메뉴 건너뛰기




Volumn 13, Issue 8, 2012, Pages 1116-1120

Catalytic Azide Reduction in Biological Environments

Author keywords

Azide reductions; Catalysis; Cellular chemistry; Fluorescence; Iron porphyrins

Indexed keywords

6 TETRAARYLPORPHINE DERIVATIVE; AMINE; AZIDE; CHEMICAL COMPOUND; FLUOROPHORE; IRON; REDUCING AGENT; THIOL DERIVATIVE; UNCLASSIFIED DRUG; WATER;

EID: 84861418856     PISSN: 14394227     EISSN: 14397633     Source Type: Journal    
DOI: 10.1002/cbic.201100719     Document Type: Article
Times cited : (107)

References (47)
  • 14
    • 84872364435 scopus 로고    scopus 로고
    • For pioneering work in this direction, see also
    • For pioneering work in this direction, see also
  • 19
    • 84872364932 scopus 로고    scopus 로고
    • For recent examples of catalytically active metal complexes in medicinal chemistry see:
    • For recent examples of catalytically active metal complexes in medicinal chemistry see:
  • 22
    • 84872365240 scopus 로고    scopus 로고
    • It is our experience that not the individual components, but rather the combination of thiols, protic solvent and air causes serious problems for most metal-containing catalysts.
    • It is our experience that not the individual components, but rather the combination of thiols, protic solvent and air causes serious problems for most metal-containing catalysts.
  • 25
    • 84872364598 scopus 로고    scopus 로고
    • Note
    • For recent applications based on the reduction of aromatic azides, see:
  • 30
    • 84872365954 scopus 로고    scopus 로고
    • For the interaction and activation of organic azides by transition metal complexes, see:
    • For the interaction and activation of organic azides by transition metal complexes, see:
  • 33
    • 0037415080 scopus 로고    scopus 로고
    • II-porphyrin-catalyzed nitrene transfer reactions with aromatic azides, the reduction of the azides to their respective amines was reported as a side reaction. For an example, see
    • II-porphyrin-catalyzed nitrene transfer reactions with aromatic azides, the reduction of the azides to their respective amines was reported as a side reaction. For an example, see: F. Ragaini, A. Penoni, E. Gallo, S. Tollari, C. Li Gotti, M. Lapadula, E. Mangioni, S. Cenini, Chem. Eur. J. 2003, 9, 249-259.
    • (2003) Chem. Eur. J. , vol.9 , pp. 249-259
    • Ragaini, F.1    Penoni, A.2    Gallo, E.3    Tollari, S.4    Gotti, C.L.5    Lapadula, M.6    Mangioni, E.7    Cenini, S.8
  • 34
    • 84872364500 scopus 로고    scopus 로고
    • For an efficient reduction of organic azides with dithiols, see:
    • For an efficient reduction of organic azides with dithiols, see:
  • 37
    • 84872366557 scopus 로고    scopus 로고
    • Aliphatic azides are not reduced under these conditions as has been tested, for example, for 2-phenethylazide.
    • Aliphatic azides are not reduced under these conditions as has been tested, for example, for 2-phenethylazide.
  • 40
    • 84872365263 scopus 로고    scopus 로고
    • Note
    • The better water-soluble poly(ethylene glycol)-functionalized catalyst [Fe(TPPE)Cl] can be used with a reduced DMSO content, although some DMSO is necessary to dissolve the rhodamine bisazide 3 substrate. See the Experimental Section for more details.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.