Highly diastereoselective construction of fused carbocycles from cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers: Scope, Mechanism, and origin of diastereoselectivity

Chemistry - A European Journal

Volumn 18, Issue 8, 2012, Pages 2196-2201

  Qu, Jian Ping ^a   Liang, Yong ^b   Xu, Hao ^a   Sun, Xiu Li ^a   Yu, Zhi Xiang ^b   Tang, Yong ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b PEKING UNIVERSITY   (China)

Author keywords

cycloaddition; cyclopropane; density functional calculations; diastereoselectivity; reaction mechanisms

Indexed keywords

CARBOCYCLES; CYCLOADDITION REACTION; CYCLOPROPANE; CYCLOPROPANE RING; DENSITY-FUNCTIONAL CALCULATIONS; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; ENOL SILYL ETHERS; REACTION MECHANISM; SILYL GROUP; STEREOCENTERS;

CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ETHERS; ORGANIC COMPOUNDS; PROPANE; STEREOSELECTIVITY;

CARBOXYLATION;

ALCOHOL DERIVATIVE; CARBOXYLIC ACID; CYCLOPROPANE; CYCLOPROPANE DERIVATIVE; ETHER DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEREOISOMERISM;

ALCOHOLS; CARBOXYLIC ACIDS; CATALYSIS; CYCLIZATION; CYCLOPROPANES; ETHERS, CYCLIC; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84863157939     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103495     Document Type: Article

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