Alkylations of functionalized organozinc reagents with allylic epoxides catalyzed by a cyanocuprate

Synlett

Volumn , Issue SPEC. ISS., 1997, Pages 477-478

  Lipshutz, Bruce H ^a   Woo, Kyoungja ^a   Gross, Tim ^a   Buzard, Daniel J ^a   Tirado, Raymond ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001245686     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-6130     Document Type: Article

References (14)

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4. Knochel, P.; Singer, R.D. Chem. Rev., 1993, 93, 2117;
5. Knochel, P. "Organozinc and Organocadmium Compounds in Organic Synthesis", in Comprehensive Organometallic Chemistry II, Hegedus, L.S., Ed., Pergamon Press, 1995, Vol. 11, pp 159-190.
6. Knochel, P. Synlett, 1995, 393.
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12. Lipshutz, B.H.; Keil, R. J. Am. Chem. Soc., 1992, 114, 7919.
13. Cahiez, G.; Alexakis, A.; Normant, J. Synthesis, 1978, 528. In our hands, the cyclic cases (entries 3-6) gave only the trans products, while the acyclic examples (entries 1,2) led to 80-90 : 20-10 ratios of E to Z products.
14. + 339.2719, found 339.2723.