Stoichiometric C=O bond oxidative addition of benzophenone by a discrete radical intermediate to form a cobalt(I) carbene

Journal of the American Chemical Society

Volumn 135, Issue 16, 2013, Pages 6018-6021

  Marquard, Seth L ^a   Bezpalko, Mark W ^a   Foxman, Bruce M ^a   Thomas, Christine M ^a  

^a BRANDEIS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPROPANATION; DENSITY FUNCTIONAL THEORY CALCULATIONS; GROUP TRANSFER; HETERO BIMETALLIC COMPLEXES; KETYL RADICALS; OXIDATIVE ADDITIONS; OXO SPECIES; SINGLE ELECTRON TRANSFER;

DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; FREE RADICAL REACTIONS; ORGANIC COMPOUNDS; ZIRCONIUM; ZIRCONIUM COMPOUNDS;

COBALT COMPOUNDS;

BENZOPHENONE; CARBENE; CARBON; COBALT COMPLEX; OXYGEN; SILANE;

ADDITION REACTION; ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; CYCLOPROPANATION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; OXIDATION; SPECTROSCOPY; STOICHIOMETRY;

EID: 84876724074     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4022683     Document Type: Article

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