Enzyme catalyzed reactions in dense gases

Journal of Supercritical Fluids

Volumn 14, Issue 1, 1998, Pages 17-29

  Knez, Z ^a   Habulin, M ^a   Krmelj, V ^a  

^a UNIVERSITY OF MARIBOR   (Slovenia)

Author keywords

Enzymes; Esterification; High pressure; Mass transfer; Thermodynamic parameters

Indexed keywords

EID: 0346854239     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(98)00097-7     Document Type: Article

References (69)

1. 2, Chem. Eng. Commun. 45 (1986) 207.
2. T.W. Randolph, H.W. Blanch, J.M. Prausnitz, C.R. Wilke, Enzymatic catalysis in SCF, Biotechnol. Lett. 7 (5) (1985) 325.
3. D.A. Hammond, M. Karel, A.M. Klibanov, Enzymatic reactions in supercritical gasses, Appl. Biochem. Biotech. 11 (1985) 393.
4. 2, Science 238 (1988) 387.
5. 2, AIChE J. 34 (1988) 1354.
6. 2, Proc. Nat. Acad. Sci. USA 85 (1988) 2979.
7. K. Nakamura, M.Y. Chi, Y. Yamada, T. Yano, Enzymatic reactions in SCF, in: Proc. 3rd World Congress on Chemical Engineering, 1986, p. 945.
8. 2, in: M. Perrut (Ed.), Proc. 1st Int. Symp. on Supercritical Fluids, vol. 2, 1988, p. 925.
9. 2, Agric. Biol. Chem. 52 (1988) 1541.
10. 2, Biotechnol. Lett. 2 (1989) 643.
11. J.C. Erickson, P. Schyns, C.L. Cooney, Effect of pressure on enzymatic reaction in a SCF, AIChE J. 36 (1990) 299.
12. 2, in: C. Balny, R. Hayashi, K. Heremans, P. Masson (Eds.), Proc. 1st European Seminar on High Pressure in Biotechnology, 1992, p. 461.
13. 2 and isooctan as solvents, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 149.
14. I.B. De Carvalho, T.C. De Sampaio, S. Barreiros, Subtisin hydration and activity in supercritical and near-critical fluids, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 149.
15. 2, Fluid Phase Equilib. 108 (1995) 1.
16. 2: Effect of water activity, in: P. Rudolf von Rohr, C. Trepp (Eds.), Proc. 3rd Int. Symp. on High Pressure Chemical Engineering, 1996, p. 115.
17. I.B. De Carvalho, T.C. De Sampaio, S. Barreiros, Solvent effect on the catalytic activity of subtilisin suspended in compressed gases, Biotechnol. Bioeng. 49 (4) (1996) 399.
18. 2, Enzyme Microb. Technol. 14 (8) (1992) 649.
19. 2, J. Ferment. Bioeng. 82 (4) (1996) 334.
20. 2, Enzyme Microb. Technol. 15 (8) (1993) 691.
21. A.J. Russell, E.J. Beckman, A.K. Chaudhaary, Studying enzyme-activity in SCF, Chemtech 24 (3) (1994) 33.
22. 2, in: M. Perrut (Ed.), Proc. 1st Int. Symp. on Supercritical Fluids, vol. 2, 1988, p. 933.
23. 2, in: C. Balny, R. Hayashi, K. Heremans, P. Masson (Eds.), Proc. 1st European Seminar on High Pressure in Biotechnology, 1992, p. 447.
24. 2, in: G. Vetter (Ed.), Abstract Handbook of the 2nd Int. Symp. on High Pressure Chemical Engineering, 1990, p. 65.
25. 2 and n-hexsan, Biotechnol. Lett. 12 (1) (1990) 11.
26. 2, in: M. McHugh (Ed.), Proc. 2nd Int. Symp. on Supercritical Fluids, 1991, p. 150.
27. T. Dumont, D. Barth, C. Corbier, G. Branlant, M. Perrut, Enzymatic reaction kinetic in organic solvent and in SCF, Biotechnol. Bioeng. 39 (1992) 329.
28. 2, Biotechnol. Bioeng. 39 (1992) 273.
29. 2, in: J. Tramper et al. (Eds.), Progress in Biotechnology 8: Biocatalysis in Non-Conventional Media, Elsevier, Amsterdam, 1992, p. 425.
30. 2, in: C. Balny, R. Hayashi, K. Heremans, P. Masson (Eds.), Proc. 1st European Seminar on High Pressure in Biotechnology, 1992, p. 451.
31. P. Bernard, D. Barth, R.M. Nicoud, Enzymatic synthesis of glycerides: a comparison between supercritical and liquid operations, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 137.
32. 2, in: J. Tramper et al. (Eds.), Progress in Biotechnology 8: Biocatalysis in Non-Conventional Media, Elsevier, Amsterdam, 1992, p. 401.
33. Ž. Knez, M. Habulin, Lipase catalyzed esterification at high pressure, Biocatalysis 9 (1994) 115.
34. Ž. Knez, V. Rižner, M. Škerget, Enzymatic ester synthesis at high pressure, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 143.
35. X.M. Shen, T.W. de Loos, J. de Swan Arons, Enzymatic reaction in organic solvent and supercritical gasses, in: J. Tramper et al. (Eds.), Progress in Biotechnology 8: Biocatalysis in Non-Conventional Media, Elsevier, Amsterdam, 1992, p. 417.
36. T. Dumont, D. Barth, M. Perrut, Synthesis of ethyl myristate by enzymatic reaction in SCF, J. Supercrit. Fluids 6 (2) (1993) 85.
37. 2, in: C. Balny, R. Hayashi, K. Heremans, P. Masson (Eds.), Proc. 1st European Seminar on High Pressure in Biotechnology, 1992, p. 401.
38. 2, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 149.
39. 2, Enzyme Eng. 12 (1995) 408.
40. 2, internal mass transfer limitation, in: P. Rudolf von Rohr, C. Trepp (Eds.), Proc. 3rd Int. Symp. on High Pressure Chemical Engineering, 1996, p. 103.
41. S.V. Kamat, E.J. Beckman, A.J. Russell, Enzyme activity in SCF, Crit. Rev. Biotechnol. 15 (1) (1994) 33.
42. 2 extraction, Ind. Eng. Chem. Res. 30 (1991) 939.
43. 2 extraction, J. Chem. Eng. Jpn. 25 (1) (1992) 104.
44. Y. Endo, K. Fujimoto, K. Arai, Enzyme reaction in SCF, in: T. Yano, R. Matsuno, K. Nakamura (Eds.), Proc. 6th Int. Congress on Engineering and Food, vol. 2, 1994, p. 849.
45. S.V. Kamat, G. Critchley, E.J. Beckman, A.J. Russell, Biocatalytic synthesis of acrylates in organic-solvent and SCF, Biotechnol. Bioeng. 46 (6) (1995) 610.
46. 2, in: C. Balny, R. Hayashi, K. Heremans, P. Masson (Eds.), Proc. 1st European Seminar on High Pressure in Biotechnology, 1992, p. 411.
47. 2, in: M. McHugh (Ed.), Proc. 2nd Int. Symp. on Supercritical Fluids, 1994, p. 146.
48. 2 as processing medium for enzymatic interesterification, in: T. Yano, R. Matsuno, K. Nakamura (Eds.), Proc. 6th Int. Congress on Engineering and Food, vol. 2, 1994, p. 852.
49. A.K. Chaudhary, S.V. Kamat, E.J. Beckman, D. Nurok, R.M. Kleyer, P. Hajdu, A.J. Russell, Control of subtilisin substrate-specificity by solvent engineering in organic-solvent and SC-fluoroform, JAOCS 118 (51) (1996) 12891.
50. 2, Enzyme Microb. Technol. 16 (9) (1994) 785.
51. 2, Abstr. Am. Chem. Soc. 213 (4) (1997) 162.
52. 2, Chemtech (1991) 240.
53. K. Nakamura, Biological applications of SCF, in: M. Perrut, G. Brunner (Eds.), Proc. 3rd Int. Symp. on Supercritical Fluids, vol. 3, 1994, p. 121.
54. M. Habulin, V. Krmelj, Ž. Knez, Synthesis of oleic acid esters catalyzed by immobilized lipase, J. Agric. Food Chem. 44 (1996) 338.
55. NOVO Nordisk - Analytical method AF 206/2-GB.
56. M. Leitgeb, Ž. Knez, The influence of water on the synthesis of n-butyl oleate by immobilized Mucor miehei lipase, J. Am. Oil Chem. Soc. 67 (1990) 775.
57. 2, J. Supercrit. Fluids 5 (1992) 251.
58. S. Kamat, E.J. Beckman, A.J. Russell, Role of diffusion in non-aqueous enzymology. 1. Theory, Enzyme Microb. Technol. 14 (4) (1992) 265.
59. J.E. Baily, D.F. Ollis, Biochemical Engineering Fundamentals, McGraw-Hill, London, 1986, p. 86.
60. Ž. Knez, V. Rizner, M. Habulin, D. Bauman, Enzymatic synthesis of oleyl oleate in dense fluids, JAOCS 72 (11) (1995) 2345.
61. M. Habulin, Ž. Knez, Influence of reaction parameters on synthesis of n-butyl oleate by immobilized Mucor Miehei lipase, Fat. Sci. Technol. 95 (1993) 249.
62. Ž. Knez, M. Leitgeb, D. Završnik, B. Lavrič, Synthesis of oleic esters with immobilized lipase, Fat. Sci. Technol. 92 (1990) 169.
63. Ž. Knez, M. Habulin, S. Pečnik, Enzymatic synthesis of esters, in: C. Christiansen et al. (Eds.), Proc. 5th European Congress on Biotechnology, vol. 1, 1990, p. 54.
64. M. Habulin, Ž. Knez, Enzymatic synthesis of n-butyl oleate in a hollow fiber membrane reactor, J. Membr. Sci. 61 (1991) 315.
65. S. Pečnik, Ž. Knez, Enzymatic fatty ester synthesis, J. Am. Oil Chem. Soc. 69 (1992) 261.
66. V. Krmelj, M Habulin, Ž. Knez, Synthesis of oleyl oleate with immobilized lipase from Mucor miehei, Fat. Sci. Technol. 97 (9) (1995) 324.
67. M. Perrut, Enzymatic reactions and cell behaviours in SCF, Chem. Biochem. Eng. Q 8 (1994) 25.
68. 2, J. Enzyme Microb. Technol. 13 (1991) 221.
69. M. Habulin, Ž. Knez, Fat. Sci. Technol. 95 (7) (1993) 249.