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Volumn 19, Issue 5, 2013, Pages 1563-1567

Photocatalytic oxidation of organic compounds in water by using ruthenium(II)-pyridylamine complexes as catalysts with high efficiency and selectivity

Author keywords

C H bond activation; electron transfer; oxidation; photocatalysis; ruthenium

Indexed keywords

AQUA COMPLEXES; CATALYTIC SYSTEM; CH-BOND ACTIVATION; ELECTRON MEDIATOR; ELECTRON TRANSFER; ORGANIC SUBSTRATE; OXIDATION CATALYSTS; PHOTOCATALYTIC OXIDATIONS; TURNOVER NUMBER;

EID: 84872712513     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201203430     Document Type: Article
Times cited : (51)

References (56)
  • 44
    • 84872743558 scopus 로고    scopus 로고
    • The light employed here is a white light (λ>380 nm), obtained from an ASAHI SPECTRA MAX-301 xenon light source (300 W) without any filters
    • The light employed here is a white light (λ>380 nm), obtained from an ASAHI SPECTRA MAX-301 xenon light source (300 W) without any filters.
  • 46
    • 84872727571 scopus 로고    scopus 로고
    • note
    • III complex was almost consumed for oxidation of benzyl alcohol, but no further oxidation of benzaldehyde occurred. Therefore, the formation of benzoic acid during the catalytic oxidation of benzyl alcohols should be negligible.
  • 49
    • 84872717320 scopus 로고    scopus 로고
    • II-aqua complex and 4-methylbenzyl alcohol were the two-photon and two-electron process. Thus, the upper limit of the quantum yields (Φ) was 50 %
    • II-aqua complex and 4-methylbenzyl alcohol were the two-photon and two-electron process. Thus, the upper limit of the quantum yields (Φ) was 50 %.
  • 50
    • 84872739347 scopus 로고    scopus 로고
    • 2+ was determined to be 58 % under irradiation at 440 nm (lit. 80 %): see ref. [10 b]
    • 2+ was determined to be 58 % under irradiation at 440 nm (lit. 80 %): see ref. [10 b].
  • 51
    • 84872740333 scopus 로고    scopus 로고
    • III.
    • III.
  • 52
    • 84872695591 scopus 로고    scopus 로고
    • IV-oxo complexes under diluted conditions cannot be determined, because the UV/Vis spectral changes ascribable to the formation of the oxo complexes under the conditions are almost negligible
    • IV-oxo complexes under diluted conditions cannot be determined, because the UV/Vis spectral changes ascribable to the formation of the oxo complexes under the conditions are almost negligible.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.