Enzymatic production of mono- and diglycerides in compressed n-butane and AOT surfactant

Journal of Supercritical Fluids

Volumn 49, Issue 2, 2009, Pages 216-220

  Valério, Alexsandra ^a   Fiametti, Karina G ^a   Rovani, Suzimara ^a   Franceschi, Elton ^a   Corazza, Marcos L ^a   Treichel, Helen ^a   de Oliveira, Débora ^a   Oliveira, J Vladimir ^a  

^a DEPARTMENT OF FOOD ENGINEERING   (Brazil)

Author keywords

Glycerolysis; Lipase; n Butane; Olive oil

Indexed keywords

AEROSOL-OT; ALTERNATIVE ROUTES; AOT SURFACTANTS; BATCH MODES; CONVENTIONAL METHODS; DIGLYCERIDES; ENZYMATIC PRODUCTIONS; ENZYME CONCENTRATIONS; GLYCEROLYSIS; HIGH CONTENTS; IMMOBILIZED LIPASE; LIPASE-CATALYZED GLYCEROLYSIS; MASS RATIOS; MILD TEMPERATURES; MOLAR RATIOS; MONOGLYCERIDES; N-BUTANE; NOVOZYM 435; OLIVE OIL; REACTION PRODUCTS; SHORT REACTION TIME; SULFOSUCCINATE;

BUTANE; GLYCEROL; SODIUM; SUBSTRATES; SURFACE ACTIVE AGENTS; VEGETABLE OILS;

LIQUEFIED PETROLEUM GAS;

EID: 65549143805     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2009.02.001     Document Type: Article

References (36)

1. Noureddini H., Harkey D.W., and Gutsman M.R. A continuous process for the glycerolysis of soybean oil. J. Am. Oil Chem. Soc. 81 (2004) 203
2. Sonntag N.O.V. Glycerolysis of fats and methyl esters: status, review and critique. J. Am. Oil Chem. Soc. 59 (1982) 795
3. Krog N. Lipid Technologies and Applications (1997), Marcel Dekker, New York, USA
4. Damstrup M.L., Abildskov J., Kiil S., Jensen A.D., Sparso F.V., and Xu X. Evaluation of binary solvent mixtures for efficient monoacylglycerol production by continuous enzymatic glycerolysis. J. Agric. Food Chem. 54 (2006) 7113
5. Pawongrat R., Xu X., and H-Kittikun A. Synthesis of monoacylglycerol rich in polyunsaturated fatty acids from tuna oil with immobilized lipase AK. Food Chem. 104 (2007) 251
6. Ferreira-Dias S., Correia A.C., Baptista F.O., and Fonseca M.M.R. Contribution of response surface design to the development of glycerolysis systems catalyzed by commercial immobilized lipases. J. Molec. Catal. B: Enzymatic 11 (2001) 699
7. Kaewthong W., Sirisansaneeyakul S., Prasertsan P., and H-Kittikun A. Continuous production of monoacylglycerols by glycerolysis of palm olein by immobilized lipase. Process Biochem. 40 (2005) 1525
8. Yang T., Rebsdorf M., Engelrud U., and Xu X. Enzymatic production of monoacylglycerols containing polyunsaturated fatty acids through an efficient glycerolysis system. J. Agric. Food Chem. 53 (2005) 1475
9. Moquin P.H.L., Temelli F., Sovová H., and Saldaña M.D.A. Kinetic modeling of glycerolysis-hydrolysis of canola oil in supercritical carbon dioxide media using equilibrium data. J. Supercrit. Fluids 37 (2006) 417
10. Murase T., Aoki M., Wakisaka T., Hase T., and Tokimitsu I. Antiobesity effect of dietary diacylglycerol in C57BL/6J mice: dietary diacylglycerol stimulates intestinal lipid metabolism. J. Lipid Res. 43 (2002) 1312
11. Taguchi H., Omachi T., Nagao T., Matsuo N., Tokimitsu I., and Itakura H. Dietary diacylglycerol suppresses high fat dietinduced hepatic fat accumulation and microsomal triacylglycerols transfer protein activity in rats. J. Nutr. Biochem. 13 (2002) 678
12. Ghamgui H., Miled N., Rebai A., Karra-chaâbouni M., and Gargouri Y. Production of mono-olein by immobilized Staphylococcus simulans lipase in a solvent-free system: optimization by response surface methodology. Enzyme Microb. Tech. 39 (2006) 717
13. Weber N., and Mukeherjee K.D. Solvent-free lipase-catalyzed preparation of diacylglycerols. J. Agric. Food Chem. 52 (2004) 5347
14. Tuter M., and Aksoy H.A. Solvent-free glycerolysis of palm and palm kernel oils catalyzed by commercial 1,3-specific lipase from Humicola lanuginosa and composition of glycerolysis products. Biotechnol. Lett. 22 (2000) 31
15. Guo Z., and Xu X. Lipase-catalyzed glycerolysis of fats and oils in ionic liquids: a further study on the reaction system. Green Chem. 8 (2006) 54
16. Jackson M.A., and King J.W. Lipase-catalyzed glycerolysis of soybean oil in supercritical carbon dioxide. J. Am. Oil Chem. Soc. 77 (1997) 103
17. Arcos J.A., and Otero C. Enzyme, medium and reaction engineering to design a low-cost, selective production method for mono- and dioleoylglycerols. J. Am. Oil Chem. Soc. 76 (1996) 673
18. Knez Z., and Habulin M. Compressed gases as alternative enzymatic-reaction solvents: a short review. J. Supercrit. Fluids 23 (2002) 29
19. Kumar R., Madras S., and Modak J. Enzymatic synthesis of ethyl palmitate in supercritical carbon dioxide. Ind. Eng. Chem. Res. 43 (2004) 1568
20. Jessop P.G., and Leitner W. Chemical Synthesis Using Supercritical Fluids (1999), Wiley-VCH, Weinheim, USA
21. Esmelindro A.F.A., Fiametti K.G., Ceni G., Corazza M.L., Treichel H., Oliveira D., and Oliveira J.V. Lipase-catalyzed production of monoglycerides in compressed propane and AOT surfactant. J. Supercrit. Fluids 47 (2008) 64
22. Habulin M., and Knez Z. Activity and stability of lipases from different sources in supercritical carbon dioxide and near-critical propane. J. Chem. Technol. Biotechnol. 76 (2001) 1260
23. Dalla Rosa C., Morandim M.B., Ninow J.L., Dariva C., Oliveira D., Treichel H., and Oliveira J.V. Lipase-catalyzed production of fatty acid ethyl esters from soybean oil in compressed propane. J. Supercrit. Fluids 47 (2008) 49
24. Carvalho C.M.L., and Cabral J.M.S. Reverse micelles as reaction media for lipases. Biochimie 82 (2000) 1063
25. Stamatis H., Xenakis A., and Kolisis F.N. Bioorganic reactions in microemulsions: the case of lipases. Biotechnol. Adv. 17 (1999) 293
26. Singh C.P., Shah D.O., and Holmberg K. Synthesis of mono- and diglycerides in water-in-oil microemulsions. J. Am. Oil Chem. Soc. 71 (1994) 583
27. Holmberg K., and Osterberg E. Enzymatic preparation of monoglycerides in microemulsion. Surfactants Detergents Tech. (1988) 1544
28. Chang P.S., Rhee J.S., and Kim J.J. Continuous glycerolysis of olive oil by Chromobacterium viscosum lipase immobilized on liposome in reverse micelles. Biotechnol. Bioeng. 38 (1991) 1159
29. Fiametti K.G., Rovani S., Oliveira D., Corazza M.L., Treichel H., and Oliveira J.V. Assessment of variables effects on solvent-free monoacylglycerols enzymatic production in AOT surfactant. Europ. J. Lipid Sci. Technol. 110 (2008) 510
30. Reid R.C., Prausnitz J.M., and Poling B.E. The Properties of Gases and Liquids. 4th ed. (1987), McGraw-Hill Book Company
31. Olds R.H., Reamer H.H., Sage B.H., and Lacey W.N. Phase equilibria in hydrocarbon systems. Volumetric behavior of n-butane. Ind. Eng. Chem. 36 (1944) 82
32. Bender J.P., Junges A., Franceschi E., Corazza F.C., Dariva C., Oliveira J.V., and Corazza M.L. High pressure cloud point data for the system glycerol + olive oil + n-butane + AOT. Braz. J. Chem. Eng. 25 (2008) 563
33. Benazzi T., Franceschi E., Corazza M.L., Oliveira J.V., and Dariva C. High-pressure multiphase equilibria in the system glycerol + olive oil + propane + AOT. Fluid Phase Equil. 244 (2006) 128
34. Oliveira D., Feihrmann A.C., Rubira A.F., Kunita M.H., Dariva C., and Oliveira J.V. Assessment of two immobilized lipases activity treated in compressed fluids. J. Supercrit. Fluids 38 (2006) 127
35. Watanabe T., Shimizu M., Sugiura M., Sato M., Kohori J., Yamada N., and Nakanishi K. Optimization of reaction conditions for the production of DAG using immobilized 1,3-regiospecific lipase Lipozyme RM IM. J. Am. Oil Chem. Soc. 80 (2003) 1201
36. Yang T., Rebsdorf M., Engelrud U., and Xu X. Monoacylglycerols synthesis via enzymatic glycerolysis using a simple and efficient reaction system. J. Food Lipids 12 (2005) 299