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Volumn 49, Issue 47, 2010, Pages 8912-8914

A molecular capsule network: Guest encapsulation and control of Diels-Alder reactivity

Author keywords

coordination networks; Diels Alder reaction; host guest systems; molecular capsules

Indexed keywords

COORDINATION NETWORKS; CRYSTAL FORMS; CYCLOPENTADIENES; DIELS-ALDER; DIELS-ALDER REACTION; GUEST MOLECULES; HOST-GUEST SYSTEM; MOLECULAR CAPSULE;

EID: 78449261589     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201004781     Document Type: Article
Times cited : (53)

References (32)
  • 4
    • 0037012747 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 1488 - 1508
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1488-1508
  • 12
    • 77954013877 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2010, 49, 4816 - 4819.
    • (2010) Angew. Chem. Int. Ed. , vol.49 , pp. 4816-4819
  • 13
    • 78449262147 scopus 로고    scopus 로고
    • For representative examples of solution-like host-guest chemistry in crystalline materials, see
    • For representative examples of solution-like host-guest chemistry in crystalline materials, see
  • 22
    • 0001118861 scopus 로고
    • J. M. Thomas, Nature 1981, 289, 633 - 634
    • (1981) Nature , vol.289 , pp. 633-634
    • Thomas, J.M.1
  • 24
    • 0000718095 scopus 로고    scopus 로고
    • 4 capsule analogous to the capsule unit of network 2 (unpublished data). When cis-chelated palladium(II) ion was employed, a bowl-shaped structure was obtained; see
    • 4 capsule analogous to the capsule unit of network 2 (unpublished data). When cis-chelated palladium(II) ion was employed, a bowl-shaped structure was obtained; see:, M. Fujita, S.-Y. Yu, T. Kusukawa, H. Funaki, K. Ogura, K. Yamaguchi, Angew. Chem. 1998, 110, 2192 - 2196
    • (1998) Angew. Chem. , vol.110 , pp. 2192-2196
    • Fujita, M.1    Yu, S.-Y.2    Kusukawa, T.3    Funaki, H.4    Ogura, K.5    Yamaguchi, K.6
  • 25
    • 0032541262 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1998, 37, 2082 - 2085.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 2082-2085
  • 26
    • 0034802195 scopus 로고    scopus 로고
    • For the Diels-Alder reaction in a single-crystal-to-single-crystal fashion, see:, - 4959
    • For the Diels-Alder reaction in a single-crystal-to-single-crystal fashion, see:, J. H. Kim, S. V. Lindeman, J. K. Kochi, J. Am. Chem. Soc. 2001, 123, 4951 - 4959.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 4951
    • Kim, J.H.1    Lindeman, S.V.2    Kochi, J.K.3
  • 27
    • 78449239267 scopus 로고    scopus 로고
    • note
    • 2=0.4105 for all data.
  • 28
    • 78449237473 scopus 로고    scopus 로고
    • note
    • 4 units form a capsule shape, and the other 16 units are open-mouthed octahedral cages in which guest molecules were not trapped (for detailed structures, see the Supporting Information).
  • 29
    • 78449244540 scopus 로고    scopus 로고
    • The dimerization of 7 to give dicyclopentadiene (8) by a Diels-Alder reaction is well-known and rapidly occurs, even at room temperature
    • The dimerization of 7 to give dicyclopentadiene (8) by a Diels-Alder reaction is well-known and rapidly occurs, even at room temperature
  • 32
    • 78449243832 scopus 로고    scopus 로고
    • note
    • 4, the ratio of 7 / 8 in the crystal was shown to be 38:62 from the crystal structure, but was estimated to be 56:44 by NMR analysis of the guests extracted from the crystals (after acid decomposition of the crystal). Presumably, monomer 7 also existed in the interstitial pores to some extent but could not be located by crystallography because of disorder.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.