Kinetic study of H-atom transfer in imidazoline-, imidazolidine-, and pyrrolidine-based alkoxyamines: Consequences for nitroxide-mediated polymerization

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 47, Issue 23, 2009, Pages 6579-6595

  Edeleva, Mariya V ^a,b   Kirilyuk, Igor A ^c   Zubenko, Dmitry P ^b   Zhurko, Irina F ^c   Marque, Sylvain R A ^d   Gigmes, Didier ^d   Guillaneuf, Yohann ^d   Bagryanskaya, Elena G ^b  

^a NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

^b INTERNATIONAL TOMOGRAPHY CENTER   (Russian Federation)

^c N N VOROZHTSOV NOVOSIBIRSK INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

^d CNRS   (France)

Author keywords

Activation energy; Alkoxyamine; Diffusion; ESR EPR; Gel permeation chromatography (GPC); H atom transfer reaction; Initiators; Kinetics (polym.); Living radical polymerization (LRP); Nitroxide; NMR

Indexed keywords

ALKOXYAMINE; ALKOXYAMINES; ESR/EPR; H-ATOM TRANSFER; KINETICS(POLYM.); LIVING RADICAL POLYMERIZATION; LIVING RADICAL POLYMERIZATION (LRP); NITROXIDES;

ACTIVATION ENERGY; ATOM TRANSFER RADICAL POLYMERIZATION; ATOMS; CHROMATOGRAPHIC ANALYSIS; CHROMATOGRAPHY; DEUTERIUM; FREE RADICAL REACTIONS; GELS; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; POLYMERS; RATE CONSTANTS; REACTION KINETICS; STYRENE;

AMINES;

EID: 72449124703     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.23701     Document Type: Article

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