 2 1980, 76, 1388-1408
76. Wick, C. D.; Dang, L. X. Molecular Dynamics Study of Ion Transfer and Distribution at the Interface of Water and 1,2-Dichloroethane J. Phys. Chem. C 2008, 112, 647-649
77. Rowlinson, J. S.; Widom, B. Molecular Theory of Capillarity; Clarendon Press: Oxford, U.K., 1982.
78. Buff, F. P.; Lovett, R. A.; Stillinger, F. H. Interfacial Density Profile for Fluids in the Critical Region Phys. Rev. Lett. 1965, 15, 621-623
79. Marcus, Y. Ionic Radii in Aqueous Solutions Chem. Rev. 1988, 88, 1475-1498
80. Jmol: an open-source Java viewer for chemical structures in 3D, http://www.jmol.org/.
81. Connolly, M. Analytical Molecular Surface Calculation J. Appl. Crystallogr. 1983, 16, 548-558
82. Parratt, L. G. Surface Studies of Solids by Total Reflection of X-Rays Phys. Rev. 1954, 95, 359-369
83. Fogden, A.; Mitchell, D. J.; Ninham, B. W. Undulations of Charged Membranes Langmuir 1990, 6, 159-162
84. Trojanek, A.; Lhotsky, A.; Marecek, V.; Samec, Z. Limited Agreement Between the Interfacial Tension and Differential Capacity Data for the Polarised Water|1,2-Dichloroethane Interface J. Electroanal. Chem. 2004, 565, 243-250
85. Lhotsky, A.; Marecek, V.; Zalis, S.; Samec, Z. Specific Adsorption of Tetraalkylammonium Cations at the Water|1,2-Dichloroethane Interface Revisited J. Electroanal. Chem. 2005, 585, 269-274
86. Lippmann, G. Relations Entre les Phenoménes électriques et Capillaires Ann. Chim. Phys 1875, 5, 494-549
87. Burgess, M. A. Metal Ions in Solution; Ellis Horwood: Chichester, England, 1978.
88. Kakiuchi, T.; Senda, M. Structure of the Electrical Double Layer at the Interface between Nitrobenzene Solution of Tetrabutylammonium Tetraphenylborate and Aqueous Solution of Lithium Chloride Bull. Chem. Soc. Jpn. 1983, 56, 1753-1760
89. Samec, Z.; Trojanek, A.; Langmaier, J. Origin of the Effect of Ion Nature on the Differential Capacity of an Interface between Two Immiscible Electrolyte Solutions J. Electroanal. Chem. 1998, 444, 1-5
90. Samec, Z.; Lhotsky, A.; Janchenova, H.; Marecek, V. Interfacial Tension and Impedance Measurements of Interfaces between Two Immiscible Electrolyte Solutions J. Electroanal. Chem. 2000, 483, 47-56