Lipase-catalyzed synthesis of poly(e-caprolactone) in supercritical carbon dioxide

Biocatalysis and Agricultural Biotechnology

Volumn 1, Issue 4, 2012, Pages 280-283

  Santos, Roseni D ^a   Rosso Comim, Sibele R ^a   Oliveira, Débora de ^a   Treichel, Helen ^b   Di Luccio, Marco ^a   Ferreira, Sandra R S ^a   Oliveira, J Vladimir ^a  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^b UNIVERSIDADE FEDERAL DA FRONTEIRA SUL   (Brazil)

Author keywords

Biopolymer; Carbon dioxide; Lipase; Polycaprolactone

Indexed keywords

EID: 84866432050     PISSN: 18788181     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.bcab.2012.04.002     Document Type: Article

References (22)

1. Albertsson A.C., Srivastava R.K. Recent developments in enzyme-catalyzed ring-opening polymerization. Adv. Drug Delivery Rev. 2008, 60:1077-1093.
2. Bender J.P., Feitein M., Franceschi E., Corazza M.L., Oliveira J.V. Phase behavior of binary systems of lactones in carbon dioxide. J. Chem. Thermodyn. 2010, 42:48-53.
3. Bergeot V., Tassaing T., Besnard M., Cansell F., Mingotaud A.F. Anionic ring-opening polymerization of ε-caprolactone in supercritical carbon dioxide: parameters influencing the reactivity. J. Supercritical Fluids 2004, 28:249-255.
4. Eisenmenger M.J., Reyes-De-Corcuera J.I. High pressure enhancement of enzymes: a review. Enzyme Microb. Technol. 2009, 45:331-347.
5. García-Arrazola R., Guerrero D.A., Gimeno M., Bárzano E. Lipase-catalyzed synthesis of poly-L-lactide using supercritical carbon dioxide. J. Supercritical Fluids 2009, 51:197-201.
6. Habulin M., Knez Z. Pressure stability of lipases and their use in different systems. J. Chem. Technol. Biotechnol. 2001, 76:1260-1266.
7. Knez Z., Habulin M., Krmelj V. Enzyme catalyzed reactions in dense gases. J. Supercritical Fluids 1998, 14:17-29.
8. Loeker F.C., Duxbury C.J., Kumar R., Gao W., Gross R., Howdle S.M. Enzyme-catalyzed ring-opening polymerization of ε-caprolactone in supercritical carbon dioxide. Macromolecule 2004, 37:2450-2453.
9. Olabisi O., Robeson L.E., Shaw M.T. Polymer-Polymer Miscibility 1979, Academic Press, New York.
10. Oliveira D., Feihrmann A.C., Rubira A.F., Kunita M.H., Dariva C., Oliveira J.V. Assessment of two immobilized lipases activity treated in compressed fluids. J. Supercritical Fluids 2006, 38:373-382.
11. Pitt C.G., Chasalow F.I., Hibionada Y.M., Klimas D.M., Schindler A. The degradation of poly(ε-caprolactone) in vivo. J. Appl. Polym. Sci. 1981, 26:3779-3784.
12. Stassin F., Halleux O., Jérôme R. Ring-opening polymerization of ε-caprolactone in supercritical carbon dioxide. Macromolecule 2001, 34:775-781.
13. Teng X., Ren J., Gu S. Preparation and characterization of porous PDLLA/HA composite foams by supercritical carbon dioxide technology. J. Biomed. Mater. Res. B Appl. Biomater. 2006, 81B:185-193.
14. Thurecht K.J., Heise A., Degeus M., Villarroya S., Zhou J., Wyatt M.F., Howdle S.M. Kinetics of enzymatic ring-opening polymerization of ε-caprolactone in supercritical carbon dioxide. Macromolecule 2006, 39:7967-7972.
15. Valério A., Fiametti K.G., Rovani S., Franceschi E., Corazza M.L., Treichel H., Oliveira D., Oliveira J.V. Enzymatic production of mono- and diglycerides in compressed n-butane and AOT surfactant. J Supercrit Fluids 2009, 49:216-220.
16. Varma I.K., Albertsson A.C., Rajkhowa R., Srivastava R.K. Enzyme catalyzed synthesis of polyesters. Prog. Polym. Sci. 2005, 30:949-981.
17. Varma M.N., Madras G. Kinetics of synthesis of butyl butyrate by esterification and transesterification in supercritical carbon dioxide. J. Chem. Technol. Biotechnol. 2008, 83:1135-1144.
18. Vija H., Telling A., Tougu V. Lipase-catalyzed esterification in supercritical carbon dioxide and in hexane. Bioorg. Med. Chem. Lett. 1997, 7:259-262.
19. Yoon C.S., Park H.D., Kim S.Y. High molecular weight poly(l-lactide) and its microsphere synthesized in the supercritical dimethyl ether. Macromol. Symp. 2007, 249-250:515-520.
20. 2. Powder Technol. 2004, 146:32-45.
21. Technical Specifications Table for Novozym 435. Available at: http://dx.doi.org/www.novozymes.com.br.
22. 2. Macromolecule 2006, 39:5352-5358.