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Volumn 18, Issue 31, 2012, Pages 9500-9504

Zinc-catalyzed dehydrogenative N-silylation of indoles with hydrosilanes

Author keywords

dehydrogenation; heterocycles; Lewis acids; silicon; zinc; zinc catalysis

Indexed keywords

HETEROCYCLES; HYDROSILANES; LEWIS ACID; NITRILE SOLVENTS; ZINC TRIFLATES;

EID: 84864149360     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201200651     Document Type: Article
Times cited : (45)

References (62)
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    • 2)indoles as synthetic intermediates, which are subsequently utilized for Ir-catalyzed site-selective borylation in one-pot. Although the report appears to be the only example of dehydrogenative N-silylation of indoles, there is no indication that the N-silylindoles have been isolated to ascertain their structures:, D. W. Robbins, T. A. Boebel, J. F. Hartwig, J. Am. Chem. Soc. 2010, 132, 4068-4069.
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 4068-4069
    • Robbins, D.W.1    Boebel, T.A.2    Hartwig, J.F.3
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    • Angew. Chem. Int. Ed. 2008, 47, 7508-7510; for Ru catalysis, see
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    • A related mechanism has been proposed for the hydrosilylation of carbonyl compounds under iridium catalysis, see:, S. Park, M. Brookhart, Organometallics 2010, 29, 6057-6964.
    • (2010) Organometallics , vol.29 , pp. 6057-6964
    • Park, S.1    Brookhart, M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.