Experimental and digital simulation studies of the electrochemical oxidation of the metal anion [CpW(CO)2(IMes)]- and the 17-electron metal radical CpW(CO)2(IMes)•. Kinetics and thermodynamics of capture and release of MeCN by a metal radical and a metal cation

Organometallics

Volumn 30, Issue 17, 2011, Pages 4555-4563

  Roberts, John A S ^a   Dubois, Daniel L ^a   Bullock, R Morris ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REDUCTION; CYCLIC VOLTAMMOGRAMS; DIGITAL SIMULATION; KINETICS AND THERMODYNAMICS; METAL CATION; METAL-CENTERED RADICALS; ONE-ELECTRON OXIDATION; RADICAL COMPLEXES; SCAN RATES; VOLTAMMOGRAMS;

CROWN ETHERS; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL OXIDATION; ELECTROCHEMISTRY; METALS; POSITIVE IONS; REDUCTION; THERMODYNAMICS; TUNGSTEN;

ELECTRONS;

EID: 80052429913     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om2002816     Document Type: Article

References (52)

1. Tilset, M.; Parker, V. D. J. Am. Chem. Soc. 1989, 111, 6711-6717
2. Modified in J. Am. Chem. Soc. 1990, 112, 2843.
3. Tilset, M. J. Am. Chem. Soc. 1992, 114, 2740-2741
4. Skagestad, V.; Tilset, M. J. Am. Chem. Soc. 1993, 115, 5077-5083
5. Ellis, W. W.; Raebiger, J. W.; Curtis, C. J.; Bruno, J. W.; DuBois, D. L. J. Am. Chem. Soc. 2004, 126, 2738-2743
6. Ryan, O. B.; Tilset, M.; Parker, V. D. J. Am. Chem. Soc. 1990, 112, 2618-2626
7. Ciancanelli, R.; Noll, B. C.; DuBois, D. L.; DuBois, M. R. J. Am. Chem. Soc. 2002, 2984-2992
8. Raebiger, J. W.; DuBois, D. L. Organometallics 2005, 24, 110-118
9. Miedaner, A.; Raebiger, J. W.; Curtis, C. J.; Miller, S. M.; DuBois, D. L. Organometallics 2004, 23, 2670-2679
10. Zhu, X. Q.; Zhang, M. T.; Yu, A.; Wang, C. H.; Cheng, J. P. J. Am. Chem. Soc. 2008, 130, 2501-2516
11. Krivenko, A. G.; Kotkin, A. S.; Kurmaz, V. A. Russ. J. Electrochem. 2005, 41, 122-136
12. Berning, D. E.; Noll, B. C.; DuBois, D. L. J. Am. Chem. Soc. 1999, 121, 11432-11447
13. Curtis, C. J.; Miedaner, A.; Ellis, W. W.; DuBois, D. L. J. Am. Chem. Soc. 2002, 124, 1918-1925
14. Price, A. J.; Ciancanelli, R.; Noll, B. C.; Curtis, C. J.; DuBois, D. L.; DuBois, M. R. Organometallics 2002, 21, 4833-4839
15. Curtis, C. J.; Miedaner, A.; Raebiger, J. W.; DuBois, D. L. Organometallics 2004, 23, 511-516
16. Raebiger, J. W.; Miedaner, A.; Curtis, C. J.; Miller, S. M.; Anderson, O. P.; DuBois, D. L. J. Am. Chem. Soc. 2004, 126, 5502-5514
17. Appel, A. M.; Lee, S.-J.; Franz, J. A.; DuBois, D. L.; Rakowski DuBois, M.; Twamley, B. Organometallics 2009, 28, 749-754
18. Appel, A. M.; Lee, S.-J.; Franz, J. A.; DuBois, D. L.; DuBois, M. R. J. Am. Chem. Soc. 2009, 131, 5224-5232
19. Tilset, M. Inorg. Chem. 1994, 33, 3121-3126
20. Tilset, M., Organometallic Electrochemistry: Thermodynamics of Metal-Ligand Bonding. In Comprehensive Organometallic Chemistry III; Crabtree, R. H.; Mingos, D. M. P., Eds.; Elsevier: New York, 2007.
21. Geiger, W. E. Organometallics 2007, 26, 5738-5765
22. Savéant, J.-M. Chem. Rev. 2008, 108, 2348-2378
23. Artero, V.; Fontecave, M. Coord. Chem. Rev. 2005, 249, 1518-1535
24. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2 nd ed.; John Wiley & Sons: New York, 2001.
25. Papish, E. T.; Rix, F. C.; Spetseris, N.; Norton, J. R.; Williams, R. D. J. Am. Chem. Soc. 2000, 122, 12235-12242
26. Tang, L.; Papish, E. T.; Abramo, G. P.; Norton, J. R.; Baik, M.-H.; Friesner, R. A.; Rappé, A. J. Am. Chem. Soc. 2003, 125, 10093-10102
27. Smith, K.-T.; Norton, J. R.; Tilset, M. Organometallics 1996, 15, 4515-4520
28. Meyer, T. J.; Caspar, J. V. Chem. Rev. 1985, 85, 187-218
29. Scott, S. L.; Espenson, J. H.; Zhu, Z. J. Am. Chem. Soc. 1993, 115, 1789-1797
30. Roberts, J. A. S.; Franz, J. A.; van der Eide, E. F.; Walter, E. D.; Petersen, J. L.; DuBois, D. L.; Bullock, R. M. J. Am. Chem. Soc., Accepted for publication. DOI: 10.1021/ja202754e.
31. Roberts, J. A. S.; Appel, A. M.; DuBois, D. L.; Bullock, R. M., J. Am. Chem. Soc., Accepted for publication. DOI: 10.1021/ja202830w.
32. Skagestad, V.; Tilset, M. Organometallics 1991, 10, 2110-2113
33. Dioumaev, V. K.; Szalda, D. J.; Hanson, J.; Franz, J. A.; Bullock, R. M. Chem. Commun. 2003, 1670-1671
34. Wu, F.; Dioumaev, V. K.; Szalda, D. J.; Hanson, J.; Bullock, R. M. Organometallics 2007, 26, 5079-5090
35. Bockris, J. O. M.; Reddy, A. K. N.; Gamboa-Aldeco, M., Modern Electrochemistry 2A. Fundamentals of Electrodics, 2nd ed.; Kluwer Academic/Plenum Publishers: New York, 2000; p 1083.
36. Tyler, D. R. Acc. Chem. Res. 1991, 24, 325-331
37. Tyler, D. R. Prog. Inorg. Chem. 1988, 36, 125-194
38. Zavarine, I. S.; Kubiak, C. P. Coord. Chem. Rev. 1998, 171, 419-438
39. Trogler, W. C. Int. J. Chem. Kinet. 1987, 19, 1025-1047
40. Therien, M. J.; Ni, C.-L.; Anson, F. C.; Osteryoung, J. G.; Trogler, W. C. J. Am. Chem. Soc. 1986, 108, 4037-4042
41. Shi, Q. Z.; Richmond, T. G.; Trogler, W. C.; Basolo, F. J. Am. Chem. Soc. 1984, 106, 71-76
42. Herrinton, T. R.; Brown, T. L. J. Am. Chem. Soc. 1985, 107, 5700-5703
43. Kowaleski, R. M.; Basolo, F.; Trogler, W. C.; Gedridge, R. W.; Newbound, T. D.; Ernst, R. D. J. Am. Chem. Soc. 1987, 109, 4860-4869
44. Zizelman, P. M.; Amatore, C.; Kochi, J. K. J. Am. Chem. Soc. 1984, 106, 3771-3784
45. Mao, F.; Philbin, C.; Weakley, T. J. R.; Tyler, D. R. Organometallics 1990, 9, 1510-1516
46. Mao, F.; Sur, S. K.; Tyler, D. R. J. Am. Chem. Soc. 1989, 111, 7627-7628
47. Schut, D. M.; Keana, K. J.; Tyler, D. R.; Rieger, P. H. J. Am. Chem. Soc. 1995, 117, 8939-8946
48. Braden, D. A.; Tyler, D. R. J. Am. Chem. Soc. 1998, 120, 942-947
49. Mao, F.; Tyler, D. R.; Bruce, M. R. M.; Bruce, A. E.; Rieger, A. L.; Rieger, P. H. J. Am. Chem. Soc. 1992, 114, 6418-6424
50. Zhang, Y.; Gosser, D. K.; Rieger, P. H.; Sweigart, D. A. J. Am. Chem. Soc. 1991, 113, 4062-4068
51. Rudolph, M.; Feldberg, S. W. DigiSim 3.03b; Bioanalytical Systems, Inc., 2004.
52. Hurle, R. L.; Woolf, L. A. J. Chem. Soc., Faraday Trans. 1 1982, 2233-2238