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The light employed here is a white light (λ>380 nm), obtained from an ASAHI SPECTRA MAX-301 xenon light source (300 W) without any filters
-
The light employed here is a white light (λ>380 nm), obtained from an ASAHI SPECTRA MAX-301 xenon light source (300 W) without any filters.
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note
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III complex was almost consumed for oxidation of benzyl alcohol, but no further oxidation of benzaldehyde occurred. Therefore, the formation of benzoic acid during the catalytic oxidation of benzyl alcohols should be negligible.
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II-aqua complex and 4-methylbenzyl alcohol were the two-photon and two-electron process. Thus, the upper limit of the quantum yields (Φ) was 50 %
-
II-aqua complex and 4-methylbenzyl alcohol were the two-photon and two-electron process. Thus, the upper limit of the quantum yields (Φ) was 50 %.
-
-
-
-
50
-
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84872739347
-
-
2+ was determined to be 58 % under irradiation at 440 nm (lit. 80 %): see ref. [10 b]
-
2+ was determined to be 58 % under irradiation at 440 nm (lit. 80 %): see ref. [10 b].
-
-
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51
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84872740333
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III.
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III.
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52
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84872695591
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IV-oxo complexes under diluted conditions cannot be determined, because the UV/Vis spectral changes ascribable to the formation of the oxo complexes under the conditions are almost negligible
-
IV-oxo complexes under diluted conditions cannot be determined, because the UV/Vis spectral changes ascribable to the formation of the oxo complexes under the conditions are almost negligible.
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56
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