Regio- and stereoselectivity in the reactions of organometallic reagents with an electron-deficient and an electron-rich vinyloxirane: Applications for sequential bis-allylic substitution reactions in the generation of vicinal stereogenic centers

Journal of Organic Chemistry

Volumn 77, Issue 11, 2012, Pages 4949-4967

  Dieter, R Karl ^a   Huang, Yaxin ^a   Guo, Fenghai ^a  

^a CLEMSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC ALCOHOL; ALLYLIC PHOSPHATES; ALLYLIC SUBSTITUTION; DIASTEREO-SELECTIVITY; ELECTRON-DEFICIENT; ELECTRON-RICH; GRIGNARD REAGENT; ORGANOMETALLIC REAGENT; REACTION CONDITIONS; STEREOCONTROL; STEREOGENIC CENTERS;

ALLYLATION; ELECTRONS; LIGANDS; LITHIUM; ORGANOMETALLICS; PARAFFINS; REGIOSELECTIVITY; STEREOSELECTIVITY;

SUBSTITUTION REACTIONS;

1,2 EPOXY 3 BUTENE; ALCOHOL; ALLYL COMPOUND;

ARTICLE; CONTROLLED STUDY; DIASTEREOISOMER; OZONOLYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 84861805362     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300304n     Document Type: Article

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