Stereochemical and Mechanistic Studies on Conjugate Addition of Organocuprates to Acyclic Enones and Enoates: Simple Rule for Diastereofacial Selectivity

Journal of Organic Chemistry

Volumn 63, Issue 13, 1998, Pages 4449-4458

  Yamamoto, Keiko ^a   Ogura, Hiroshi ^a   Jukuta, Jun Ichi ^a   Inoue, Hiroko ^a   Hamada, Kazuhiro ^a   Sugiyama, Youko ^a   Yamada, Sachiko ^a  

^a TOKYO MEDICAL AND DENTAL UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000285765     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo980308x     Document Type: Article

References (91)

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53. 2c,d
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64. 6 The configurations of other cuprate addition products 15, 16, 23, 24, 27, and 28 were assigned on the basis of an assumption that those cuprate additions operate via a similar mechanism and hence have similar facial selectivity.
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90. In entries 14, 15, 17, 21, 23, and 26 in Table 1, the residue was chromatographed on silica gel at this stage to isolate the byproduct 20, 21, or 22.
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