Mechanistic analysis and optimization of the copper-catalyzed enantioselective intramolecular alkene aminooxygenation

Journal of Organic Chemistry

Volumn 78, Issue 2, 2013, Pages 506-515

  Paderes, Monissa C ^a   Keister, Jerome B ^a   Chemler, Sherry R ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

A-CARBON; AMINO ALCOHOLS; ASYMMETRIC INDUCTION; C-O BOND FORMATION; CARBON RADICALS; DEUTERIUM LABELING; ENANTIOSELECTIVE; FIRST ORDER; GRAM SCALE; KINETIC ISOTOPE EFFECTS; KINETICS STUDIES; MECHANISTIC ANALYSIS; OXAZOLINES; OXYGEN SOURCES; PYRROLIDINES; RATE-LIMITING STEPS; REACTION TEMPERATURE; ZERO ORDER;

ALCOHOLS; CARBON; CATALYSIS; COPPER; DEUTERIUM; NITROGEN COMPOUNDS; OLEFINS; OPTIMIZATION; REACTION KINETICS;

ENANTIOSELECTIVITY;

ALKENE; COPPER; NITROGEN; OXAZOLINE DERIVATIVE; PYRROLIDINE DERIVATIVE; TEMPOL;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; ENANTIOSELECTIVITY; OXYGENATION; REACTION OPTIMIZATION; SUBSTITUTION REACTION;

ALKENES; AMINES; CATALYSIS; COPPER; KINETICS; LIGANDS; ORGANOMETALLIC COMPOUNDS; OXAZOLES; OXYGEN; STEREOISOMERISM; TEMPERATURE;

EID: 84872512919     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo3023632     Document Type: Article

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