A theoretical investigation on the mechanism and stereochemical course of the addition of (E)-2-butenyltrimethylsilane to acetaldehyde by electrophilic and nucleophilic activation

Journal of the American Chemical Society

Volumn 135, Issue 12, 2013, Pages 4743-4756

  Wolf, Larry M ^a   Denmark, Scott E ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIASTEREO-SELECTIVITY; ELECTROPHILIC ACTIVATION; ELECTROSTATIC REPULSION; EXPERIMENTAL MODELS; NUCLEOPHILIC ACTIVATION; ORBITAL INTERACTION; STERIC INTERACTIONS; THEORETICAL INVESTIGATIONS;

DENSITY FUNCTIONAL THEORY; ELECTROSTATICS; STEREOSELECTIVITY;

ACETALDEHYDE;

ACETALDEHYDE; FLUORIDE; SILANE DERIVATIVE;

ADDITION REACTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DESILYLATION; DIASTEREOISOMER; ELECTROPHILICITY; ENERGY; NUCLEOPHILICITY; STATIC ELECTRICITY; STEREOCHEMISTRY;

EID: 84875702726     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja311889v     Document Type: Article

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