Diastereoselectivity in lewis-acid-catalyzed mukaiyama aldol reactions: A DFT study

Journal of the American Chemical Society

Volumn 134, Issue 36, 2012, Pages 14973-14981

  Lee, Joshua M ^a   Helquist, Paul ^a   Wiest, Olaf ^a,b  

^a UNIVERSITY OF NOTRE DAME   (United States)

^b PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIPERIPLANAR; DENMARK; DFT STUDY; DIASTEREO-SELECTIVITY; LEWIS ACID; MUKAIYAMA ALDOL REACTION; PHENYL GROUP; POLARIZABLE CONTINUUM MODEL; QUALITATIVE MODEL; SILYL ENOL ETHERS; SILYL GROUP; SOLVATION EFFECT; STERIC EFFECT; TERT-BUTYL GROUP; TRANSITION STATE; TRANSITION STRUCTURES; TRIMETHYL;

ALDEHYDES; CARBON; CHEMICAL REACTIONS; CONTINUUM MECHANICS; DENSITY FUNCTIONAL THEORY; ETHERS; KETONES; ORGANIC COMPOUNDS; STEREOCHEMISTRY;

STEREOSELECTIVITY;

ALDEHYDE; LEWIS ACID;

ALDOL REACTION; ARTICLE; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ISOMERISM; MUKAIYAMA REACTION; SOLVATION; STEREOCHEMISTRY;

ALCOHOLS; ALDEHYDES; CATALYSIS; KETONES; LEWIS ACIDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; QUANTUM THEORY; STEREOISOMERISM;

EID: 84866358406     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3052975     Document Type: Article

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