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Volumn 48, Issue 35, 2009, Pages 6386-6389

Radicals and transition-metal catalysis: An alliance par excellence to increase reactivity and selectivity in organic chemistry

Author keywords

Cross coupling; Elimination; Homogeneous catalysis; Hydrogen transfer; Radicals

Indexed keywords

CROSS-COUPLING; ELIMINATION; HOMOGENEOUS CATALYSIS; HYDROGEN TRANSFER; RADICALS;

EID: 70349924979     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901761     Document Type: Article
Times cited : (46)

References (36)
  • 5
    • 20544450502 scopus 로고    scopus 로고
    • 2nd ed. (Eds.: A. deMeijere, F. Diederich), Wiley-VCH, Weinheim
    • a) Metal-Catalyzed Cross-Coupling Reactions, 2nd ed. (Eds.: A. deMeijere, F. Diederich), Wiley-VCH, Weinheim, 2004;
    • (2004) Metal-Catalyzed Cross-Coupling Reactions
  • 6
    • 0003779363 scopus 로고    scopus 로고
    • Eds. : M. Beller, C. Bolm, Wiley-VCH, Weinhein
    • b) Transition Metals for Organic Synthesis (Eds. : M. Beller, C. Bolm), Wiley-VCH, Weinhein, 2004.
    • (2004) Transition Metals for Organic Synthesis
  • 16
    • 70349782336 scopus 로고    scopus 로고
    • and references therein.
    • Angew. Chem. Int. Ed. 2009, 48, 2656, and references therein.
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 2656
  • 20
  • 24
    • 70349965904 scopus 로고    scopus 로고
    • Generally the coupling of free aryl radicals is not synthetically useful. For a recent oxidative homocoupling of aryl Grignard reagents mediated or catalyzed by the free radical TEMPO, see
    • Generally the coupling of free aryl radicals is not synthetically useful. For a recent oxidative homocoupling of aryl Grignard reagents mediated or catalyzed by the free radical TEMPO, see: M. S. Maji, T Pfeifer, A. Studer, Angew. Chem. 2008, 120, 9690;
    • (2008) , vol.120 , pp. 9690
    • Maji, M.S.1    Pfeifer, T.2    Studer, A.3    Chem, A.4
  • 25
    • 56749122100 scopus 로고    scopus 로고
    • The mechanism has, however, not been elucidated.
    • Angew. Chem. Int. Ed. 2008, 47, 9547. The mechanism has, however, not been elucidated.
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 9547
  • 28
    • 53549085446 scopus 로고    scopus 로고
    • Though no proof exists for the presence of radicals in this example, the proposed mechanism parallels that proposed and studied in detail for the hydrohydrazination and hydroazidation reactions. See
    • Angew. Chem. Int. Ed. 2008, 47, 5758. Though no proof exists for the presence of radicals in this example, the proposed mechanism parallels that proposed and studied in detail for the hydrohydrazination and hydroazidation reactions. See :
    • Angew. Chem. Int. Ed. 2008 , vol.47 , pp. 5758


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.