New insights into the mechanism of amine/nitroxide cycling during the hindered amine light stabilizer inhibited oxidative degradation of polymers

Journal of the American Chemical Society

Volumn 134, Issue 31, 2012, Pages 12979-12988

  Gryn'ova, Ganna ^a   Ingold, K U ^b   Coote, Michelle L ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO MOLECULAR ORBITAL THEORY; ALKOXYAMINES; EXPERIMENTAL OBSERVATION; GASPHASE; HINDERED AMINE LIGHT STABILIZER; HYDROGEN ATOMS; NITROXIDES; OXIDATIVE DEGRADATION; REACTION ENERGY; REGENERATION CYCLES; STOICHIOMETRIC FACTORS;

CALCULATIONS; HYDROGEN; MOLECULAR ORBITALS;

DEGRADATION;

ALKYL GROUP; AMINE; NITROXIDE; POLYMER; RADICAL;

AB INITIO CALCULATION; AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENERGY; ENTROPY; OXIDATION; REACTION ANALYSIS; STEREOSPECIFICITY; STOICHIOMETRY; THERMODYNAMICS;

EID: 84864704522     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3006379     Document Type: Article

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