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Volumn 49, Issue 21, 2010, Pages 10117-10132

Models for the active site in [FeFe] hydrogenase with iron-bound ligands derived from Bis-, Tris-, and tetrakis(mercaptomethyl)silanes

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; HYDROGENASE; IRON; IRON HYDROGENASE; IRON SULFUR PROTEIN; LIGAND; ORGANOMETALLIC COMPOUND; SILANE DERIVATIVE; SILICON;

EID: 77958085566     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic101399k     Document Type: Article
Times cited : (68)

References (93)
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    • Recent publications dealing with sila-substituted odorants
    • Recent publications dealing with sila-substituted odorants: Büttner, M. W., Penka, M., Doszczak, L., and Kraft, P. Organometallics 2007, 26, 1295-1298
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    • Recent publications dealing with sila-substituted explosives
    • Recent publications dealing with sila-substituted explosives: Klapötke, T. M., Krumm, B., Ilg, R., Troegel, D., and Tacke, R. J. Am. Chem. Soc. 2007, 129, 6908-6915
    • (2007) J. Am. Chem. Soc. , vol.129 , pp. 6908-6915
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    • a value of acetic acid in acetonitrile is 22.6 and that of pivalic acid should not be significantly different.
    • a value of acetic acid in acetonitrile is 22.6 and that of pivalic acid should not be significantly different.
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    • 5 ≈ 4 yielding virtually the same standard deviation between simulated and experimental CVs.
    • 5 ≈ 4 yielding virtually the same standard deviation between simulated and experimental CVs.
  • 75
    • 78049252671 scopus 로고    scopus 로고
    • Reaction 10 is fully irreversible. Consequently, there is an infinite number of E °/ k ° combinations yielding exactly the same current curve. For this reason, the "right" combination cannot be determined exclusively from electrochemical data.
    • Reaction 10 is fully irreversible. Consequently, there is an infinite number of E °/ k ° combinations yielding exactly the same current curve. For this reason, the "right" combination cannot be determined exclusively from electrochemical data.
  • 76
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    • Reaction 11 should be considered an overall reaction that occurs in several steps. It describes the re-oxidation of the species generated in reaction 10 and is necessary only to render the re-oxidation peak observed in the reverse scan at around -1.05 V.
    • Reaction 11 should be considered an overall reaction that occurs in several steps. It describes the re-oxidation of the species generated in reaction 10 and is necessary only to render the re-oxidation peak observed in the reverse scan at around -1.05 V.
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    • It should be mentioned that this behavior is strongly dependent on the applied supporting electrolyte. It becomes even more pronounced when using tetra- n -butylammonium perchlorate instead of tetraethylammonium perchlorate. In that case, the "isosbestic point" is lost and a positive shift of less than 10 mV is observed virtually independently of the HP concentration unless the HP concentration becomes distinctly lower than [HP]/[ 5b ] = 1.
    • It should be mentioned that this behavior is strongly dependent on the applied supporting electrolyte. It becomes even more pronounced when using tetra- n -butylammonium perchlorate instead of tetraethylammonium perchlorate. In that case, the "isosbestic point" is lost and a positive shift of less than 10 mV is observed virtually independently of the HP concentration unless the HP concentration becomes distinctly lower than [HP]/[ 5b ] = 1.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.