Stereoselective allylation of ketones: Explanation for the unusual inversion of the induced stereochemistry in the auxiliary-mediated crotylation and pentenylation of butanone by DFT calculations

Chemistry - A European Journal

Volumn 15, Issue 7, 2009, Pages 1706-1712

  Tietze, Lutz F ^a   Kinzel, Tom ^a   Schmatz, Stefan ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Allylation; Chiral auxiliaries; Density functional calculations; Diastereoselectivity; Norpseudoephedrine

Indexed keywords

ACTIVATION ENERGY; DICHLOROMETHANE; ETHERS; ISOMERS; KETONES; STEREOCHEMISTRY; SULFUR COMPOUNDS;

ALLYLATION; CHIRAL AUXILIARIES; DENSITY FUNCTIONAL CALCULATIONS; DIASTEREOSELECTIVITY; NORPSEUDOEPHEDRINE;

DENSITY FUNCTIONAL THEORY;

EID: 60749116595     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801889     Document Type: Article

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