The influence of water on the rates of 1,3-dipolar cycloaddition reactions: Trigger points for exponential rate increases in water-organic solvent mixtures. Water-super versus water-normal dipolarophiles

Journal of the American Chemical Society

Volumn 126, Issue 38, 2004, Pages 11923-11929

  Butler, Richard N ^a   Cunningham, William J ^a   Coyne, Anthony G ^a   Burke, Luke A ^b  

^a NATIONAL UNIVERSITY OF IRELAND   (Ireland)

^b RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDS; HYDROPHOBICITY; METHANOL; ORGANIC SOLVENTS; REACTION KINETICS; WATER;

CYCLOADDITION REACTIONS; DIPOLAROPHILES; SOLVATION; STRUCTURED WATER CLUSTERS;

ADDITION REACTIONS;

ACETONE; ACETONITRILE; ETHYL VINYL KETONE; KETONE; METHANOL; ORGANIC SOLVENT; PYRIDAZINE DERIVATIVE; PYRIDAZINIUM DICYANOMETHANIDE; SOLVENT; TERT BUTYL ALCOHOL; UNCLASSIFIED DRUG; WATER;

ARTICLE; CALCULATION; CHEMICAL REACTION KINETICS; CYCLOADDITION; DRUG MIXTURE; GROWTH REGULATION; HYDROGEN BOND; HYDROPHOBICITY; REACTION ANALYSIS; STATISTICAL SIGNIFICANCE; THEORETICAL MODEL; WATER ANALYSIS;

EID: 4644277320     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja040119y     Document Type: Article

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