Ion distributions near a liquid liquid interface

Science

Volumn 311, Issue 5758, 2006, Pages 216-218

  Luo, Guangming ^a   Malkova, Sarka ^a   Yoon, Jaesung ^a   Schultz, David G ^a   Lin, Binhua ^b   Meron, Mati ^b   Benjamin, Ilan ^c   Vanýsek, Petr ^d   Schlossman, Mark L ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

^b UNIVERSITY OF CHICAGO   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d NORTHERN ILLINOIS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; COMPUTER SIMULATION; CONTACTS (FLUID MECHANICS); ELECTROLYTES; FLUID DYNAMICS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; POISSON EQUATION; REFLECTION; X RAYS;

CHARGED SURFACES; GOUY-CHAPMAN THEORY; ION DISTRIBUTIONS; MEAN FIELD THEORIES;

IONIC CONDUCTION;

ELECTROLYTE; ION; NITROBENZENE DERIVATIVE; TETRABUTYLAMMONIUM; TETRABUTYLAMMONIUM TETRAPHENYLBORATE; TETRAPHENYLBORON; UNCLASSIFIED DRUG;

LIQUID;

AQUEOUS SOLUTION; ARTICLE; CALCULATION; CHEMICAL STRUCTURE; ELECTRIC POTENTIAL; ENERGY; FORCE; GOUY CHAPMAN THEORY; HYDROPHILICITY; HYDROPHOBICITY; ION DISTRIBUTION; ION TRANSPORT; LIQUID; MATHEMATICAL ANALYSIS; MOLECULAR DYNAMICS; PARAMETER; PREDICTION; PRIORITY JOURNAL; SIMULATION; THEORY; X RAY ANALYSIS;

EID: 30844443071     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1120392     Document Type: Article

References (31)

1. G. Gouy, C. R. Acad. Sci. 149, 654 (1910).
2. D. L. Chapman, Philos. Mag. Ser. 6 25, 475 (1913).
3. S. Levine, C. W. Outhwaite, L. B. Bhuiyan, J. Electroanal. Chem. 123, 105 (1981).
4. J. G. Kirkwood, J. Chem. Phys. 2, 767 (1934).
5. L. I. Daikhin, A. A. Kornyshev, M. Urbakh, J. Electroanal. Chem. 500, 461 (2001).
6. H. H. Girault, in Modern Aspects of Electrochemistry, J. O. M. Bockris, Ed. (Plenum, New York, 1993), vol. 25, p. 1.
7. Z. Samec, V. Marecek, D. Homolka, J. Electroanal. Chem. 187, 31 (1985).
8. C. M. Pereira, A. Martins, M. Rocha, C. J. Silva, F. Silva, J. Chem. Sac. Faraday Trans. 90, 143 (1994).
9. O. Stern, Z. Elektrochem. Angew. Phys. Chem 30, 508 (1924).
10. C. Gavach, P. Seta, B. d'Epenoux, J. Electroanal. Chem. 83, 225 (1977).
11. M. J. Bedzyk, G. M. Bommarito, M. Caffrey, T. L. Penner, Science 248, 52 (1990).
12. J. M. Bloch et al., Phys. Rev. Lett. 61, 2941 (1988).
13. F. Leveiller et al., Science 252, 1532 (1991).
14. D. Vaknin, P. Kruger, M. Losche, Phys. Rev. Lett. 90, 178102 (2003).
15. P. Fenter et al., J. Colloid Interface Sci. 225, 154 (2000).
16. R. Das et al., Phys. Rev. Lett. 90, 188103 (2003).
17. K. Andresen et al., Phys. Rev. Lett. 93, 248103 (2004).
18. Materials and methods are available as supporting material on Science Online.
19. J. D. Reid, O. R. Melroy, R. P. Buck, J. Electroanal. Chem. 147, 71 (1983).
20. L. G. Parratt, Phys. Rev. 95, 359 (1954).
21. W. Schmickler, Interfacial Electrochemistry (Oxford Univ. Press, Oxford, 1996).
22. H. Ohtaki, T. Radnai, Chem. Rev. 93, 1157 (1993).
23. B. S. Krumgalz J. Chem. Soc. Faraday Trans. 78, 437 (1982).
24. D. M. Mitrinovk, A. M. Tikhonov, M. Li, Z. Huang, M. L. Schlossman, Phys. Rev. Lett. 85, 582 (2000).
25. K. R. Mecke, S. Dietrich, Phys. Rev. E 59, 6766 (1999).
26. L. I. Daikhin, A. A. Kornyshev, M. Urbakh, J. Electroanal. Chem. 483, 68 (2000).
27. G. Luo et al., data not shown.
28. Both φ(z) and f(z) include the potential drop due to the neat liquid-liquid interface. We assume that the potential drop across the neat interface is much smaller than that produced by the ions.
29. D. M. Burley, V. C. L. Hutson, C. W. Outhwaite, Mol. Phys. 23, 867 (1972).
30. I. Benjamin, Science 261, 1558 (1993).
31. M.L.S. and P.V. acknowledge support from NSF-CHE031S691, and I.E. acknowledges support from NSF-CHE034S361. M.L.S. thanks J. Gebhardt, T. Graber, and H. Brewer for help with the ChemMatCARS ID beamline and B. Hou for assisting with the x-ray measurements. ChemMatCARS is supported by NSF-CHE, NSF-DMR, and the U.S. Department of Energy (DOE). The APS is supported by the DOE Office of Basic Energy Sciences.