Water and organic synthesis: A focus on the in-water and on-water border. Reversal of the in-water breslow hydrophobic enhancement of the normal endo -effect on crossing to on-water conditions for huisgen cycloadditions with increasingly insoluble organic liquid and solid 2π-dipolarophiles

Journal of Organic Chemistry

Volumn 78, Issue 7, 2013, Pages 3276-3291

  Butler, Richard N ^a   Coyne, Anthony G ^b   Cunningham, William J ^a   Moloney, Eamon M ^a  

^a NATIONAL UNIVERSITY OF IRELAND   (Ireland)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL ACRYLATES; CYCLOADDITIONS; HYDROPHOBIC CHARACTER; MEASUREMENTS OF; ORGANIC LIQUID; ORGANIC SYNTHESIS; PRODUCT RATIOS; WATER SOLUBILITIES;

ACETONITRILE; CYCLOADDITION; KETONES; ORGANIC SOLVENTS; STYRENE;

HYDROPHOBICITY;

1,4 BENZOQUINONE; ACETONITRILE; ACRYLIC ACID DERIVATIVE; CARBON; KETONE DERIVATIVE; STYRENE DERIVATIVE; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYST; CHEMICAL REACTION; CLAISEN REARRANGEMENT; CYCLOADDITION; ENCAPSULATION; ENVIRONMENTAL TEMPERATURE; HYDROGEN BOND; HYDROPHOBICITY; PARTICLE SIZE; SOLUBILITY; SYNTHESIS;

EID: 84875940974     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo400055g     Document Type: Article

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