Enzyme-like catalysis via ternary complex mechanism: Alkoxy-bridged dinuclear cobalt complex mediates chemoselective O-esterification over N-amidation

Journal of the American Chemical Society

Volumn 135, Issue 16, 2013, Pages 6192-6199

  Hayashi, Yukiko ^a   Santoro, Stefano ^b   Azuma, Yuki ^a   Himo, Fahmi ^b   Ohshima, Takashi ^c   Mashima, Kazushi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b STOCKHOLM UNIVERSITY   (Sweden)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC SYSTEM; DENSITY FUNCTIONAL THEORY CALCULATIONS; DINUCLEAR COBALT COMPLEXES; DINUCLEAR COMPLEX; GROUP-SELECTIVE; LATE TRANSITION METALS; MICHAELIS-MENTEN; TERNARY COMPLEX MECHANISM;

CARBON DIOXIDE; CARBOXYLATION; CATALYST SELECTIVITY; COBALT; COORDINATION REACTIONS; COPPER; DENSITY FUNCTIONAL THEORY; ENZYMES; ESTERIFICATION; ESTERS;

COBALT COMPOUNDS;

COBALT;

AMIDATION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; ESTERIFICATION; TRANSESTERIFICATION;

ACYLATION; ALCOHOLS; AMIDES; CATALYSIS; COBALT; CRYSTALLOGRAPHY, X-RAY; ENZYMES; ESTERS; KINETICS; MODELS, MOLECULAR; PHENOLS; SPECTROPHOTOMETRY, ULTRAVIOLET; TRANSITION ELEMENTS;

EID: 84876698288     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja400367h     Document Type: Article

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