Electrochemical analysis of cyclopentadienylmetal carbonyl dimer complexes: Insight into the design of hydrogen-producing electrocatalysts

Journal of Organometallic Chemistry

Volumn 711, Issue , 2012, Pages 25-34

  Donovan, Elizabeth S ^a   Felton, Greg A N ^a  

^a OAKLAND UNIVERSITY   (United States)

Author keywords

Electrocatalysis; Electrochemistry; Hydrogen; Metal hydrides; Reduction

Indexed keywords

4-TERT-BUTYLPHENOL; DIHYDROGEN; DIMER COMPLEXES; ELECTROCHEMICAL ANALYSIS; METAL COMPOSITION; METAL HYDRIDES; MOLECULAR HYDROGEN; MOLYBDENUM COMPLEX; ORGANOMETALLIC COMPOUNDS; OVERPOTENTIAL; PROTON SOURCE; WEAK ACIDS;

CATALYSIS; DIMERS; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROCHEMISTRY; HYDROGEN; IRON COMPOUNDS; MOLYBDENUM; MOLYBDENUM COMPOUNDS; NEGATIVE IONS; ORGANOMETALLICS; REDUCTION; TUNGSTEN;

TUNGSTEN COMPOUNDS;

EID: 84861048673     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2012.03.031     Document Type: Article

References (58)

1. C. Tard, and C.J. Pickett Chem. Rev. 109 2009 2245 2274
2. F. Gloaguen, and T.B. Rauchfuss Chem. Soc. Rev. 38 2009 100 108
3. J.F. Capon, F. Gloaguen, F.Y. Pétillon, and P. Schollhammer J. Coord. Chem. Rev. 253 2009 1476 1494
4. Y. Ohki, and K. Tatsumi Eur. J. Inorg. Chem. 2011 973 985
5. R.D. Theys, M.D. Dudley, and M.M. Hossain Coord. Chem. Rev. 253 2009 180 234
6. D.J. Darensbourg, J.H. Reibenspies, C. Lai, W. Lee, and M.Y. Darensbourg J. Am. Chem. Soc. 119 1997 7903 7904
7. V. Artero, and M. Fontecave C.R. Chim. 11 2008 926 931
8. T.S. Piper, F.A. Cotton, and G. Wilkinson J. Inorg. Nucl. Chem. 1 1955 165 174
9. G.A.N. Felton, A.K. Vannucci, N. Okumura, L.T. Lockett, D.H. Evans, R.S. Glass, and D.L. Lichtenberger Organometallics 27 2008 4671 4679
10. G.A.N. Felton, C.A. Mebi, B.J. Petro, A.K. Vannucci, D.H. Evans, R.S. Glass, and D.L. Lichtenberger J. Organomet. Chem. 694 2009 2681 2699
11. J.L. Dempsey, B.S. Brunschwig, J.R. Winkler, and H.B. Gray Acc. Chem. Rev. 42 2009 1995 2004
12. S. Losse, J.G. Vos, and S. Rau Coord. Chem. Rev. 254 2010 2492 2504
13. J.P. Bigi, T.E. Hanna, W.H. Harman, A. Chang, and C.J. Chang Chem. Commun. 46 2010 958 960
14. M.R. DuBois, and D.L. DuBois Acc. Chem. Rev. 42 2009 1974 1982
15. D.L. DuBois, and R.M. Bullock Eur. J. Inorg. Chem. 2011 1017 1027
16. A.M. Appel, D.L. DuBois, and M.R. DuBois J. Am. Chem. Soc. 127 2005 12717
17. H.I. Karunadassa, C.J. Chang, and J.R. Long Nature 464 2010 1329 1333
18. Y. Oudart, V. Artero, J. Pécaut, C. Lebrun, and M. Fontecave Eur. J. Inorg. Chem. 2007 2613 2626
19. E.A. Ison, R.A. Corbin, and M.M. Abu-Omar J. Am. Chem. Soc. 127 2005 11938 11939
20. S. Canaguier, L. Vaccaro, V. Artero, R. Ostermann, J. Pécaut, M.J. Field, and M. Fontecave Chem. Eur. J. 15 2009 9350 9364
21. E.O. Fischer, and A. Volger Z. Naturforsch. 17b 1962 421
22. E.O. Fischer, W. Hafner, and H.O. Stahl Z. Anorg. Allg. Chem. 282 1955 47 62
23. M. Tilset, and V.D. Parker J. Am. Chem. Soc. 111 1989 6711 6717
24. A recent example: Z. Zhang, Q. Lin, S. Zheng, X. Bu, and P. Feng Chem. Commun. 47 2011 3918 3920
25. R.E. Dessy, P.M. Weissman, and R.L. Phol J. Am. Chem. Soc. 88 1966 5117 5121
26. J.R. Pugh, and T.J. Meyer J. Am. Chem. Soc. 114 1992 3784 3792
27. N.G. Connelly, and W.E. Geiger Adv. Organomet. Chem. 23 1984 1 93
28. S.G. Davies, S.J. Simpson, and V.D. Parker J. Chem. Soc. Chem. Chem. Commun. 1984 352 353
29. S. Fukuzumi, K. Ohkubo, M. Fujitsuka, O. Ito, M.C. Teichman, E. Maisonhaute, and C. Amatore Inorg. Chem. 40 2001 1213 1219
30. E.F. Dalton, S. Ching, and R.W. Murray Inorg. Chem. 30 1991 2642 2648
31. T.J. Meyer, and J.V. Caspar Chem. Rev. 85 1985 187 218
32. J.L. Hughey, C.R. Bock, and T.J. Meyer J. Am. Chem. Soc. 97 1975 4440 4441
33. At 0.050 V/s and 1.2 V of electrolysis time leads to a dimensionless time parameter of 0.064. This value meets the criteria of being <<1, such that diffusion is predominantly linear due to the diffusion layer being thin relative to the electrode disk radius: M.L. Longmire, M. Watanabe, H. Zhang, T.T. Wooster, and R.W. Murray Anal. Chem. 62 1990 747 752
34. M.W. Lehmann, and D.H. Evans J. Electroanal. Chem. 500 2001 12 20
35. W.E. Geiger, and T. Gennet Organometallics 6 1987 1634 1639
36. H. Wang, Y. Xie, R.B. King, and H.F. Schaefer Inorg. Chem. 45 2006 3384 3392
37. K.M. Kadish, D.A. Lacombe, and J.E. Anderson Inorg. Chem. 25 1986 2246 2250
38. M.-L. Marcos, C. Moreno, R.M. Medina, M.-J. Macazaga, S. Delagado, and J. González-Velasco J. Organomet. Chem. 568 1998 185 196
39. R.J. Klinger, W. Butler, and M.D. Curtis J. Am. Chem. Soc. 97 1975 3535 3536
40. J.A.S. Roberts, D.L. DuBois, and R.M. Bullock Organometallics 30 2011 4555 4563
41. T. Munisamy, and S.L. Gipson J. Organomet. Chem. 692 2007 1087 1091
42. J.M. Anna, J.T. King, and K.J. Kubarych Inorg. Chem. 50 2011 9273 9283
43. M. Gallagher, P. Dougherty, P.S. Tanner, D.C. Barbini, J. Schulte, and W.E. Jones Inorg. Chem. 38 1999 2953 2956
44. M. Tilset Inorg. Chem. 33 1994 3121 3126
45. D.C. Barbini, P.S. Tanner, T.D. Francone, K.B. Furst, and W.E. Jones Inorg. Chem. 35 1996 4017 4022
46. D.R. Tyler Acc. Chem. Res. 24 1991 325 331
47. C. Nataro, L.M. Thomas, and R.J. Angelici Inorg. Chem. 36 1997 6000 6008
48. G.A.N. Felton, R.S. Glass, D.L. Lichtenberger, and D.H. Evans Inorg. Chem. 45 2006 9181 9184
49. A.K. Justice, R.C. Linck, and T.B. Rauchfuss Inorg. Chem. 45 2006 2406 2412
50. D.P. Estes, A.K. Vannucci, A.R. Hall, D.L. Lichtenberger, and J.R. Norton Organometallics 30 2011 3444 3447
51. E.J. Moore, J.M. Sullivan, and J.R. Norton J. Am. Chem. Soc. 108 1986 2257 2263
52. V. Fourmond, P.-A. Jacques, M. Fontecave, and V. Artero Inorg. Chem. 49 2010 10338 10347
53. Value used is for phenol, taken from: K. Izutsu Acid-Base Dissociation Constants in Dipolar Aprotic Solvents 1990 Blackwell Scientific Oxford, U.K.
54. R. Mejia-Rodriguez, D. Chong, J.H. Reibenspies, M.P. Soriaga, and M.Y. Darensbourg J. Am. Chem. Soc. 126 2004 12004 12014
55. R.M. Bullock Comments Inorg. Chem. 12 1991 1 33
56. R.F. Jordan, and J.R. Norton J. Am. Chem. Soc. 104 1982 1255 1263
57. G.A.N. Felton, A.K. Vannucci, J. Chen, L.T. Lockett, N. Okumura, B.J. Petro, U.I. Zakai, D.H. Evans, R.S. Glass, and D.L. Lichtenberger J. Am. Chem. Soc. 129 2007 12521 12530
58. R.C. Badger, J.S. D'Acchioli, B.C. Gamoke, S.B. Kim, T.A. Oudenhoven, D.A. Sweigart, and R.S. Tanke Organometallics 28 2009 418 424