Gibbs energies of transfer of Alkali metal cations between mutually saturated water-solvent systems determined from extraction experiments with radiotracer137Cs

Journal of Physical Chemistry B

Volumn 110, Issue 16, 2006, Pages 8432-8440

  Rais, Jiří ^a   Okada, Tatsuhiro ^b   Alexova J ^a  

^a NUCLEAR RESEARCH INSTITUTE   (Czech Republic)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

GIBBS FREE ENERGY; HYDRATION; ORGANIC SOLVENTS; POSITIVE IONS; SATURATION (MATERIALS COMPOSITION);

ALKALI METAL CATIONS; LIQUID-LIQUID EXTRACTION METHOD; RADIOACTIVE TRACING;

ALKALI METALS;

EID: 33646441010     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp060318z     Document Type: Article

References (59)

1. Rais, J.; Selucký, P.; Kyrš, M. J. Inorg. Nucl. Chem. 1976, 38, 1376.
2. Samec, Z. Pure Appl. Chem. 2004, 76, 2147.
3. Bakker, E.; Bühlman, P.; Pretsch, E. Talanta 2004, 63, 2004.
4. Schamberger, J.; Clarke, R. J. Biophys. J. 2002, 82, 2002.
5. Marcus, Y. Ion Properties; Marcel Dekker: New York, 1997;
6. Electrochim. Acta 1998, 44, 91.
7. Baes, C. F., Jr.; Moyer, B. A. J. Phys. Chem. B 1997, 101, 6566.
8. Fawcett, W. R. Mol. Phys. 1998, 95, 507.
9. Moyer, B. A.; Sun, Y. In Ion Exchange and Solvent Extraction; Marinsky, J. A., Marcus, Y., Eds.; Marcel Dekker: New York, 1997; Vol. 13.
10. Abraham, M. H.; Zhao, Y. H. J. Org. Chem. 2004, 69, 4677. Interestingly, this same author (M.H.A.) some 25 years ago developed a model based on a modified two-layer Born model
11. (J. Chem. Soc., Faraday Trans. 1, 1978, 74, 1604, 2858), from which a newer model of ref 8 evolved.
12. Zhao, Y. H.; Abraham, M. H. J. Org. Chem. 2005, 70, 2633.
13. Gritzner, G. Electrochim. Acta 1998, 44, 73.
14. Rais, J.; Okada, T. J. Phys. Chem. A 2000, 104, 7314.
15. Rais, J. In Ion Exchange and Solvent Extraction; Marcus, Y., SenGupta, A. K., Eds.; Marcel Dekker: New York, 2004; Vol. 17.
16. Rais, J.; Selucký, P.; Kyrš, M. J. Inorg. Nucl. Chem. 1976, 38, 1376.
17. Rais, J.; Selucký, P.; Kyrš, M.; Kadlecová, L. J. Radioanal. Nucl. Chem. 1993, 27, 1347.
18. Ohde, H.; Uehara, A.; Yoshida, Y.; Maeda, K.; Kihara, S. J. Electroanal. Chem. 2001, 496, 110.
19. Ulmeanu, S. M.; Jensen, H.; Samec, Z.; Bouchard, G.; Carrupt, P. A.; Girault, H. H. J. Electroanal. Chem. 2002, 530, 10.
20. Rais, J.; Grüner, B. In Ion Exchange and Solvent Extraction; Marcus, Y., SenGupta, A. K., Eds.; Marcel Dekker: New York, 2004; Vol. 17.
21. Rais, J.; Šístková, N.; Alexová, J. unpublished results.
22. Winget, P.; Dolney, D. M.; Giesen, D. J.; Cramer, C. H.; Truhlar, D. G. Minnesota Solvent Descriptor Database, http://comp.chem.umn.edu/ solvation/mnsddb.pdf (last accessed Dec 2005).
23. IUPAC - NIST Solubility Database NIST Standard Reference Database 106, online ed. http://srdata.nist.gov/solubility/ sol_detail.asp?sys_ID=77_136 (last accessed Dec 2005).
24. Samec, Z.; Langmaier, J.; Trojánek, A. J. Electroanal. Chem. 1996, 409, 1.
25. Langmaier, J.; Stejskalová, K.; Samec, Z. J. Electroanal. Chem. 2001, 496, 143.
26. Rais J.; Mason C. V.; Abney K. D. Sep. Sci. Technology, 1997, 32, 951.
27. Chrisstoffels, L. A. J.; de Jong, F.; Reinhoudt, D. N. Chem. - Eur. J. 2000, 6, 1376.
28. Girault, H. H. Electrochemical Online Database, http:// serveur-isic.epfl.ch/labo/girault/cgi/DB/InterrDB.pl (last accessed December 2005).
29. Sakaki, T.; Harada, T.; Kawahara, Y.; Shinkai, S. J. Inclusion Phenom. 1994, 17, 377.
30. Levitskaia, T. G.; Macdonald, D. M.; Lamb, J. D.; Moyer, B. A. Phys. Chem. Chem. Phys. 2000, 2, 1481.
31. Haugen, G. R.; Friedman, H. L. J. Phys. Chem. 1968, 72, 4549.
32. Selucký, P.; Rais, J.; Krtil, J. International Solvent Extraction Conference; The Hague, 1971; paper 79, p 14.
33. Abboud, J. L. M.; Notario, R. Pure Appl. Chem. 1999, 71, 645.
34. IUPAC - NIST Solubility Database NIST Standard Reference Database 106, online edition, http://srdata.nist.gov/solubility/ sol_detail.asp?sys_ID=77_146, http://srdata.nist.gov/solubility/ sol_detail.asp?sys_ID=77_1, respectively (last accessed Dec 2005).
35. Marcus, Y. Ion Solvation: John Wiley: Chichester, 1985.
36. 2): vacuum, 0.1751, -45.18, 1; pure NM, 0.0395, -10.30, 0.9993; NB, 0.0281, -7.21, 0.9989; NPOE, 0.0256, -6.60, 1; 1-NP, 0.0247, -6.38, 0.9999; NM, 0.0193, -4.92, 0.9971.
37. Selucký, P.; Rais, J.; Kyrš, M.; Kadlecová, L. J. Radioanal. Nucl. Chem. 1991, 148, 227.
38. - is under the experimental conditions fully dissociated in water-saturated 1,2-DClE.
39. + 2 kJ/mol in ref 5, which is largely an outlier value (based according to the references in ref 5 on two older papers: Kihara, S.; Suzuki, M.; Maeda, K.; Ogura, K.; Umetani, S.; Matsui, M.; Yoshida, Z. Anal. Chem. 1986, 55, 2954
40. and Kihara, S.; Suzuki, M.; Maeda, K.; Ogura, K.; Matsui, M. J. Electroanal. Chem. 1986, 210, 147).
41. +/37. This seems to be a typographical error for alkali metal cations in the latter publication. The former values well agree with the original paper denoted as f in Table 3.
42. Sabela, A.; Mareček V.; Samec, Z.; Fuoco, R. Electrochim. Acta 1992, 37, 231.
43. Samec, Z.; Mareček, V.; Colombini, M. P. J. Electroanal. Chem. 1988, 257, 147.
44. Yoshida, Y.; Kihara, S. Bunseki Kagaku 2002, 51, 1103.
45. Zhan, D.; Xiao, Y.; Yuan, Y.; He, Y.; Wua, B.; Shao, Y. J. Electroanal. Chem. 2003, 555, 43.
46. Shao, Y.; Stewart, A. A.; Girault, H. H. J. Chem. Soc., Faraday Trans. 1991, 87, 2593.
47. Yoshida, Y.; Matsuia, M.; Shirai, O.; Maeda, K.; Kihara, S. Anal. Chim. Acta 1998, 373, 213.
48. Abraham, M. H.; Danil de Namor, A. F. J. Chem. Soc., Faraday Trans. 1 1976, 72, 955-962.
49. Kontturi, A. K.; Kontturi, K.; Manzanares, J. A.; Mafe, S.; Murtomäi, L. Ber. Bunsen-Ges. Phys. Chem. 1995, 99, 1131.
50. 2): 0.048, -12.566, 0.9984. See note 33 for comparison.
51. Sassi, P.; Paolantoni, M.; Cataliotti, R. S.; Palombo, F.; Morresi, A. J. Phys. Chem. B 2004, 108, 19557.
52. Margolis, S. A.; Levenson, M. Fresenius' J. Anal. Chem. 2000, 367, 1.
53. Bouchard, G.; Galland, A.; Carrupt, P.-A.; Gulaboski, R.; Mirčeski, V.; Scholz, F.; Girault, H. H. Phys. Chem. Chem. Phys. 2003, 5, 3748.
54. Scholz, F.; Gulaboski, R. ChemPhysChem. 2005, 6, 16;
55. Gulaboski, R.; Mirčeski, V.; Scholz, F. Electrochem. Commun. 2002, 4, 277.
56. 2): 0.0007, -0.0556, 0.9982. See notes 33 and 45 for comparison.
57. Bedlechowicz, I.; Maj-Zurawska, M.; Sokalski, T.; Hulanicki, A. J. Electroanal. Chem. 2002, 537, 111.
58. Handbook of Chemistry and Physics, 84th ed.; Lide, D. R. Ed.; CRC Press: New York, 2003.
59. or.