Bromenium-catalysed tandem ring opening/cyclisation of vinylcyclopropanes and vinylcyclobutanes: A metal-free [3+2+1]/[4+2+1] cascade for the synthesis of chiral amidines and computational investigation

Chemistry - A European Journal

Volumn 18, Issue 39, 2012, Pages 12498-12511

  Ganesh, Venkataraman ^a   Sureshkumar, Devarajulu ^a   Chanda, Debasree ^a   Chandrasekaran, Srinivasan ^a,b  

^a INDIAN INSTITUTE OF SCIENCE   (India)

^b JAWAHARLAL NEHRU CENTRE FOR ADVANCED SCIENTIFIC RESEARCH   (India)

Author keywords

bromine; chirality; cyclization; vinylcyclobutanes; vinylcyclopropanes

Indexed keywords

CARBOCATIONS; CHLORAMINE-T; COMPUTATIONAL INVESTIGATION; CONTINUUM MODEL; DFT CALCULATION; DFT STUDY; DOUBLE BONDS; EXPERIMENTAL OBSERVATION; GASPHASE; IN-SITU; ONE POT; PRODUCT SELECTIVITIES; REACTION PATHWAYS; RING OPENING; SOLVATION MODELS; VINYLCYCLOBUTANES; VINYLCYCLOPROPANES;

ACETONITRILE; BROMINE; CATALYSIS; CHIRALITY; CONTINUUM MECHANICS; DENSITY FUNCTIONAL THEORY; ENANTIOMERS; PROPANE; STEREOSELECTIVITY;

CYCLIZATION;

EID: 84866412658     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103556     Document Type: Article

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