Oxidation and degradation of native wheat starch by acidic bromate in water at room temperature

Carbohydrate Polymers

Volumn 93, Issue 1, 2013, Pages 73-80

  Komulainen, Sanna ^a   Verlackt, Christof ^b   Pursiainen, Jouni ^a   Lajunen, Marja ^a  

^a UNIVERSITY OF OULU   (Finland)

^b UNIVERSITY OF ANTWERP   (Belgium)

Author keywords

Bromate; Oxidation; Synthetic method; Water soluble oxidized starch

Indexed keywords

STARCH;

BROMATE; CARBONYL AND CARBOXYL GROUPS; INSOLUBLE PRODUCTS; OXIDATION REACTIONS; OXIDIZED STARCH; POLYMERIC STRUCTURES; SHORT REACTION TIME; SYNTHETIC METHODS;

OXIDATION;

TRITICUM AESTIVUM;

EID: 84874659851     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2012.06.001     Document Type: Conference Paper

References (40)

1. 3 reagent: pH dependence, stoichiometry, substrates and origin of selectivity Tetrahedron 61 21 2005 4911 4917
2. 1H-NMR spectroscopy Starch-Stärke 47 12 1995 469 475
3. Y.-L. Du, Y. Cao, F. Lu, F. Li, Y. Cao, and X.-L. Wang Biodegradation behaviors of thermoplastic starch (TPS) and thermoplastic dialdehyde starch (TPDAS) under controlled composting conditions Polymer Testing 27 8 2008 924 930
4. 13C NMR study Starch-Stärke 49 12 1997 488 491
5. L. Farkas, B. Perlmutter, and O. Schachter The oxidation of ethyl alcohol in the presence of bromate and bromine Journal of the American Chemical Society 71 8 1949 2833 2835
6. L. Farkas, B. Perlmutter, and O. Schachter The reaction between ethyl alcohol and bromine Journal of the American Chemical Society 71 8 1949 2829 2833
7. K.K.S. Gupta, S.C. Kumar, P.K. Sen, A. Banerjee, and H. Chatterjee Relative reactivities of some mono-ols and vicinal diols towards bromate ion in acid medium Journal of Chemical Research, Synopses 5 1991 118 119
8. R. Hollingsworth, and M.R. El-Gewely The chemical degradation of starch: Old reactions and new frontiers Biotechnology annual review 1996 Elsevier (pp. 281-291)
9. M. Izydorczyk Understanding the chemistry of food carbohydrates S.W. Cui, Food carbohydrates 2005 CRC Press/Taylor & Francis Group Boca Raton 52
10. S. Kajigaeshi, T. Nakagawa, N. Nagasaki, H. Yamasaki, and S. Fujisaki Oxidation of alcohols and ethers using sodium bromate-hydrobromic acid system Bulletin of the Chemical Society of Japan 59 3 1986 747 750
11. Y. Kato, R. Matsuo, and A. Isogai Oxidation process of water-soluble starch in TEMPO-mediated system Carbohydrate Polymers 51 1 2003 69 75
12. Komulainen, A.; Pursiainen, J.; Perämäki, P.; & Lajunen, M. Complexation of iron(III) with water-soluble oxidized starch, under review.
13. D. Kuakpetoon, and Y.-J. Wang Structural characteristics and physicochemical properties of oxidized corn starches varying in amylose content Carbohydrate Research 341 11 2006 1896 1915
14. J. Kärkkäinen, K. Lappalainen, P. Joensuu, and M. Lajunen HPLC-ELSD analysis of six starch species heat-dispersed in [BMIM]Cl ionic liquid Carbohydrate Polymers 84 1 2011 509 516
15. L. Metsger, and S. Bittner Autocatalytic oxidation of ethers with sodium bromate Tetrahedron 56 13 2000 1905 1910
16. A. Mora-Gutierrez, and I.C. Baianu Carbon-13 nuclear magnetic resonance studies of chemically modified waxy maize starch, corn syrups, and maltodextrins. Comparisons with potato starch and potato maltodextrins Journal of Agricultural and Food Chemistry 39 6 1991 1057 1062
17. P. Muhrbeck, A.C. Eliasson, and A.C. Salomonsson Physical characterization of bromine oxidised potato starch Starch-Stärke 42 11 1990 418 420
18. R. Natarajan, and W. Venkatasubramanian The kinetics of oxidation of secondary alcohols by potassium bromate Tetrahedron Letters 10 57 1969 5021 5024
19. 1H-NMR spectroscopy improved resolution and two-dimensional spectroscopy Starch-Stärke 48 10 1996 352 357
20. M. Pagliaro Autocatalytic oxidations of primary hydroxyl groups of cellulose in phosphoric acid with halogen oxides Carbohydrate Research 308 3-4 1998 311 317
21. S. Pääkkönen, J. Pursiainen, and M. Lajunen Fast oxidation of secondary alcohols by the bromate-bromide system using cyclic microwave heating in acidic water Tetrahedron Letters 51 51 2010 6695 6699
22. S. Pääkkönen, J. Pursiainen, and M. Lajunen Room-temperature oxidation of secondary alcohols by bromate-bromide coupling in acidic water Synthetic Communications 42 4 2012 534 540
23. S. Pavlovic, and P.R.G. Brandao Adsorption of starch, amylose, amylopectin and glucose monomer and their effect on the flotation of hematite and quartz Minerals Engineering 16 11 2003 1117 1122
24. M. Rinaudo Main properties and current applications of some polysaccharides as biomaterials Polymer International 57 3 2008 397 430
25. A.-C.B. Salomonsson, R.E. Andersson, L.J. Torneport, and O. Theander A 1H- and 13C-N.M.R. study of bromine-oxidised potato starch Carbohydrate Research 217 1991 221 225
26. K.K. Sen Gupta, A. Banerjee, and H. Chatterjee Oxidative behaviours and relative reactivities of some α-hydroxy acids towards bromate ion in hydrochloric acid medium Tetrahedron 48 25 1992 5323 5330
27. A. Serrero, S. Trombotto, P. Cassagnau, Y. Bayon, P. Gravagna, and S. Montanari Polysaccharide gels based on chitosan and modified starch: Structural characterization and linear viscoelastic behavior Biomacromolecules 11 6 2010 1534 1543
28. M.I.B. Tavares, A.L.B.S. Bathista, E.O. Silva, P.M. Costa, N.P. Filho, and J.S. Nogueira 13C-NMR study of dipteryx alata vogel starch Journal of Applied Polymer Science 92 4 2004 2151 2154
29. A. Teleman, K. Kruus, E. Ämmälahti, J. Buchert, and K. Nurmi Structure of dicarboxyl malto-oligomers isolated from hypochlorite-oxidised potato starch studied by 1H and 13C NMR spectroscopy Carbohydrate Research 315 3-4 1999 286 292
30. R.N. Tharanathan Starch - Value addition by modification Critical Reviews in Food Science and Nutrition 45 5 2005 371 384
31. H. Tomioka, K. Oshima, and H. Nozaki Cerium catalyzed selective oxidation of secondary alcohols in the presence of primary ones Tetrahedron Letters 23 5 1982 539 542
32. L.J. Torneport, B.A.C. Salomonsson, and O. Theander Chemical characterization of bromine oxidized potato starch Starch-Stärke 42 11 1990 413 417
33. Y.-J. Wang, and L. Wang Physicochemical properties of common and waxy corn starches oxidized by different levels of sodium hypochlorite Carbohydrate Polymers 52 3 2003 207 217
34. O. Varela Oxidative reactions and degradations of sugars and polysaccharides Advances in carbohydrate chemistry and biochemistry 2003 Academic Press (pp. 307-369)
35. D.H. Williams, and I. Fleming Spectroscopic methods in organic chemistry 1987 McGrawhill Book Company London (p. 38)
36. R.E. Wing, and J.L. Willett Water soluble oxidized starches by peroxide reactive extrusion Industrial Crops and Products 7 1 1997 45 52
37. Y. Yamamoto, H. Suzuki, and Y. Moro-oka Ruthenium-catalyzed oxidation of alcohols with sodium bromate Tetrahedron Letters 26 17 1985 2107 2108
38. S.-D. Zhang, X.-L. Wang, Y.-R. Zhang, K.-K. Yang, and Y.-Z. Wang Preparation of a new dialdehyde starch derivative and investigation of its thermoplastic properties Journal of Polymer Research 17 3 2010 439 446
39. S.-D. Zhang, Y.-R. Zhang, X.-L. Wang, and Y.-Z. Wang High carbonyl content oxidized starch prepared by hydrogen peroxide and its thermoplastic application Starch-Stärke 61 11 2009 646 655
40. Q. Zhu, R. Sjöholm, K. Nurmi, and E. Bertoft Structural characterization of oxidized potato starch Carbohydrate Research 309 2 1998 213 218