Isolation of a mixed valence diiron hydride: Evidence for a spectator hydride in hydrogen evolution catalysis

Journal of the American Chemical Society

Volumn 135, Issue 9, 2013, Pages 3633-3639

  Wang, Wenguang ^a   Nilges, Mark J ^a   Rauchfuss, Thomas B ^a   Stein, Matthias ^b  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLOGRAPHIC ANALYSIS; DENSITY FUNCTIONAL THEORY CALCULATIONS; HYDRIDO COMPLEXES; HYDROGEN EVOLUTION; HYDROGEN EVOLUTION REACTIONS; HYPERFINE COUPLING; SINGLY OCCUPIED MOLECULAR ORBITALS; SPECTRAL SIMULATIONS;

DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; HYDRIDES; HYDROGEN; ISOMERS; LIGANDS; MAGNETIC RESONANCE; MOLECULAR ORBITALS; PARAMAGNETISM; PHOSPHORUS COMPOUNDS; REDUCTION; STEREOCHEMISTRY;

IRON COMPOUNDS;

DIIRON HYDRIDE; HYDROGEN; IRON DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CRYSTALLOGRAPHY; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; STEREOISOMERISM;

CATALYSIS; FERROUS COMPOUNDS; HYDROGEN; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; QUANTUM THEORY;

EID: 84874891015     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja312458f     Document Type: Article

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